• Journal of Magnetics
• /
• 제11권1호
• /
• pp.36-42
• /
• 2006

In this report, we demonstrate a comprehensive analysis of the effects of Au addition on the microstructure and magnetic properties of $Fe_{73.5}Si_{13.5}B_{9}Nb_{3}Au_1$ Finemet-type alloy. It was found that the as-quenched alloys were the amorphous state and turned into nanocrystalline state under heat treatments. The DSC analysis indicates that the sharply exothermal peak corresponding to the crystallization of the $\alpha-Fe(Si)$ was observed at $547-579^{\circ}C$ depending on the heating rates, which is little higher than that of original Finemet (542-$570{^{\circ}C}$, respectively). Besides, the thermomagnetic result confirmed that the full substitution of Cu by Au with the single phase structure in the M(T) curve along cooling cycle. Ultrasoft magnetic properties of the nanocrystallized samples were significantly enhanced by the proper annealing such as the increase of permeability and the decrease of the coercivity. The optimum annealing condition was found at the annealing temperature of $540^{\circ}C$ and the increase of the annealing time up to 90 min.

• 한국재료학회지
• /
• 제15권4호
• /
• pp.246-251
• /
• 2005

Plasma enhanced chemical vapor deposition(PE-CVD) method has an advantage in synthesizing carbon nanotubes(CNTs) at lower temperature compared with thermal enhanced chemical vapor deposition(TE-CVD) method. In this study, CNTs was prepared by using PE-CVD method. The growth rate of CNT was faster more than 100 times on using Invar alloy than iron as catalyst. It was found that chrome silicide was formed at the interface between chrome layer and silicon substrate which should be considered in designing process. Nanoparticles of Invar catalyst were found oxidized on their surfaces with a depth of 10 m. Microstructure was analyzed by scanning electron microscopy, transmission electron microscopy, scanning transmission electron microscopy, and energy dispersive x-ray spectrometry. Based on the result of analysis, growth mechanism at an initial stage was suggested.

• Applied Microscopy
• /
• 제47권1호
• /
• pp.50-54
• /
• 2017

The microstructure, the crystallization behavior, and magnetic properties of FeSi-based soft magnetic alloys (FINEMET) were investigated using transmission electron microscopy, X-ray diffraction, and coercive force measurements. The amorphous $Fe_{73.28}Si_{13.43}B_{8.72}Cu_{0.94}Nb_{3.63}$ alloys particles, prepared in $10^{-4}$ torr by gas atomization process, were heat treated at $530^{\circ}C$, $600^{\circ}C$, and $670^{\circ}C$ for 1 hour in a vacuum of $10^{-2}$ torr. Nanocrystalline Fe precipitation was first formed followed by the grain growth. Phase formation and crystallite sizes was compared linked to its magnetic behavior, which showed that excellent soft magnetic property can directly be correlated with its microstructure.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2003년도 The 8th Asian Symposium on Precision Forging ASPF
• /
• pp.43-46
• /
• 2003

Prediction of final microstructures after high temperature forming of Ti-6Al-4V alloy was attempted in this study. Using two typical microstructures, i.e., equiaxed and $Widmanst\ddot{a}tten$ microstructures, compression test was carried out up to the strain level of 0.6 at various temperatures $(700\~1100^{\circ}C)$ and strain rates $(10^{-4}\~10^2/s)$. From the flow stress-strain data, parameters such as strain rate sensitivity (m) and activation energy (Q) were calculated and used to establish constitutive equations for both microstructures. Then, finite element analysis was performed to predict the final microstructure of the deformed body, which was well accorded with the experimental results.

• 소성∙가공
• /
• 제22권8호
• /
• pp.456-462
• /
• 2013

Compression tests were conducted at the various temperatures and strain rates to investigate void formation and microstructures behavior of a 1.9wt%C ultrahigh carbon steel used in forged workrolls. The microstructure, grain size and volume fraction of cementite were determined using specimens deformed in the temperature range from 800 to $1150^{\circ}C$ and strain rates from 0.01 to 10/s. It was found from the microstructural analysis that the grain size is larger at higher temperatures and lower strain rate deformation conditions. In addition, a higher volume fraction of cementite was measured at lower temperatures. The brittle blocky cementite was fractured at $800^{\circ}C$ and $900^{\circ}C$ regardless of strain rate. As a result, numerous new micro voids were formed in the fragmented blocky cementite. It was also found that local melting can occur at temperatures of more than $1130^{\circ}C$. Therefore, the forging temperature should be controlled between $900^{\circ}C$ and $1120^{\circ}C$. The temperature rise, which depends on the anvil stroke and velocity, was estimated through cogging simulation to find the appropriate forging temperature and to prevent local melting due to plastic work.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2007년도 추계학술대회 논문집
• /
• pp.146-149
• /
• 2007

