• Title/Summary/Keyword: Microstructure properties

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Development of Branched Oligosaccharides as a Cryoprotectant in Surimi (올리고당의 수리미 냉동변성방지제로의 개발)

  • Auh, Joong-Hyuk;Lee, Kyoung-Sook;Lee, Hyeon-Gyu;Park, Kwan-Hwa
    • Korean Journal of Food Science and Technology
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    • v.31 no.4
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    • pp.952-956
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    • 1999
  • Cryoprotection of surimi by three commercial oligosaccharides (isomalto-, fructo- or galacto-, oligosaccharides) was investigated and compared with commercially used cryoprotectants (sucrose, sucrose+sorbitol). Surimis were made with oligosaccharides as cryoprotectants, and gels were prepared after 3 months of storage at $-18^{\circ}C$. After gel preparation, various physical properties (texture, water holding capacity, color, and microstructures) were measured. The gels containing oligosaccharides showed similar water holding capacities and microstructure as the commercially used cryoprotectants. They also showed similar lightness and whiteness as the commercial ones. In TPA(texture profile analysis), gels prepared with fructooligosaccharides showed highest fracturability than gets with sucrose, sucrose+sorbitol, or other oligosaccharides. These results showed a applicability of commercial oligosaccharides as a cryoprotectant in surimi processing.

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Influence of porosity and cement grade on concrete mechanical properties

  • Huang, Jiandong;Alyousef, Rayed;Suhatril, Meldi;Baharom, Shahrizan;Alabduljabbar, Hisham;Alaskar, Abdulaziz;Assilzadeh, Hamid
    • Advances in concrete construction
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    • v.10 no.5
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    • pp.393-402
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    • 2020
  • The given research focuses on examining the effect of relatively humidity (RH) and curing temperature on the hydrates as well as the porosity of calcium sulfoaluminate (CSA) cement pastes. Numerous tests, which consist of mercury intrusion porosimetry (MIP), thermosgravi metric (TG) and X-ray diffraction (XRD) were conducted. Various characterization techniques which include, scanning electron microscopy, Fourier transform microscopy along with X-ray diffraction evaluations were conducted on the samples to examine phase formation and crystallinity, morphology and microstructure along with bond formations and functional groups, respectively. During long-term study, the performance of concrete which consisted of limestone and flash-calcined was close to those from standard Portland cement concrete. Traditional classifications and methods of corrosion were widely used for the assessment of steel in concrete which may get employed to concrete which contains LC3 to recalibrate the range of polarization resistance for passitivity condition. For example, there is up to 79.5% and 146% respective flexural and compressive strengths. Moreover, they developed more advance electrical and thermo-mechanical performance with a substantial reduction in absorption of water of close to 400%. These advantages allow this research crucial to evaluate how these methods can be applied. Additionally, the research evaluates developed and more advanced cement preservation and repair techniques. The conclusion suggests concerted efforts by various stakeholders such as policy makers to enable low-carbon rates.

Vapor Permeation Characteristics of TiO2 Composite Membranes Prepared on Porous Stainless Steel Support by Sol-Gel Method

  • Lee, Yoon-Gyu;Lee, Dong-Wook;Kim, Sang-Kyoon;Sea, Bong-Kuk;Youn, Min-Young;Lee, Kwan-Young;Lee, Kew-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.687-693
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    • 2004
  • Composite membranes with a titania layer were prepared by soaking-rolling method with the titania sol of nanoparticles formed in the sol-gel process and investigated regarding the vapor permeation of various organic mixtures. The support modification was conducted by pressing $SiO_2$ xerogel of 500 nm in particle size under 10 MPa on the surface of a porous stainless steel (SUS) substrate and designed the multi-layered structure by coating the intermediate layer of ${\gamma}-Al_2O_3$. Microstructure of titania membrane was affected by heat-treatment and synthesis conditions of precursor sol, and titania formed at calcination temperature of 300$^{\circ}C$ with sol of [$H^+$]/[TIP]=0.3 possessed surface area of 210 $m^2$/g, average pore size of 1.25 nm. The titania composite membrane showed high $H_2/N_2$ selectivity and water/ethanol selectivity as 25-30 and 50-100, respectively. As a result of vapor permeation for water-alcohol and alcohol-alcohol mixture, titania composite membrane showed water-permselective and molecular-sieve permeation behavior. However, water/methanol selectivity of the membrane was very low because of chemical affinity of permeants for the membrane by similar physicochemical properties of water and methanol.

