• Journal of Welding and Joining
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• v.23 no.4
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• pp.27-33
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• 2005

Quantitative evaluation was performed on the microstructure of flux-cored arc(FCA) weld metal using a method blown as IIW scheme. It was mainly intended to figure out any practical difficulties in applying this method and also to provide the consumable makers with basic guide line in developing FCA welding consumables far better properties. Assessment of the experimental results showed IIW scheme was quite reliable in the low heat input range where the acicular ferrite was a major constituent. However, in the high heat input range, some scatter was noticed as the other phases like grain boundary ferrite and Widmansttaten ferrite become dominant. It implies that the accuracy of IIW scheme depends on the faction of microstructural constituents and it become worse as the fraction of latter two phases increases. This tendency was discussed in terms of the characteristics of those two phases. In addition, base line microstructure of rutile type FCA weld metal was addressed for developing new FCA welding consumables intended for higher heat input welding.

• International Journal of Korean Welding Society
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• v.3 no.2
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• pp.29-39
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• 2003

The durability and reliability of thermal barrier coatings (TBCs) play an important role in the service reliability, availability and maintainability (RAM) of hot­section components in advanced turbine engines for aero and utility applications. Photostimulated luminescence spectroscopy (PSLS) and electrochemical impedance spectroscopy (EIS) are being concurrently developed as complimentary non­destructive evaluation (NDE) techniques for quality control and life­remain assessment of TBCs. This paper overviews the governing principles and applications of the luminescence and the impedance examined in the light of residual stress, phase constituents and resistance (or capacitance) in TBC constituents including the thermally grown oxide (TGO) scale. Results from NDE by PSLS and EIS are discussed and related to the microstructural development during high temperature thermal cycling, examined by using a variety of microscopic techniques including focused ion beam (FIB) in­situ lift­out (INLO), transmission and scanning transmission electron microscopy (TEM and STEM).

• Journal of Welding and Joining
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• v.7 no.2
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• pp.35-48
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• 1989

This study is concerned with a correlation of microstructure and local brittle zone (LBZ) in offshore structural steel welds. The influence of the LBZ on fracture toughness was investigated by means of simulated heat-affected zone (HAZ) tests as well as welded joint tests. Micromechanical processes involved in void and cleavage microcrack formation were also identified using notched round tensile tests and subsequent SEM observations. The LBZ in the HAZ of a multiphase welded joint is the interstitially reheated coarse grained HAZ, which is influenced by metallurgical factors such as effective grain size, the major matrix structure and the amount of high-carbon martensite-austenite (M-A) constituents. The experimental results indicate that Chirpy energy was found to scale monotonically with the amount of M-A constituents, confirming that the M-A constituent is the major microstructural factor controlling the HAZ toughness. In addition, voids and microcracks are observed to initiate at M-A constituents by the shear cracking process. Thus, the M-A constituent played an important role in initiating the voids and microcracks, and consequently caused brittle fracture.

• Corrosion Science and Technology
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• v.22 no.2
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• pp.131-136
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• 2023

The aim of this study was to investigate effects of microstructure control on hydrogen diffusivity, trap activation energy, and cracking behaviors of high-strength steel using a range of experimental techniques. Results of this study showed that susceptibility to hydrogen induced cracking (HIC) was significantly associated with hydrogen diffusivity and trap activation energy, which were primarily influenced by the microstructure. On the other hand, microstructural modifications had no significant impact on electrochemical polarization behavior on the surface at an early corrosion stage. To ensure high resistance to HIC of the steel, it is recommended to increase the cooling rate during normalizing to avoid formation of banded pearlite in the microstructure. However, it is also essential to establish optimal heat treatment conditions to ensure that proportions of bainite, retained austenite (RA), and martensite-austenite (MA) constituents are not too high. Additionally, post-heat treatment at below A₁ temperature is desired to decompose locally distributed RA and MA constituents.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.3 no.2
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• pp.185-201
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• 1993

The objectives of this study are to identify the physical, chemical and microstructural properties of coal fly ash and to increase the industrial use of coal fly ash. Experimental results show that 3 major constituents of coal fly ash are $SiO_2$, $Al_2O_3$ and coal fly ash includes the crystalline of Quartz and Mullite. Coal fly ash are classified into 7 groups based on the type of microstructure. Cenosphere is divided into floater and dry separated cenosphere which are consist mainly of $SiO_2$ and $Al_2O_3$. Cenosphere segregations are formed by adsorption and neck growth of the smaller sized cenosphere particles on the condition of the high temperature and air pressure.

• Geomechanics and Engineering
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• v.21 no.4
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• pp.337-348
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• 2020

Tropical organic soils having more than 65% of organic matters are named "peat". This soil type is extremely soft, unconsolidated, and possesses low shear strength and stiffness. Different conventional and industrial binders (e.g., lime or Portland cement) are used widely for stabilisation of organic soils. However, due to many factors affecting the behaviour of these soils (e.g., high moisture content, fewer mineral particles, and acidic media), the efficiency of the conventional binders is low and/or cost-intensive. This research investigates the impact of different constituents of cement-sodium silicate grout system on the compressibility behaviour of organic soil, including settlement and void ratio. A microstructure analysis is also carried out on treated organic soil using Scanning Electron Micrographs (SEM), Energy Dispersive X-ray spectrometer (EDX), and X-ray Diffraction (XRD). The results indicate that the settlement and void ratio of treated organic soils decrease gradually with the increase of cement and kaolinite contents, as well as sodium silicate until an optimum value of 2.5% of the wet soil weight. The microstructure analysis also demonstrates that with the increase of cement, kaolinite and sodium silicate, the void ratio and porosity of treated soil particles decrease, leading to an increase in the soil density by the hydration, pozzolanic, and polymerisation processes. This research contributes an extra useful knowledge to the stabilisation of organic soils and upgrading such problematic soils closer to the non-problematic soils for geotechnical applications such as deep mixing.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.235-243
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• 2002

