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Geochemical Behavior, Dispersion and Enrichment of Environmental Toxic Elements in Coaly Metapelites and Stream Sediments at the Hoenam Area, up the Taecheong Lake, Korea (대청호 상류, 회남일대에 분포하는 탄질 변성니질암과 하상 퇴적물의 환경유해원소에 관한 지화학적 거동, 분산 및 부화)

  • Lee, Chan Hee;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.30 no.3
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    • pp.209-222
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    • 1997
  • The Hoenam area, up the Taecheong lake, composed mainly of low grade coal-bearing metapelites within the Ogcheon Supergroup. These coal formations are developed discontinuously several hundred meters and swelling from 10 to 300 cm along the host metapelites. Although the formations have been mined for coal, but already mined out, and the formations were higher content (mean value of 42 samples) of environmental toxic elements as As (13 ppm). Ba (1.81 wt. %), Cd (2 ppm), Cr (188 ppm), Cu (87 ppm), Mo (214 ppm), Pb (25 ppm), Sb (3 ppm), Se (12 ppm), U (55 ppm), V (2124 ppm) and Zn (234 ppm) than the host metapelites and the NASC. The Al, Ti, Mg, K and Na contents in stream sediments derived from the Hando and Bugook mine area were highly concentrations than the samples from the Samseongjeil mine area. The mean value (wt. %) of Fe (10.07), Mn (0.15), Ca (0.84), P (0.18) and Ba (0.77) influenced by the Samseongjeil mine were higher than the other mine drainage sediments. The mean content (ppm) of environmental toxic elements in drainage sediments from the Samseongjeil mine were taken As (2083), Cu (447), Mo (202), Ni (720), Pb (42), U (250), V (1070) and Zn (2632), which are extremely high concentrations against NASC and EPA. Characteristics of elemental behavior and dispersion of the all toxic elements are the same as increased with increasing U, V, and Cu. Rare earth elements in the sediments are enriched with LREE (La, Ce and Nd) from the drainage on strong concentration of toxic elements. The pH of stream water is neutral, but pH of the sediments ranged from 4.92 to 6.93 (mean 6.22), those are slightly acid in the Hando mine area. Major elements in the host rocks at the Hoenam area are mostly depleted especially Ca, excepting Ti and Ba, normalized with NASC. The sediments were highly enriched of Ti, Fe, Mg, Mn and Ba, but depleted of Al, K, Ca, Na and P on the basis of host rocks and NASC. Minor and environmental toxic elements in the host rocks were strongly enriched all elements (As, Cd, Mo, Se, D, V and Zn), excepting Co, Ni and Sr. Enrichment index (mean value) about toxic elements (As, Cr, Cu, Fe, Ni, Pb and Zn) of the sediments in this area have taken 41.35 (Hando mine drainage; 2.73, Samseongjeil mine drainage; 113.14 and Bugook mine drainage; 8.19), those are seriously contaminated by environmental toxic elements.

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Studies on Purification of Mine Drainage with NaOCl and $H_2O_2$ (산화제 NaOCl와 $H_2O_2$를 이용한 광산배수 정화에 관한 연구)

  • Choi, Seung-Won;Jang, Yun-Deug;Kim, Young-Hun;Kim, Jeong-Jin
    • Economic and Environmental Geology
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    • v.43 no.1
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    • pp.21-31
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    • 2010
  • Mine and leachate waters were collected from the Okdong mine for study on reaction with oxidizing agents such as NaOCl and $H_2O_2$. The pH and EC of the mine and leachate waters are 5.77, 831 uS/cm, and 6.38, 1920 uS/cm, respectively. The concentrations of Mg, Mn, and Zn are 23.25 mg/l, 14.90 mg/l, and 22.99 mg/l for the mine water and 98.75 mg/l, 3.38 mg/l, and 6.16 mg/l for the leachate water. The concentrations of Mg, Mn and Zn decreased after the reaction with the oxidizing agents and mine water. The concentrations of Mg, Mn and Zn rapidly decreased when oxidizing agents increased. The saturation indices that were computed by visual MINTEQ for initial mine and leachate water were undersaturated with Mg, Zn and Mn compounds. The precipitates after the reaction with the oxidizing agents are composed mainly of mangano-calcite[(Mn, Ca)$CO_3$] with small amount of calcite-magnesian and calcite.

