• 제목/요약/키워드: Mineral Oil

검색결과 524건 처리시간 0.025초

국내 유통 엔진오일 고온모사증류시험 분석 (The SIMDIST (Simulated Distillation) Analysis of Distributing Engine Oil)

  • 임영관;김지연;김종렬;하종한
    • 공업화학
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    • 제28권6호
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    • pp.632-637
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    • 2017
  • 자동차용 윤활유가 국내 윤활유 시장의 35%를 차지하고 있으며, 이 중 엔진오일이 자동차용 윤활유의 75%를 차지하고 있다. 운전자와 엔진보호를 위해 유통 엔진오일의 품질이 적절하게 관리되어져야 한다. 하지만 KS제품과 합성엔진오일(합성기유가 30% 이상 포함된 제품)은 석유 및 석유대체연료 사업법상 품질관리에서 제외되어져 있다. PAO (poly alpha olefin)와 같은 합성오일은 기존 광유보다 내마모성, 바니쉬 조절 및 산화안정도와 같은 특성이 우수한 것으로 알려져 있으며, 이러한 이유로 PAO는 엔진오일, 로터리 스크류, 중장비, 왕복 압축기, 극압장비 등에 많이 사용되어져 왔다. 본 연구에서는 고온모사증류시험(SIMDIST)을 이용하여 광유, PAO, 일정 비율의 PAO가 혼합된 광유시료를 분석하였다. 분석결과, 광유는 브로드란 크로마토그램을 얻은 반면, PAO는 특정한 머무름시간에서 샤프한 피크를 보였다. 또한 점도가 큰 물질은 큰 분자량과 높은 끓는점을 지녀 긴 머무름시간을 보였다. 특히 20%의 PAO가 함유된 시료에서 전형적인 광유와 다른 PAO 패턴의 크로마토그램을 보였다. 유통엔진오일 내 PAO 함량을 모니터링하기 위해 국내 판매량이 높은 27종류의 유통엔진오일을 분석한 결과, 모든 제품에서 PAO 함량이 20%보다 낮은 것으로 나타났다. 더욱이 제품명에 PAO라 표현한 제품조차도 PAO 함량이 낮은 것을 보였다. 따라서 합성엔진오일에 대한 적절한 관리 법규가 필요한 것으로 판단된다.

Comparison of Rolling Contact Fatigue Life of Bearing Steel Rollers Lubricated with Traction Oil and Mineral Oil Corresponding to ISO VG32

  • Nakajima, A.;Mawatari, T.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.291-292
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    • 2002
  • Using a low viscosity synthetic traction oil and a low viscosity mineral oil with nearly equal viscosity grade of ISO VG 32, the effect of kind of oil on the fatigue life of bearing steel rollers was examined. A pair of rollers finished the contact surfaces to a mirror-like condition were driven under rolling with sliding conditions of s = -3.2% and a maximum Hertzian stress in the range of $P_H=2.8GPa{\sim}4.0GPa$ was applied in point contact condition. As a result of experiments, the fatigue life with a mineral oil was longer than that with a traction oil under higher stress conditions above $P_H=3.4GPa$. Based on the numerical calculation results of the thermal EHL which simulates the present experiment, the authors discuss the reason why such a difference in the fatigue life comes out.

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식물성 절연유의 유속과 BTA에 따른 유동대전 현상 연구 (Research of Flow Velocity and BTA According to the Streaming Electrification of Vegetable Insulating Oils)

  • 최순호;방정주;허창수
    • 한국전기전자재료학회논문지
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    • 제25권10호
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    • pp.791-797
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    • 2012
  • Mineral insulating oils are an important insulating materials in oil-filled transformer. However, the mineral oil is the cause of the environmental problem. The vegetable oils are substitutes for mineral oil because of its biodegradability characteristic. As large size and high rating of the transformer increases, the losses increase at a faster rate. So insulating oil is forced circulation in the oil-filled transformer by using oil pumps. The flow electrification occurs when insulating oil was forced to be circulated. To check the flow electrification, had conducted experiments varying factors. As a result, the streaming electrification could see the changes according to flow velocity, oil temperature and insulation materials.