The effects of boron additions in steels have long been recognized as very important, mainly with respect to hardnability of heat treatable steels. The systematics of structure and properties of boron steels will then be illustrated in the context of low-alloy steels with carbon contents raging from 0.05 to 0.25% and boron contents 0-130 ppm. we investigated the effect of the microstructure and mechanical properties with heat treatment condition of the boron-treated(0.0013 ppm) low carbon(0.2 %C) low alloy steel. The specimens were austenitised for 5 and 10, 15 min at $880{\sim}940^{\circ}C$(with/without tempered at 150, 180 and $210^{\circ}C$ for the various periods of time from 60 min to 120 min) After heat treatment, mechanical properties were measured by tensile test and hardness test. For analysis of microstructure, Optical/SEM analysis and XRD were carried out.

• Journal of Welding and Joining
• /
• 제27권6호
• /
• pp.43-48
• /
• 2009

In this study, Cu-based bulk metallic glass (BMG) coatings were deposited by atmospheric plasma spraying (APS) process with different process conditions (with- and without hydrogen gas). As adding the hydrogen gas, thermal energy in the plasma flame increased and induced difference in the melting state of the Cu-based BMG particles. The microstructure and mechanical properties of the coatings were analyzed using a scanning electron microscope (SEM) with an energy dispersive spectroscopy (EDS) and nano-indentation tester in the light of phase analysis. It was elucidated by the nano-indentation tests that un-melted region was a mainly amorphous phase which showed discrete plasticity observed as the flow serrations on the load.displacement (P - h) curves, and the curves of solidified region showed lower flow serrations as amorphous phase mingled with crystalline phase. Oxides produced during the spraying process had the highest hardness value among the phases and were well mixed with other phases resulted from the increase in melting degree.

• 소성∙가공
• /
• 제32권3호
• /
• pp.145-152
• /
• 2023

The Inconel 706 alloy is a nickel-based super alloy and requires a large load for hot forging due to its excellent mechanical properties at high temperature. Rotary forging process is an innovative metal forging process where workpiece is gradually deformed by the revolving conical upper die with an inclination angle. This process allows that the workpiece is partially in contact with an upper die during the process so that the press force is considerably lower compared with the conventional upsetting process. In this study, experiments of rotary forging process and conventional upsetting process for cylindrical parts using Inconel 706 where conducted to investigate the formability of rotary forging process. And microstructure analysis and mechanical properties of Inconel 706 were performed to investigate the effect of rotary forging process on the material property.

• 한국표면공학회지
• /
• 제34권5호
• /
• pp.421-428
• /
• 2001

New WC-CrN superlattice film was deposited on Si substrate (500$\mu\textrm{m}$) using cathodic arc ion plating system. The microstructure and mechanical properties of the film depend on the superlattice period (λ). In the X-ray diffraction analysis (XRD), preferred orientation of microstructure was changed according to various superlattice periods(λ). During the Transmission Electron Microscope analysis (TEM), microstructure and superlattice period (λ) of the WC - CrN superlattice film was confirmed. Hardness and adhesion of the deposited film was evaluated by nanoindentation test and scratch test, respectively. As a result of nanoindentation test, the hardness of WC - CrN superlattice film was gained about 40GPa at superlattice period (λ) with 7nm. Also residual stress with various superlattice period (λ) was measured on Si wafer (100$\mu\textrm{m}$) by conventional beam-bending technique. The residual stress of the film was reduced to a value of 0.2 GPa by introducing Ti - WC buffer layers periodically with a thickness ratio ($t_{buffer}$/$t_{buffer+superlattice}$ ). To the end, for the evaluation of oxidation resistance at the elevated temperature, CrN single layer and WC - CrN superlattice films with various superlattice periods on SKD61 substrate was measured and compared with the oxidation resistance.

• Advances in nano research
• /
• 제13권4호
• /
• pp.407-416
• /
• 2022

In this study, the gravitating mechanical stir casting method was used to fabricating the Nb₂O₅/AZ31 magnesium matrix nanocomposites. Niobium pentoxide (Nb₂O₅) used as reinforcement with two different weight percentages (3 wt % and 6 wt %). The influence of Nb₂O₅ on microstructure and mechanical properties has been investigated. The microstructure analysis showed that the composites are mainly composed of the primary α-magnesium phase and phase β-Mg₁₇Al₁₂ secondary phase. The secondary phase was dispersed evenly along the grain boundary of the Mg phase. The Nb₂O₅/AZ31 nanocomposites revealed that the grain size and its lamellar shape (β-Mg₁₇Al₁₂) were gradually refined. Different strengthening mechanisms were assessed in terms of their contributions. Results showed that composite material properties of hardness, yield strength, and fracture study were directly related to Nb₂O₅ as a reinforcement. The maximum values of the mechanical properties were achieved with the addition of 3 wt% Nb₂O₅ on the AZ31 alloy.