Environmental Geochemistry and Heavy Matel Contamination of Ground and Surface Water, Soil and Sediment at the Kongjujuil Mine Creek, Korea (공주제일광산 수계에 분포하는 지하수, 지표수, 토양 및 퇴적물의 환경지구화학적 특성과 중금속 오염)

  • 이찬희
    • Economic and Environmental Geology
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    • v.32 no.6
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    • pp.611-631
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    • 1999
  • Enviromental geochemisty and heary metal contamination at the Kongjueil mine creek were underaken on the basis of physicohemical properties and mineralogy for various kinds of water (surface, mine and ground water),soil, precipitate and sediment collected of April and December in 1998. Hydrgeochemical composition of the water samples are characterized by relatively significant enricant of Ca+Na, alkiali ions $NO_3$ and Cl inground and surfore water, wheras the mine waters are relatively eneripheral water of the mining creek have the characteristics of the (Ca+Mg)-$(HCO_3+SO_4)$type. The pH of the mine water is high acidity (3.24)and high EC (613$\mu$S/cm)compared with those of surface and ground water. The range of $\delta$D and $\delta^{18}O$ values (relative to SMOW) in the waters are shpwn in -50.2 to -61.6% and -7.0 to -8.6$\textperthousand$(d value=5.8 to 8.7). Using computer program, saturation index of albite, calcite, dolomite in mine water are nearly saturated. The gibbiste, kaolinite and smectite are superaturated in the surface and ground water, respectively. Calculated water-mineral reaction and stabilities suggest that weathing of silicate minerals may be stable kaolinite owing to the continuous water-rock reaction. Geochemical modeling showed that mostly toxic heavy metals may exist larfely in the from of metal-sulfate $(MSO_4\;^2)$and free metal $(M^{2+})$ in nmine water. These metals in the ground and surface water could be formed of $CO_3$ and OH complex ions. The average enrichment indices of water samples are 2.72 of the groundwater, 2.26 of the surface water and 14.15 of the acid mine water, normalizing by surface water composition at the non-mining creek, repectively. Characteristics of some major, minor and rate earth elements (Al/Na, K/Na, V/Ni, Cr/V, Ni/Co, La/Ce, Th/Yb, $La_N/Yb_N$, Co/Th, La/Sc and Sc/Th) in soil and sediment are revealed a narrow range and homogeneous compositions may be explained by acidic to intermediate igneous rocks. And these suggested that sediment source of host granitic gneiss colud be due to rocks of high grade metamorphism originated by sedimentary rocks. Maximum concentrations of environmentally toxic elements in sediment and soil are Fe=53.80 wt.% As=660, Cd=4, Cr=175, Cu=158, Mn=1010, Pb=2933, Sb=4 and Zn=3740 ppm, and extremely high concentrations are found are found in the subsurface soil near the ore dump and precipitates. Normalizing by composition of host granitic gneiss, the average enerichment indices are 3.72 of the sediments, 3.48 of the soils, 10.40 of the precipitates of acid mine drainage and 6.25 of the soils near the main adit. The level of enerichment was very severe in mining drainage sediments, while it was not so great in the soils. mineral composition of soil and sediment near the mining area were partly variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. reddish variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. Reddish brown precipitation mineral in the acid mine drainage identifies by schwertmanite. From the separated mineralgy, soil and sediment are composed of some pyrite, arsenopyite, chalcopyrite, sphalerite, galena, malachite, goethite and various kinds of hydroxied minerals.

