• 한국건설순환자원학회논문집
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• 제11권1호
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• pp.48-54
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• 2023

본 연구에서는 금속성분을 다량 함유한 전기로산화슬래그(EOS)를 골재로 활용한 콘크리트에 도전성이 높은 카본계 재료를 혼입하여 현장적용이 가능한 EMP 차폐 콘크리트의 최적배합을 도출하고자 기초적인 물성과 두께별 EMP 차폐성능을 평가하였다. 평가결과 슬럼프는 카본섬유(CF)의 혼입량이 증가할수록 저하, 밀드카본(MCF) 혼입시 증가하는 것을 확인할 수 있었다. 압축강도는 EOS가 NA에 비해 강도를 증진시키는 것을 확인할 수 있었으며, CF 및 MCF 혼입시 강도가 저하되는 것을 확인할 수 있었다. EMP 차폐 측정결과 두께가 증가할수록 차폐율이 증가하였으며, 도전성 재료의 첨가량보다 도전성 재료의 종류 및 시험체의 두께가 차폐율 증가에 영향력이 더 큰 것을 확인할 수 있었다. 종합적으로 비교평가를 진행한 결과 EMP 차폐 콘크리트 배합으로 EOS CF 0.2가 적합한 것으로 사료된다.

• Bulletin of the Korean Chemical Society
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• 제31권5호
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• pp.1331-1335
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• 2010

A novel spherical carbon composite material, in which nanosized disordered carbons are dispersed in a soft carbon matrix, has been prepared and investigated for use as a potential anode material for lithium ion batteries. Disordered carbons were synthesized by ball milling natural graphite in air. The composite was prepared by mixing the ball-milled graphite with petroleum pitch powder, pelletizing the mixture, and pyrolyzing the pellets at $1200^{\circ}C$ in an argon flow. The ballmilled graphite consists of distorted nanocrystallites and amorphous phases. In the composite particle, nanosized flakes are uniformly distributed in a soft carbon matrix, as revealed by X-ray diffractometer (XRD) and transmission electron microscopy (TEM) experiments. The composite is compatible with a pure propylene carbonate (PC) electrolyte and shows high rate capability and excellent cycling performance. The electrochemical properties are comparable to those of hard carbon.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.651-654
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• 2004

In the research for giving self-diagnosing capability, conductive mortar intermixed with cokes and milled carbon fiber was produced. Then after examining change in the value of electric resistance dsand AE characteristics before and after the occurrence of cracks at each weight-stage, the correlations of each factors were analyzed.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2004년도 International Symposium on Powder Materials and Processing
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• pp.32-32
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• 2004

• 한국정밀공학회지
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• 제23권3호
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• pp.171-178
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• 2006

The sonication mettled is widely used with surfactants to suspend individual single-walled carbon nanotubes in solution, and it is well known that sonication-induced tube cutting occurs. Recently, it is found out that ultrasonicated nanotubes yield simultaneous separation by tube length and diameter. Nanotubes that have been cut shortest possess the greatest enrichments of large-diameter species. In this study, single-walled carbon nanotubes are cut using a ball milling method. Similar fracture behavior is observed fur the ball milled nanotubes: i.e., large diameter tubes are cut shorter. The ability to separate carbon nanotubes by diameter and length will contribute to tile development of nanotube-based applications.

• 대한화학회지
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• 제60권5호
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• pp.299-309
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• 2016

In this study, the physicochemical and electrochemical properties of carbon nanomaterials and synthesized nano-carbon/Si composites were studied. The nano-carbon/Si composites were ball-milled to a nano size and coated with pyrolytic carbon using Chemical Vapor Deposition (CVD). They were then finely mixed with respective nano-carbon materials. The physicochemical properties of samples were analyzed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), Raman spectroscopy, X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and surface area analyzer. The electrochemical characteristics were investigated using the galvanostatic charge-discharge and cyclic voltammetry (CV) measurements. Three-electrode cells were fabricated using the carbon nanomaterials and nano-carbon/Si composites as anode materials and LiPF₆ and LiClO₄ as electrolytes of Li secondary batteries. Reversibility using LiClO₄ as an electrolyte was superior to that of LiPF₆ as the electrolyte. The initial discharge capacities of nano-carbon/Si composites were increased compared to the initial discharge capacities of nano-carbon materials.

• 열처리공학회지
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• 제18권1호
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• pp.29-40
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• 2005

Formation of nanocrystalline ferrite was investigated using milled powders obtained by planetary ball milling of chips, which were made by high speed mechanical cutting of a low carbon steel(0.15%C-1.1%Mn-0.01%Ti). After 4 hour milling the chips were changed to powders of $50{\mu}m$ in average size, and with increasing milling time the powders were refined to about $3{\mu}m$ for 128 hour and showed more equiaxed shapes. Nanocrystalline(nc) region appeared in the surfaces of powders milled for 1 hour, and the 4 hour milled powders were almost filled with nc region. Hardness of nc region was much higher than that of work-hardened(WH) region. With increasing milling time, ferrite and cementite in pearlite were severely deformed and lamellar spacing was decreased, and then cementites began to disappear after 4 hour milling due to dissolution into ferrite. Deformation bands formed in lightly work-hardened region showed large width and similar crystallographic orientations. Spacing of deformation bands was decreased with deformation and the layered microstructure consisting of narrow deformation bands subdivided into variously oriented small grains was formed by more deformation, and eventually this structure seemed to be evolved to the nc structure by further deformation. It is also conjectured the growth of nc ferrite grains occurred through the coalescence of nanocrystalline ferrites rather than the nucleation and growth of recrystallized grains.

• 한국분말재료학회지
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• 제12권3호
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• pp.174-178
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• 2005

This paper deals with the fabrication of titanium carbide using fine titanium hydride. The ratio of $TiH_2$ and C (Activated carbon) was 1:1 (mol) and milled in a planetary ball mill at a ball-to-powder weight ratio of 20:1. Thereafter, TGA was performed at $1400^{\circ}C$ to observe change of weight with milling time. Titanium carbide was obtained by using tempering the milled powders at $1100-1500^{\circ}C$. The microstructures of titanium carbide as well as the change of the lattice parameters and particle size have been studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

• 한국입자에어로졸학회지
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• 제5권4호
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• pp.153-158
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• 2009

Tungsten carbide powder was fabricated with carbothermal reaction by pulsed electric current flowing in compact of tunsten oxide and carbon. The mixed powder of tunsten oxide and carbon was ball-milled into ultrafine powders. The mixed powder of tungsten oxide and carbon was put into carbon mold and heat-treated at $1050{\sim}1200^{\circ}C$ by pulsed electric current flowing. The formation of tungsten carbide powder could be achieved by heat treatment at $1200^{\circ}C$ for 10 minitues.

• Progress in Superconductivity
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• 제10권1호
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• pp.17-22
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• 2008

We have examined the effect of ball-milling on the superconducting properties of $MgB_2$ doped with C. The ball-milling of pre-reacted $MgB_2$ powder was carried out in dry or wet state using C or diethylenetriamine ($C_{4}H_{13}N_3$) as additives. The diethylenetriamine, whose chemical formula contains no oxygen, was chosen to avoid an excess oxidation during doping. The superconducting transition temperature (Tc) of the ball-milled or doped $MgB_2$ powders was only slightly smaller than that of undoped $MgB_2$. The critical current density (Jc) of the highly ball-milled $MgB_2$ was higher than that of C-doped $MgB_2$. The addition of diethylenetriamine was detrimental to Jc, although Tc was almost unchanged.