Field-emission Properties and Long-term Stability of Tip-type Carbon Nanotubes Coated with Gallium-incorporated Zinc Oxide Films (갈륨이 첨가된 산화아연막의 코팅에 따른 미세팁 구조 탄소나노튜브의 전계방출 특성 및 장시간 안정성)

  • Kim, Jong-Pil;Noh, Young-Rok;Jo, Kyoung-Chul;Lee, Sang-Yeol;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.4
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    • pp.65-69
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    • 2009
  • Carbon nanotubes (CNTs) were coated with undoped zinc oxide (ZnO) or 5 wt% gallium-incorporated ZnO (GZO) using various deposition conditions. The CNTs were directly grown on conical-type tungsten substrates at $700^{\circ}C$ using inductively coupled plasma-chemical vapor deposition. The pulsed laser deposition technique was used to deposit the ZnO and GZO thin films with very low stress. Field-emission scanning electron microscopy and high-resolution transmission electron microscopy were used to monitor the variations in the morphology and microstructure of CNTs prior to and after ZnO or GZO coating. The formation of ZnO and GZO films on CNTs was confirmed using energy-dispersive x-ray spectroscopy. In comparison to the as-grown (uncoated) CNT emitter, the CNT emitter that was coated with a thin (10 nm) GZO film showed remarkably improved field emission characteristics, such as the emission current of $325\;{\mu}A$ at 1 kV and the threshold field of $1.96\;V/{\mu}m$ at $0.1\;{\mu}A$, and it also exhibited the highly stable operation of emission current up to 40 h.

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Effect of Cooling Rate on Microstructural and Mechanical Properties of SAF 2205 Duplex Stainless Steel (SAF 2205 듀플렉스 스테인레스강의 미세조직 및 기계적 특성에 미치는 냉각속도의 영향)

  • Oh, Y.J.;Yang, W.J.;Lee, J.H.;Kim, D.H.;Yoo, W.D.;Lee, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.1
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    • pp.14-20
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    • 2013
  • Duplex stainless steel, which is a kind of stainless steel with a mixed microstructure of about equal proportions of austenite and ferrite, is generally known as a unique material with excellent corrosion resistance and high strength. However, toughness, strength, and corrosion resistance of the steel could be reduced due to precipitation of topologically closed packed phases such as sigma phase during cooling. In case of large forged products, they have strong possibility that ${\sigma}$-phase precipitates due to difference of cooling rate between surface and inner of the products. Investigation on sigma phase precipitation behavior of duplex stainless steel with change of cooling rate was carried out in this study. Forged SAF 2205 duplex stainless steel was used as specimens to examine the cooling rate effect. Dissolution behavior of sigma phase was also discussed through resolution test of duplex stainless steel containing lots of sigma phase. Experimental results revealed that impact energy was very sensitive to precipitation of small amount sigma phase. However, sigma phase could be removed by short term resolution treatment and impact resistance of the duplex stainless steel was restored.

Effects of Excess Yttrium Addition on YBCO Thin Films Prepared by TFA-MOD Process (MOD-TFA 공정에 의한 YBCO박막제조시 과잉 yttrium첨가 효과에 관한 연구)

  • Lee Seung-Yi;Song Seul-A;Kim Byeong-Joo;Park Jin-A;Kim Ho-Jin;Lee Hee-Gyoun;Hong Gye-Won;Jang Seog Heon;Joo Jinho;Yoo Jai-Moo;Pradeep Halder
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.87-91
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    • 2005
  • [ $YBa_{2}Cu_{3}O_{7-x}$ ] thin films were fabricated on $LaAlO_3$(100) substrate by TFA-MOD process. Yttrium-excess (0, 2.5, 5, 10, 15, 20 $at\%$) coating solution was prepared by adding extra amount of yttrium into a stoichiometric(Y:Ba:Cu=1:2:3) TFA precursor solution. Results are presented concerning the influence of excess yttrium additions on the microstructure development and superconducting properties of $YBa_{2}Cu_{3}O_{7-x}$ film. Large sized CuO particles was observed by SEM EDS investigation. The addition of excess yttrium affected little on $T_c$ of $YBa_{2}Cu_{3}O_{7-x}$ film. $J_c$ of YBCO film was enhanced with excess yttrium addition. Jc maximum of $2.21\;MA/cm^2$ (77 K, self field) appeared with the $15\;at\%$ addition of excess yttrium. With further yttrium addition up to $20\;at\%$, Jc decreased down to $0.9\;MA/cm^2$.

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Effect of pre-annealing conditions on mechanical and superconducting properties of Bi-2223/Ag tapes (초전도 선재의 전 열처리에 따른 기계적 및 초전도 특성에 미치는 효과)

  • 양주생;하동우;이동훈;최정규;황선역;하홍수;오상수;권영길;김명호
    • Progress in Superconductivity
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    • v.5 no.2
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    • pp.124-127
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    • 2004
  • Many of research efforts have been focused on the improvement of critical current density (Jc) of silver-sheathed Bi-2223 tapes far practical applications. In this study, the transformation of Bi-2212 phase was investigated, which was transformed to orthorhombic from tetragonal through pre-annealing during powder packing and drawing process. The relationship between hardness of Bi-2212 orthorhombic phase and workability of Bi-2223/Ag tape was investigated. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking and drawing process with different heat-treatment histories. Before rolling process, round wires were pre-annealing at 76$0^{\circ}C$ and in a low oxygen partial pressure. We confirmed that pre-annealing step was to transform to Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases. However the breakages were created at Ag-alloy clad during rolling for pre-annealed Bi-22231Ag tapes. Several pre-annealing scenarios were introduced to reduce the breakages during rolling process. Microstructure and critical current density of pre-annealed Bi-2223 superconducting tapes were investigated. We could achieve proper pre-annealing conditions for Ag-alloy clad Bi-2223 superconducting tapes.

