• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.873-875
• /
• 2009

Middle distillate was produced by the hydrocracking of F-T wax on the zeolite catalysts. Novel metal loaded zeolite catalysts had good performance for hydrocracking of F-T wax. 2 wt.% Platinum loaded H-Y zeolite catalyst showed the highest selectivity of middle distillate and conversion of F-T wax. H-Y zeolite had more strong acidity site and large pore than that of another zeolite catalyst. So, H-Y zeolilte catalyst showed the best activity for hydrocracking of F-T wax.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.114.2-114.2
• /
• 2010

Fisher-Tropsch 반응을 통하여 생성되는 왁스는 황 또는 질소 성분을 포함하지 않으며 또한 방향족 및 중금속 성분이 없기 때문에 청정 수송유로써 사용이 가능하다는 장점이 있다. 그러나 Fisher-Tropsch 왁스는 그 분자량이 매우 큰 사슬형 탄화수소이기 때문에 수소첨가 분해반응을 통하여 중질유 range의 탄소수를 갖는 탄화수소로의 전환 기술이 반드시 필요하다. 이러한 수소첨가 분해반응에 사용되는 촉매는 강한 산점을 지니고 있는 양이온 교환 지르코니아가 대표적이라 할 수 있는데 최근 들어 강한 산점과 높은 산밀도, 그리고 기공의 모양과 크기에 따라 특정 반응이 제어되거나 활성화되는 형상선택성을 가지고 있기 때문에 다양한 반응에 촉매로 사용되는 제올라이트에 Pt 등의 귀금속을 담지한 촉매를 사용하여 Fisher-Tropsch 왁스의 전환율 및 중질유분의 선택도를 높이는 기술에 대한 연구가 활발히 진행되고 있다. 따라서 본 연구에서는 다양한 제올라이트 촉매에 귀금속을 담지하여 촉매를 제조하고 1L 급 고압 배치형 반응기를 이용하여 Fisher-Tropsch 왁스의 수소첨가 분해반응에 의한 중질유 제조 실험을 수행하고 그 결과를 고찰하였다.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 1986.06a
• /
• pp.10-20
• /
• 1986

I. 윤활기유 제조시설소개 개요 1) 고급 윤활기유(HVI)생산공장으로서 그간 수입에만 의존하던 최고급 품질의 기유를 국내 수요업체에 안정공급 2) 세계 최신 공정인 Gulf Lube Oil Hydrotreating Process Type III (수소첨가 개질공정)채택 3) 국내 최초일뿐 아니라, 세계에서도 일본, 카낟에 이어 3번째로 건설 1. 고품질 제품 생산-고점도 지수, 산화안정성 및 열안정성 우수, 잔류탄소분, 윤황분, 질소분 극소, 방향족 성분 및 회분 극소, 색상 양호 2. 첨가제(특히 산화방지제 및 점도 지수 향상제)사용효과 상승으로 완제품 생산시 생산비 감소 3. 동일 VI 제품 생산기준 수율이 높음 - Hydrocarbon Structure 변화로 원료 유중 부적합성분의 윤활기유화 4. Severity 조절로 Production Mode 변경 용이 5. 양질의 부산물 생산 - HDT Naphtha, Middle distillate 6. 용제 추출기유는 원유종류 및 성상에 따라 제품특성이 결정되나, 사용가능 원유가 다양 하면서도 제품특성 및 품질이 일정함.

• Journal of Energy Engineering
• /
• v.16 no.2
• /
• pp.58-63
• /
• 2007

In recent years, the technologies for the production of synthetic fuel from natural gas have been attracting considerable interest because of high oil prices. While oil prices remaining high, GTL (Gas-to-Liquids) technology would provide an attractive option for utilizing gas resources. Furthermore, GTL fuels contain almost zero sulfur and low aromatics and have a very high cetane so that they are estimated to be environmentally friendly diesel fuels able of meeting the advanced fuel specifications of the 21st century. GTL process generally consists of three primary steps: synthesis gas production from natural gas reforming, hydrocarbon production from synthesis gas by Fischer-Tropsch (F-T) synthesis, product upgrading by hydrocracking/hydroisomerization. This paper presents a brief summary of GTL technology and worldwide development trend about it focusing on the reforming of natural gas and the F-T synthesis.

• Journal of the Korean Chemical Society
• /
• v.45 no.5
• /
• pp.481-490
• /
• 2001

The purpose of this study was to find out the problems on the fractional distillation experiments in the middle school science textbooks based on the 6th curriculum and to suggest an efficient experiment method for the middle school students. The first step was the classification of the experiments in 8 science textbooks according to heating apparatus and liquid mixtures. The second step was doing each experiment 3 times followed by the experimental process in the textbooks. The third step was developing the alternative experiments for solving the problems found in the second step. The heating method used in the alternative experiments were direct heating, oil bath, and heating mantle. The results of the second step showed that the direct heating experiment of branched round flask was more close to the theoretical prediction than the experiment of water bath heating of branched test tube. Also the direct heating experiment of thermally insulated branched round flask was better than the result of the experiment which was not insulated. The results of the third step showed that the experiment using heating mantle regulated heating power by observing the temperature of distillate gave the closest result to the theoretical prediction. From the above results, it is concluded that the experiment using branched test-tube with water bath heating is not adequate for the fractional distillation and an alternative experiment using insulated branched round flask with heating mantle regulated heating power during experiment is recommended.