Biomass Gasification 공정에서 발생하는 Tar 제거연구 (Removal of Tar from Biomass Gasification Process)

  • 김주회;조영민;김종수;김상범
    • 한국산학기술학회논문지
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    • 제19권8호
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    • pp.552-561
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    • 2018
  • 화석연료의 고갈과 환경문제를 대응하기 위한 대체에너지 중 재생가능하고 탄소중립(Carbon-neutral)자원인 바이오매스 (Biomass)를 연료로 이용하는 연구가 진행되고 있다. 바이오매스를 사용하는 대부분의 에너지 생산 시스템은 열화학전환방법이 대표적이다. 이 가운데 가스화 기술을 이용해 합성가스 (syngas)를 생산해 보일러나 엔진 등에 적용하여 열과 전기를 생산한다. 하지만 합성가스 (syngas)를 생산하는 과정에서 타르 (tar)가 발생되며 낮은 온도에서 응축되기 때문에 배관 및 엔진 등에 막힘 현상을 일으켜 공정 효율을 감소시키는 문제를 야기한다. 타르를 제거하기 위해 대부분의 가스화 공정에서 물을 이용한 wet scrubber를 사용하고 있는데 효율이 낮은 문제점이 있다. 이에 본 연구에서는 물과 oily material (soybean oil, waste cooking oil, mineral oil)을 이용하여 제거효율이 높은 순으로 나타내자면 Soybean oil>Waste Cooking Oil>Mineral oil>Water 순서로 나타났고 제거효율은 각각 약 97%, 약 70%, 약 63%, 약 30%의 효율을 보여주었으며 식물성 오일 종류인 soybean oil을 사용하였을 때 타르 제거 효율이 가장 높았다.

Role of FT-IR in Assessing Lubricant Degradation - A Study on Palm Oil Methyl Ester Blended Lubricant

  • Maleque, M.A.;Masjuki, H.H.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.351-352
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    • 2002
  • In this paper, studies were made on the palm oil methyl ester (POME) added lubricants using FT-IR for monitoring oil degradation. In order to assess the degradation characteristics of POME added lubricant by FT-IR, static oxidation test was conducted using three different blended lubricants (viz, zero percent POME, five percent POME and ten percent POME with mineral-based oil) for 280 hrs. The oxidation temperature was set at $140^{\circ}C$. FT-IR quantitative data indicate an increased in oxidation products which was formed from 10% POME added lubricants after 280 hrs of oxidation test. The 5% POME added lubricant and mineral-based lubricant (without POME) showed less oxidation product after the test. From the FT-IR spectrum analysis of the oxidized oils it could be concluded that 5% POME can improve the performance of mineral-based oil by forming protective films.

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Suitability of Palm Based Oil as Dielectric Insulating Fluid in Transformers

  • Azis, Norhafiz;Jasni, Jasronita;Kadir, Mohd Zainal Abidin Ab;Mohtar, Mohd Nazim
    • Journal of Electrical Engineering and Technology
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    • 제9권2호
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    • pp.662-669
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    • 2014
  • Mineral oil has been widely used as dielectric insulating fluid in transformers due to its excellent performance in-service. However, there are few issues with mineral oil such as it has poor biodegradability and could contaminate the environment if a spillage occurs. With the increasing tight regulation on safety and environment, alternative fluids for mineral oil are currently being investigated and among the suitable candidate is the vegetable oil. There are different types of vegetable oils and one of them is the palm based oil. At the moment, extensive research works are carried out to examine its feasibility to be applied in transformers. This paper will review the previous research works that were carried out to examine the suitability of palm based oil as dielectric insulating fluid in transformers. The physical and chemical properties of palm based oil are studied based on viscosity, acidity, oxidation stability and flash point. Next, the electrical characteristics of palm based oil are examined based on AC breakdown voltage, relative permittivity, dissipation factor and partial discharge.

