• Corrosion Science and Technology
• /
• v.21 no.6
• /
• pp.445-453
• /
• 2022

SiO_x was prepared from a mixture of Si and SiO₂ via high-energy ball milling as a negative electrode material for Li-ion batteries. The molar ratio of Si to SiO₂ as precursors and the milling time were varied to identify the synthetic condition that could exhibit desirable anode performances. With an appropriate milling time, the material showed a unique microstructure in which amorphous Si nanoparticles were intimately embedded within the SiO₂ matrix. The interface between the Si and SiO₂ was composed of silicon suboxides with Si oxidation states from 0 to +4 as proven by X-ray photoelectron spectroscopy and electrochemical analysis. With the addition of a conductive carbon (Super P carbon black) as a coating material, the SiO_x/C manifested superior specific capacity to a commercial SiO_x/C composite without compromising its cycle-life performance. The simple mechanochemical method described in this study will shed light on cost-effective synthesis of high-capacity silicon oxides as promising anode materials.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.57 no.3
• /
• pp.280-285
• /
• 2012

This study was conducted to establish proper milling condition and harvesting time for improving the milling recovery of head foxtail millet grain. Brown foxtail millet recovery and the percentage of head foxtail millet recovery were significantly different according to the number of hulling and milling time. Also, the interaction of these factors had influence on brown foxtail millet recovery and the percentage of head foxtail millet recovery. To improve the percentage of head foxtail millet recovery, it was effective to hull grain twice and mill for 1.30 minute. 1000-grain weight of brown foxtail millet, brown foxtail millet recovery, hardness of brown foxtail millet, milling recovery, and the percentage of milling recovery of head foxtail millet grain were significantly different according to harvesting day after heading. For improving the ratio of ripened grain and the percentage of recovery of head foxtail millet, it is recommended to harvest 45 days (accumulated temperature : $1,148^{\circ}C$) after heading (DAH) in early maturing Hwangkeumjo, 50 DAH (accumulated temperature : $1,150^{\circ}C$) in mid-late maturing Samdamae and Kyeongkwan1, and 55 DAH (accumulated temperature : $1,168^{\circ}C$) in late maturing Samdachal.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.17 no.8
• /
• pp.2001-2011
• /
• 1993

This study deals with the machining of sculptured surfaces on 5-axis CNC milling machine with end mill cutter. The study (I) has the following contents. In 5-axis CNC milling, CL-data consist of CC-data and cutter axis direction vector at the CC-point. Thus, in machining of the sculptured surface on 5-axis CNC milling machine, determination of the direction vector of the milling cutter is very important. The direction vector is obtained by the fact that bottom plane of the milling cutter must not interfere with the free-form surface being machined. The interference is checked by the z-map method which can be applied in all geometric types of the sculptured surfaces. After generating NC part programs from 5-axis post-processing algorithms, sculptured surfaces were machined with 5-axis CNC milling machine (CINCINNATI MILACRON, 20V-80). From these machining tests, it was shown that the machining of the free-form surfaces on 5-axis CNC milling machine with the end mill has smaller cusp heights and shorter cutting time than on 3-axis CNC milling machine with the ball-end mill. Thus, 5-axis CNC end milling was effective machining method for sculptured surfaces. The study (II) deals with the prediction of cusp height and the determination of tool path interval for the 5-axis machining of sculptured surfaces on the basis of study(I).

• 연구논문집
• /
• s.34
• /
• pp.121-129
• /
• 2004

The influence of powder size and ball-milling time on the magnetic properties of $Fe_{73}Si_{16}B_7Nb_3Cu_1$ nanocrystalline alloy powder was investigated. Flake-shaped powders were produced by pulverizing the ribbons annealed at $550^\circC$ for 1 hour. The powders were classified and consolidated into core shapes at a pressure of 18ton/$cm^2$. The initial permeability at 100kHz of the inductor core produced using $53-75\mum$ powders showed the highest value although its consolidated density showed the lowest one. The reason for the result is due to the cracking of the particles larger than $75\mum$ during the consolidation process. The ball-milling of powders for 2-4 hours improved the consolidation density and the initial permeability of the cores. The intrinsic coercivity of the powder decreased as well, resulting from the stress relief of the powder by a short-time milling.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2000.11a
• /
• pp.767-770
• /
• 2000

In order to reduce lean-time and cost, recently the technology of Rapid Prototyping and Manufacturing(PR/M) has been used widely. So various RP/M methods have been developed and these systems commercialized several years ago. The machining process is one of these methods. It also offers advantages such as precision and versatility. But there are some considerations during machining. The most important problem among them is the fixturing. So we have to overcome the limitation because the fixturing time is depend on the complexity of geometry to be machined. In this paper, we have developed the fixturing technique using filling process that can be widely useful for rapid products within a short time. So we have carried out some kinds of rapid products such as plastic knob and metal fan using our fixturing process. In fixturing step, the filling material might chosen a resin or a alloy according to wether the work material is plastic or metal respectively. Also we developed the set-up equipment attachable on the table of the milling machine that provided practicable quality during a series of machining operations, named by two step milling process.