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Study on the ICT Device Safety System Application Examples in Mines (광산에서의 ICT 장비 활용 및 안전시스템 운용 사례 연구)

  • Kim, Seung-Jun;Ko, Young-Hun;Kim, Jung-Gyu;Seo, Man-Keun;Kim, Jong-Gwan
    • Tunnel and Underground Space
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    • v.32 no.3
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    • pp.194-202
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    • 2022
  • An increased number of cases have occurred in applying ICT technology in the resource development field due to factors such as safety, eco-friendliness, and low cost since the 2000s. In Korea, the 2nd mining master plan specified the significance of converging the full cycle of mining and ICT, while the 3rd mining master plan highlighted ICT and smart mining such as supporting the supply of an ICT mining device and introducing demonstrational smart mining. This study introduces the application of an ICT device and safety system operation in the Jangseong underground mine of Korea Cement Co., Ltd. Currently, Jangseong mine combines two different kinds of 3D equipment including the handheld 3D scanner and multi-station that provides both the measurement and 3D scanning to perform a 3D measurement of the mine. Taken from the 3D measurement of the mine, it is now possible to identify any hazardous areas and abnormalities in different directions and analyze the safety of the crown pillar between two stopes in different level. Besides, the real-time location tracking and communications system have established highly efficient rescue and evacuation plans to effectively deal with any accidents in the mine.

Numerical Analysis on Effective Countermeasure for Ground Subsidence due to Mining Hazard (광해로 인한 지반침하의 효율적인 보강방안에 관한 수치해석)

  • Hong, Won-Pyo;Lee, Jae-Ho;Hur, Se-Young
    • Journal of the Korean Geosynthetics Society
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    • v.6 no.4
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    • pp.7-13
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    • 2007
  • When the structure such as roadway, railway are constructed on abandoned coal mine area, the countermeasure to prevent settlements is necessary. In this study, numerical analyses are performed to evaluate the effect of the various countermeasures. As a results, the method which is filling the coal mine is more effective than that of reinforcing the ground above the coal mine. The ground settlement decreases hyperbolically with increasing the filling ratio of the coal mine. Also, the relationship between the filling ratio and the settlement reduction ratio is discussed precisely.

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Adaptation of Betula schmidtii Seedling in Coal-mine Field with Different Sewage Sludge Treatment Methods

  • Han, Sim-Hee;Lee, Jae-Cheon;Oh, Chang-Young;Kim, Pan-Gi
    • The Korean Journal of Ecology
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    • v.28 no.4
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    • pp.189-192
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    • 2005
  • We tested the field adaptation of Betula schmidtii on the abandoned coal-mine soil with sludge amendment methods for promoting physiological activity of B. schmidtii seedlings under several environmental stress. Sewage sludges were amended to coal-mine soil with B. schmidtii seedlings which grown in the mixture of artificial soil and composted sludge soil before transplanting (before-fertilized treatment, BF) and fertilized with composted sludge after transplanting (after-fertilized treatment, AF). The percent of establishment of seedlings for AF (80.7%) was lower than that for BF (92.7%). Nitrate reductase activity and photosynthetic pigment content were higher in AF than in BF, but malondialdehyde (MDA) content and superoxide dismutase (SOD) activity were lower in AF than in BF These results represent that after-fertilized seedlings increase resistance against physiological stress at field condition using nitrogen source of composted sludge. On the contrary, before-fertilized seedlings were susceptible to environmental stress on abandoned coal-mine soil by exhausting of nitrogen source from composted sludge.

Neutralization Processes of Acid Mine Drainage (AMD) from the Abandoned Donghae Coal Mine (동해 폐탄광 일대 산성 광산폐수의 중화처리)

  • 김정엽;전효택;오대균
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.38-47
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    • 1995
  • This study was carried out in order to provide basic information on neutralization processes of acid mine drainage (AMD) from the abandoned Donghae coal mine in the Samchuk coalfield. The contents of potentially toxic elements in stream water increase and the level of pH decreases during dry season. Hydrated lime is turned out to be the best neutralizer of the acid mine water from a technical and economic viewpoint. From the results of equilibrium calculation, Fe and Al could be precipitated as FeOOH, and Al(OH)$_3$, respectively, in the neutralization process. The sites of holding basins necessary to equalize quantity and quality of AMD are recommended by GIS analysis, and the capacities of holding basins are determined by hydrological calculation.

