• Coupled systems mechanics
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• 제5권4호
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• pp.355-369
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• 2016

Changes in chemical structure have profound effects on the physical properties of epoxy-based materials, and eventually affect the durability of the entire system. Microscopic structural voids generally existing in the epoxy cross-linked networks have a detrimental influence on the epoxy mechanical properties, but the relation remains elusive, which is hindered by the complex structure of epoxy-based materials. In this paper, we investigate the effect of structural voids on the epoxy-based materials by using our developed mesoscale model equipped with the concept of multiscale modeling, and SU-8 photoresist is used as a representative of epoxy-based materials. Developed from the results of full atomistic simulations, the mesoscopic model is validated against experimental measurements, which is suitable to describe the elastic deformation of epoxy-based materials over several orders of magnitude in time- and length scales. After that, a certain quantity of the structure voids is incorporated in the mesoscale model. It is found that the existence of structural voids reduces the tensile stiffness of the mesoscale epoxy network, when compared with the case without any voids in the model. In addition, it is noticed that a certain number of the structural voids have an insignificant effect on the epoxy elastic properties, and the mesoscale model containing structural voids is close to those found in real systems.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집C
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• pp.246-250
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• 2001

In resin transfer molding (RTM), resin is forced to flow through the fiber perform of inhomogeneous permeability. This inhomogeneity is responsible for the mismatch of resin velocity within and between the fiber tows. The capillary pressure of the fiber tows exacerbates the spatial variation of the resin velocity. The resulting microscopic perturbations of resin velocity at the flow front allow numerous air voids to form. In this study, a mathematical model was developed to predict the formation and migration of micro-voids during resin transfer molding. A transport equation was employed to account for the migration of voids between fiber tows. Incorporating the proposed model into a resin flow simulator, the volumetric content of micro-voids in the preform could be obtained during the simulation of resin impregnation.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.925-928
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• 2001

Recently great efforts and investment have been made in order to achieve economical production by applying new methods like minimization of man-Power into construction field. This paper describe the performance of water purification, to which living organisms can adapt, and the physical properties of porous concrete with continuous voids. Although conventional concrete has been regarded as a destroyer of nature, water and air can pass freely through concrete when it is made porous by forming continuous voids. this not only enables plants to vegetables, but also makes it possible for microscopic animals and plants, including bacteria, to attach to and inhabit uneven surface as well as internal voids when the concrete is provided in a natural water area or waterside area. As a result, Porous concrete using recycled aggregate improved the performance of water purification.

• Composites Research
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• 제17권3호
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• pp.1-7
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• 2004

최근 대형 복합재료 구조물 성형에 적합한 공정으로 주목받는 vacuum assisted RTM (VARTM) 공정에 있어, 보강섬유의 조직 내부에 잔류하는 공기를 제거하여 기공함유율을 낮추는 기술의 중요성이 인식되고 있다. 거대기공 혹은 불완전 함침영역은 부적절한 주입구 및 공기배출구의 위치, 혹은 금형의 형상에 의해 발생한다. 미세기공은 불균일한 수지 유동선단의 속도로 인해 유동선단 부분에서 집중적으로 형성되며, 금형충전 공정 도중 수지와 함께 이동한다. 성형이 완료된 제품내의 잔류 기공들은 완성품의 물리적 성질을 저하 및 제품의 파손을 초래할 수 있다. 본 연구에서는 VARTM 공정에서의 기공의 형성 및 이동을 해석할 수 있는 통합된 거시적/미시적 해석 방법을 개발하였다. 수치해석 프로그램을 개발하여 VARTM 공정에서의 3차원 수지 유동을 해석하였으며, 그에 따른 거대기공 및 미세기공의 분포를 예측하였다.