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Effects of Polyacrylic Acid Doping on Microstructure and Critical Current Density of $MgB_2$ Bulk ($MgB_2$ bulk의 미세구조와 임계전류밀도에 미치는 polyacrylic acid doping 효과)

  • Lee, S.M.;Hwang, S.M.;Lee, C.M.;Joo, J.;Kim, C.J.
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.87-91
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    • 2010
  • We fabricated the polyacrylic acid (PAA)-doped $MgB_2$ bulks and characterized their lattice parameters, actual C substitutions, microstructures, and critical properties. The boron (B) powder was mixed with PAA using N,N-dimethylformamide as solvent and then the solution was dried out at $200^{\circ}C$ and crushed. The C treated B powder and magnesium powder were mixed and compacted by uniaxial pressing at 500 MPa, followed by sintering at $900^{\circ}C$ for 1 h in high purity Ar atmosphere. We observed that the PAA doping increased the MgO amount but decreased the grain size, a-axis lattice constant, and critical temperature ($T_c$), which is indicative of the C substitution for B sites in $MgB_2$. In addition, the critical current density ($J_c$) at high magnetic field was significantly improved with increasing PAA addition: at 5 K and 6.6 T, the $J_c$ of 7 wt% PAA-doped sample was $6.39\;{\times}\;10^3\;A/cm^2$ which was approximately 6-fold higher than that of the pure sample ($1.04\;{\times}\;10^3\;A/cm^2$). This improvement was probably due to the C substitution and the refinement of grain size by PAA doping, suggesting that PAA is an effective dopant in improving $J_c$(B) performance of $MgB_2$.

Deposition of Indium Tin Oxide films on Polycarbonate substrates by Ion-Assisted deposition (IAD)

  • Cho, Jn-sik;Han, Young-Gun;Park, Sung-Chang;Yoon, Ki-Hyun;Koh, Seok-Keun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.98-98
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    • 1999
  • Highly transparent and conducting tin-doped indium oxide (ITO) films were deposited on polycarbonate substrate by ion-assited deposition. Low substrate temperature (<10$0^{\circ}C$) was maintained during deposition to prevent the polycarbonate substrate from be deformed. The influence of ion beam energy, ion current density, and tin doping, on the structural, electrical and optical properties of deposited films was investigated. Indium oxide and tin-doped indium oxide (9 wt% SnO2) sources were evaporated with assisting ionized oxygen in high vacuum chamber at a pressure of 2$\times$10-5 torr and deposition temperature was varied from room temperature to 10$0^{\circ}C$. Oxygen gas was ionized and accelerated by cold hallow-cathode type ion gun at oxygen flow rate of 1 sccm(ml/min). Ion bea potential and ion current of oxygen ions was changed from 0 to 700 V and from 0.54 to 1.62 $\mu$A. The change of microstructure of deposited films was examined by XRD and SEM. The electrical resistivity and optical transmittance were measured by four-point porbe and conventional spectrophotometer. From the results of spectrophotometer, both the refractive index and the extinction coefficient were derived.

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Studies of Valve Lifer for Automotive Heavy Duty Diesel Engine by Ceramic Materials II. Development of SiC Valve Lifter by Injection Molding Method (Ceramic 재질을 이용한 자동차용 대형 디젤엔진 Valve Lifter 연구 II. 사출성형에 의한 탄화규소질 Valve Lifter 개발)

  • 윤호욱;한인섭;임연수;정윤중
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.172-179
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    • 1998
  • Valve lifter namely tappet is supported by lifter hole which is located upper side of camshaft in cylinder block transforms rotatic mvement of camshaft into linear movement and helps to open and shut the en-gine valve as an engine parts. The face of valve lifter which is continuously contacting with camshaft brings about abnormal wears such as unfair wear and early wear because it is severely loaded in the valve train system. These wears act as a defect like over-clearance and cause imperfect combustion of fuel during the valve lifting in the combustion chamber. Consequently this imperfect combustion makes the engine out-put decrease and has cause on air pollution. To prevent these wears therefore The valve lifter cast in me-tal developed into SiC ceramics valve lifter which has an excellence in wear and impact resistance As a results the optimum process conditions like injection condition mixture ratio and debonding process could be established. After sintering fine-sinered dual microstructure in which prior ${\alpha}$-SiC matches well with new SiC(${\beta}$-SiC) produced by reaction among the ${\alpha}$-SiC carbon and silicon was obtained. Based on the study it is verified that mechanical properties of SiC valve lifter are excellent in Vickers hardness 1100-1200 bending strength (300-350 Pa) fracture toughness(1.5-1.7 Mpa$.$m1/2) Through engine dynamo test-ing SiC valve lifter and metal valve lifter are examined and compared into abnormal phenomena such as early fracture unfair and early wear. It is hoped that this research will serve as an important springboard for the future study of heavy duty diesel engine parts developed by ceramics which has a good wear resis-tance relaibility and lightability.

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