• Journal of Technologic Dentistry
• /
• v.29 no.1
• /
• pp.49-57
• /
• 2007

This study was to add crushed frit with different grain sizes to 3Y-TZP so that it could determine the mechanical properties depending on sintering temperature. In this study, 3 types specimens were prepared in powder with respective additions of 20wt.% frit, which was sized through 24-, 48- and 72-hour ball milling with zirconia. Then, sintered pellets were tested in experiments under the temperature variations for different compositions. As a result, this study came to the following findings: 1. It was found that the higher sintering temperature and the longer ball milling time of frit led to the higher sintered density. 2. Bending strength tended to increase with higher sintering temperature and longer ball milling time of frit. 3. Hardness tended to increase with higher sintering temperature and longer ball milling time of frit. 4. However, it was found that fracture toughness didn't vary significantly depending on sintering temperature. From these findings, it was concluded that the smaller frit grain size and the narrower particle size distribution of frit lead to the better mechanical properties.

• Journal of Magnetics
• /
• v.14 no.4
• /
• pp.155-160
• /
• 2009

This study examined the effects of a decrease in thickness of magnetic alloy flakes on the electromagnetic wave absorption characteristics of nanocrystalline $Fe_{73.5}Cu_1Nb_3Si_{15.5}B_7$ (at.%) alloy flakes/polymer composite sheets available for a quasi-microwave band. The thickness of FeCuNbSiB alloy flakes decreased to 1-2 $\mu$m with increasing milling time up to 24 h, and the composite sheet including alloy flakes milled for 24 h exhibited considerably enhanced power loss properties in the GHz range compared to the sheets having non-milled alloy powders. Although a considerable increase in loss factor upon milling was observed in the narrow frequency range of 4-6 GHz, there was no correlation between the complex permeability and flake thickness. However, the complex permittivity increased with increasing milling time, and there was good agreement between the milling time and the frequency dependences of the complex permittivity and power loss.

• Journal of the Korean Electrochemical Society
• /
• v.13 no.3
• /
• pp.169-174
• /
• 2010

Sulfur cathodes were prepared by ball milling method with different types of electronic conductors and binders in different ball milling time. The sulfur cell with a cathode prepared in 45 min ball milling time gave an initial discharge capacity of 794mAh/g with Super-P as an electronic conductor and poly(vinylidene fluoride) as a binder. The cathode with multi-walled carbon nanotube as an electronic conductor showed an initial discharge capacity of 944 mAh/g and a discharge capacity of 300 mAh/g after 20 cycles. Cathodes with poly(ethylene oxide) and poly(vinylidene fluoride) as binders showed different cycle performance.

• Proceedings of the Korean Society of Crop Science Conference
• /
• 2022.10a
• /
• pp.314-314
• /
• 2022

In the production of rice flour, wet milling is a method of milling rice after soaking it in water, and it takes a lot of time and cost from milling to drying. To overcome this problem, the floury type rice was developed for dry milling and it is known to have round starch granules, low content of damaged starch after milling, and a starch structure similar to wheat. Because of its unique properties different from normal rice, it is necessary to research on processing and characteristics of floury-type rice to expand its utility in the food industry. Therefore, this study aimed to prepare the pregelatinized floury type rice (Baromi2) by autoclave and investigate their physicochemical properties. As the heat treatment time increased, the brightness decreased from 83.8 to 76.8, however, both redness and yellowness increased from 0.57 to 4.5 and from 14.58 to 21.13, respectively. Despite of same treatment time, soaking in water (10 min) before autoclaving increased the solubility and swelling power of Baromi2 over 2 times. The peak viscosity of native Baromi2 was over 2000 RVU, on the other hand, there was a significantly decrease to less than 1000 RVU of pregelatinized Baromi2. Heat treatment without immersion caused partial gelatinization of starch, resulting that some starch granules maintaining their integrity. Whereas there were no starch granules in heat treatment with soaking in water due to complete gelatinization. This study would be helpful to the suggestion of using heat-treated floury-type rice as an intermediate material in the food industry in the future.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.17 no.1
• /
• pp.39-45
• /
• 2004

Fine LaAlO$_3$ powders wore successfully synthesized from La$_2$O$_3$ and ${\gamma}$ $Al_2$O$_3$ powders milling for 10∼50 hours via the high energy milling technique (mechanochemical method) in room temperature and air. The particle size of LaAlO$_3$ powder were estimated from XRD patterns and SEM images to be 160∼180 nm. The LaAlO$_3$ ceramics arc derived for the synthesized powders (milling for 10, 30 and 50 hours) by sintering at 140$0^{\circ}C$ and 150$0^{\circ}C$. The micrographs of grains showed an agglomeration and the degree of agglomeration increased with the milling time. The LaAlO$_3$ made from synthesized powders milling for 50 hours can be sintered to 99.5％ of theoretical density at 150$0^{\circ}C$ for 1 hour. These ceramics exhibits a dielectric constant of 20, a dielectric loss of 0.0003 and a temperature coefficient of capacitance of 15 ppm/$^{\circ}C$ at 1 MHz.