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Evaluation of Heavy Metal Contamination in Geochemical Environment around the Abandoned Coal Mine - With special reference to geochemical environment around the Imgok Creek in the Gangreung Coal Field - (폐석탄광 주변 지구화학적 환경의 중금속 오염 평가 - 강릉탄전 임곡천 일대를 중심으로 -)

  • Chon, Hyo-Taek;Kim, Ju-Yong;Choi, Si-Young
    • Economic and Environmental Geology
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    • v.31 no.6
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    • pp.499-508
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    • 1998
  • The Imgok Creek is located in the Gangreung coal field, which has been known that sulfides are more abundant than other coal fields in Korea, and it has been severly contaminated by acid mine drainage (AMD) discharging from the abandoned coal mines, such as the Youngdong, the Dongduk and the Waryong coal mines. The purposes of this study are to synthetically assess the contamination of natural water, stream sediment and cultivated soils, and to provide the basic data for AMD treatment. Geochemical samples were collected in December, 1996 (dry season) and April, 1997 (after three day's rainfall). TDS of the Youngdong mine water was remarkably higher than those of other mine waters. In the Imgok Creek, concentrations of most elements, except Fe decreased with distance by dilution caused by the inflow of uncontaminated tributaries. From the results of NAMDI and $I_{geo}$ calculation, the Youngdong coal mine was the main contamination source of the study area. Groundwater pollution was not yet confirmed in this study and the paddy and farm land soils were also not yet contaminated by mining activity based on the pollution index ranging from 0.27 to 0.47.

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Mineralogy of Ferrihydrite and Schwertmannite from the Acid Mine Drainage in the Donghae Coal Mine Area (동해탄광일대의 산성광산배수에서 침전된 페리하이드라이트와 슈워트마나이트에 대한 광물학적 연구)

  • Kim, Jeong-Jin;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.2
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    • pp.191-198
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    • 2003
  • The ochreous precipitates, reddish brown and brownish yellow in color, are pre- cipitated in the stream bottom of acid mine drainage (AMD) in the Donghae coal mine area. X-ray diffraction analysis shows that the reddish brown precipitate consists mainly of ferrihydrite with small amount of goethite, while the brownish yellow precipitate of schwertmannite. Thermal experiments show that ferrihydrite and schwertmannite partially convert to poorly-crystallized hematite at $400^{\circ}C$ and to well-crystallized hematite at $700^{\circ}C$.

Environmental Assessment of Vitrified Mine Tailing Aggregate Using Various Leaching Methods (고농도 중금속 함유 광미를 이용한 유리화 처리 골재의 장기 용출특성에 따른 환경안전성 평가)

  • Lee, Sang-Woo;Chun, Sa-Ho;Lee, Ki-Kang;Lee, Sanghoon
    • Journal of Environmental Impact Assessment
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    • v.16 no.1
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    • pp.35-43
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    • 2007
  • Vitrified aggregates obtained by using mine tailings were evaluated using various leaching methods to assess their environmental safety. The leaching tests in this study include continuous batch leaching, Dutch availability leaching, pH-stat and tank diffusion test as well as TCLP (Toxicity Characteristic Leaching Procedure), which is commonly adopted. Vitrification technique has successfully been applied treating some solid wastes containing high level of heavy metals, such as EAF (Electric Arc Furnace) dust and mine tailings. The potentially most leachable element among trace metals was As and theoretically about 7% of total concentrations in the aggregate can be released under extreme condition. Zinc was leached about 4% and the other trace metals including Cd, Cr and Pb were hardly released from the vitrified mine tailing aggregate.