중질유 오염토양의 생물학적 처리에 있어 amendments의 효과 (Effects of Organic Amendments on Heavy Mineral Oil Biodegradation)

  • 이상환;김을영;최호진
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제12권5호
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    • pp.54-63
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    • 2007
  • 중질유로 오염된 토양의 생물학적 정화에 있어 amendment의 처리효과를 보고자 포장에서 pilot 규모로 105일간 실험을 수행하였다. 실험기간 중 주기적으로 토양시료를 채취하여 유류성분과 생물학적 활성과 관련된 분석을 수행하였는데 퇴비의 처리구들에서 쌀겨+무기양분처리구에 비하여 유류성분의 분해활성이 현저하게 증가함을 확인할 수 있었다. 105일 경과 후 amendment 처리구들에서는 초기농도 $6,205{\pm}173mgkg^{-1}$$33{\sim}45%$가 소실된 반면 무처리구에서는 8%만이 분해된 것으로 나타났다. 퇴비처리구들에서 무처리구 및 쌀겨처리구에 비해서 높은 중질유 분해활성을 관찰할 수 있었는데 실험기간 중 모니터링한 생물학적 지표들 중 soil respiration, dehydrogenase, lipase, urease 등의 효소활성이 쌀겨처리구에 비해 현저하게 높은 활성이 관찰되었고 이들 미생물학적 지표들과 중질유의 분해정도 사이에는 높은 상관관계가 존재하였다(p < 0.01).

주상변압기의 절연매질인 광유의 절연파괴특성에서 분해생성물의 영향 (Effect of Decomposition Product on the Insulation Characteristics of Mineral Oil as Insulation Medium of Distribution Transformer)

  • 임동영;박숭규;박철호;김기채;이광식;최은혁
    • 조명전기설비학회논문지
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    • 제28권6호
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    • pp.52-59
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    • 2014
  • This paper deals with the effect of decomposition products which occur in breakdown of mineral oil, on the insulation characteristics of its oil. Breakdown tests in the oil were conducted by the proposed experimental methods under a quasi-uniform field and AC HV (60Hz). The breakdown voltage in the oil shows characteristics of dispersion from successive breakdowns and, it is found that there are three patterns of the decomposition products behavior at the process of breakdown progress in the oil. Finally, the breakdown voltage dispersion in the oil can be described in detail based on the behavior patterns of the decomposition products and its diffusion time.

施肥量이 油菜 無機養分 吸收 및 油質에 미치는 影響 (The Effects of the Amount of Applied Fertilizer on the Mineral Nutrient Uptake and Oil Quality in Rapes)

  • Moon, Yong Sick;Chae Kyu Lim
    • The Korean Journal of Ecology
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    • 제7권3호
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    • pp.170-176
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    • 1983
  • The results obtained from the experiments conducted to investigate Cruciferae plants in rape dependent on the amount of applied fertilizer in aspects of mineral nutrient uptake and on the effects of the composition of oil quality are as follows: Absorption of mineral nutrients in the respective pars of the plant body was high in nitorgen in the order of leaf and stem

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Washing Culture Oil이 돼지 수정란의 체외 발육에 미치는 영향 (Effect of Washing Culture Oil on In Vitro Development in Porcine Embryos)

  • 이연주;김유진;이상희;정희태;양부근;박춘근
    • Reproductive and Developmental Biology
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    • 제38권3호
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    • pp.93-98
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    • 2014
  • The objective of this study was to investigate the changes of oxidative stress and antioxidant enzyme during in vitro development with washing culture oil in porcine embryos. During the culture, the four types of culture oil such as paraffin oil with or without washing and mineral oil with or without washing were examined. The oil was washed with PZM-3 during 7 days and collected oil only. The embryos were stained with CellTracker$^{TM}$ Red, DCFDA and Hoechst 33342 to confirm the effects of the oil. As a results, Cleavage rates and total cell number were no difference among the four oil groups. However, ${\geq}16$ cell embryos were significantly different in fore type oil treatment and blastocyst rate was significantly higher washing paraffin treatment than in other group(p<0.05). Also, the expression of free radical were lower in washing paraffin oil than in other groups (p<0.05). On the other hand, the expression of glutathione were not significant different among paraffin oil with or without washing and mineral oil with or without washing, however washing paraffin oil and washing mineral groups were higher than other treatment groups. In conclusion, the washing oil was expected with positive effects on in vitro development in porcine embryos.