Ni-base superalloys are used extensively in industry, both in aeroengines and land based turbines. About 60% by weight of most modern gas turbine engine structural components are made of Ni-base superalloys. To satisfy practical demands, the efficiency of gas turbine engines has been steadily and systematically increased by design modifications to handle higher turbine inlet or firing temperatures. However, the increase in operating temperatures has lead to a decrease in the life of components and increase in costs of replacement. Moreover, around 80% of the large frame size industrial/utility gas turbines operating in the world today were installed in the mid-sixties to early seventies and are now 25 to 30 years old. Consequently, there are greater opportunities now to repair and refurbish the older models. Basically, there are two major factors influencing the weldability of the cast alloys: strain-age cracking and liquation cracking. Susceptibility to strain-age cracking is due to the total Ti plus AI content of the alloy; Liquation cracking is due either to the presence of low melting constituents or constitutional liquation of constituents. Though Rene 41 superalloy has 4.5wt.% total Ti and Al content and falls just below the safe limit proposed by Prager et al., controlled grain size and special heat treatments are needed to obtain crack-free welds. Varying heat treatments and filler materials were used in a laboratory study, then the actual welding of service parts was carried out to verity the possibility of crack-tree weld of components fabricated from Rene 41 superalloy. The microstructural observations indicated that there were two kinds of carbides in the FCC matrix. MC carbides were located along the grain boundaries, while M$_{23}$C$_{6}$ carbide was located both inter and intra granularly. Two kinds of filler materials, Rene 41 and Hastelloy X were used to gas tungsten arc weld a patch into the sheet metal, along with varying pre-weld heat treatments. The microstructure, hardness and tensile tests were determined. The service distressed parts were categorized into three classes: with large cracks, with medium cracks and with small or no visible cracks. No significant difference in microstructure among the specimens was observed. Specimens were cut from the corner and the straight edge of the patch repair, away from the corner. The only cracks present were found to be associated with inadequate surface preparation to remove oxidation. Guidelines for oxide removal and the welding procedures developed in the research enabled crack-free welds to be produced.d.

• Journal of the Korean Ceramic Society
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• v.41 no.12 s.271
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• pp.933-938
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• 2004

The clinkerbility and the behaviour of formation of $3CaO{\cdot}Al_{2}O_3$ were studied using the mixture of waste oyster shell and spent oil-refining catalyst mainly by the mineral and microstructural observation. By virtue of the formation of $12CaO{\cdot}7Al_{2}O_3$ at relatively low temperature and its successive reaction with CaO, the $3CaO{\cdot}Al_{2}O_3$ clinkers were formed easily without affection of minor constituents contained in oyster shell. Thus clinkers were formed at $1400^{\circ}C$ directly but began to melt incongruently at higher temperature above that. Aluminium hydroxide, however, was not desirable as an aluminous raw materials of the clinker because rapid melting occurs before $3CaO{\cdot}Al_{2}O_3$ forms main clinker mineral.

• Korean Journal of Metals and Materials
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• v.50 no.7
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• pp.487-493
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• 2012

To analyze the factors on stretch-flangeability for 980 MPa-grade hot-rolled steels, two types of steels (Fe-Cr and Fe-Mo) were manufactured by hot-rolling. Manufactured steels at the low coiling temperature, such as 400 and $500^{\circ}C$, had poor stretch-flangeability due to un-uniformly distributed carbides and a large deviation of interphase hardness. However, when the coiling temperature was set at $650^{\circ}C$ with Fe-Cr steel, 998 MPa of ultimate tensile strength, 19% of total elongation and 65% of the hole expanding ratio were achieved by microstructural constituents of polygonal ferrite (PF) and granular ferrite (GF) dispersed with fine carbides (<50 nm). Therefore, the material to attain 980 MPa with superior formability was the Fe-Cr steel that was precipitation-hardened in polygonal ferrite and granular ferrite at the coiling temperature $650^{\circ}C$.

• Computers and Concrete
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• v.34 no.4
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• pp.489-501
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• 2024

Geopolymers are part of a class of materials characterized by properties combining polymers, ceramics, and cement. These include exceptionally high thermal and chemical stability, excellent mechanical strength and durability in aggressive environments. This work deals with the synthesis, characterization, and sustainability evaluation of GP_GBFS-MK geopolymers by alkaline activation of a granulated blast furnace slag-metakaolin mixture. In the first step, elemental and oxide analyses by XRF and EDS showed that the main constituents of GP_GBFS-MK geopolymers are silicon, sodium, and aluminium oxides. The structural analyses by XRD and FTIR confirmed that the geopolymerization for GP_GBFS-MK geopolymers did occur, accompanied by the formation of disordered networks from the blends and a modification to the microstructure by the geopolymerization process. Similarly, the microstructural study made by SEM showed that the GP_GBFS-MK geopolymers are constituted by aluminosilicates in the form of dense clusters on which are adsorbed particles of unreacted GBFS in the form of spheroids and white residues of the alkaline activating solution. In addition, the study of the sustainability evaluation of GP_GBFS-MK geopolymers showed that the water absorption of geopolymeric materials is lower than that of OPC cement. As for the elevated temperature resistance, the analyses indicated an excellent elevated temperature resistance of GP_GBFS-MK. In the same way, the study of the resistance to chemical aggressions showed that the GP_GBFS-MK geopolymeric materials are unattackable, contrary to the OPC cement-based materials which are strongly altered.