• 한국광물학회지
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• 제4권1호
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• pp.51-55
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• 1991

산청 할로이사이트의 전자 회절분석 및 레플리카와 박편을 이용한 형태 연구결과 관산 할로이사이트는 반경이 서로 다른 몇 개의 관들이 중첩되어 있으며 내부의 작은 관은 원형이나 외부의 큰 관은 다각형으로서 두 관 사이에 삼각형의 공극이 형성되어 있음이 관찰되었다. 할로이사이트의 단면은 대체로 직경이 500${\AA}$보다 작으면 원형을 이루고 그보다 크면 다각형을 이룬다. 다각형의 단면을 갖는 할로이사이트의 전자 회절상은 이들이 이층 단사 구조를 갖고 있음을 지시한다.

• Advances in concrete construction
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• 제16권3호
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• pp.141-153
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• 2023

In order to develop and take full advantage of pasture fiber and waste concrete, this article studied how different amounts of pasture fiber influenced the toughness and pore structure of concrete with different replacement rates of recycled fine aggregate. Pasture fiber recycled concrete constitutive equations were established under idealized stiffness and toughness damage rate, based on fracture energy and damage mechanics theories. The relationship between pore structure and toughness was studied utilizing nuclear magnetic resonance and fractal theory. The toughness of text groups (0% (JZ), 10% (ZS10), 20% (ZS20)) first increased and then decreased with increasing amounts of pasture fiber, based on the damage rate of toughness. The toughness of concrete samples with recycled fine aggregate and pasture fiber is negatively correlated to the fractal dimension of small and medium-sized pores with a pore size of 0-500 nm. At a replacement rate of 10% of the recycled fine aggregate, the fractal dimension of the air voids (r: 500-9000 nm, i.e., Lg(r) ∈ [2.7, 3.9]) shows a gradual decrease with the increase of grass fiber dosage, indicating that with such a replacement rate of the recycled fine aggregate, the increase of pasture fiber can reduce the complexity of the pore structure of the air voids (500-9000 nm).

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2003년도 봄 학술발표회 논문집
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• pp.85-92
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• 2003

Generally, ordinary portland cement(OPC) is widely used for grouting to reduce permeability of ground under the foundations of structures. But, it is hard to be injected into the microscopic voids, fissures and crevices in soil or rock formation for the OPC material. Therefore new method what is called MSG(Micro Silica Grouting) has been developed recently to improve the weak point of the OPC material. In this case study, in order to verify performance of the MSG's water cut-off, trial injections were performed in rear of CIP(Cast in Place Pile) on the site A(weathered soil) and B(alluvial soil) that are constructed for the subway No. 9 nowadays. To take the proper grouting method of the MSG in the trial injecting, the injections are carried out for grouting types(constant pressure or fixed Quantity) and grouting methods(1.5shot or 2.0shot) and to confirm the effects of water cut-off and the injection range of the MSG, the tests of permeability and indicator(phenolphthalein) response were performed before and after the injection. Through the tests results, we could affirm the effects of water cut-off of the MSG and the injection range for the weathered and alluvial soil layers near the Han River. Finally we could make sure the application of the MSG method in actual construction under the layers.

• 소성∙가공
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• 제19권8호
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• pp.480-485
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• 2010

In this work, the closing behavior of cylindrical-shaped voids was experimentally investigated according to various parameters such as reduction ratio in height, initial void size and billet rotation during hot open die forging process. The reduction ratio in height, number of path, and billet rotation were chosen as key process parameters which influence the void closing behavior including the change of void shape and size. On the other hand, values of die overlapping and die width ratio were set to be constant. Void closing behavior was estimated by microscopic observation. Based on the observations, it was confirmed that application of billet rotation is more efficient to eliminate the void with less reduction ratio in height. The experimental results obtained from this study could be helpful to establish the optimum path schedule of open die forging process.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.649-652
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• 2006

This paper describe the performance of seawater purification, to which living organisms can adapt, and the physical properties of porous concrete with continuous void. Although conventional concrete has been regarded as a destroyer of nature, seawater and air can pass freely through concrete when it is made porous by forming continuous void. This not only enables plants to vegetables, but also makes it possible for microscopic animals and plants, including bacteria, to attach to and inhabit uneven surface as well as internal voids when the concrete is provided in a natural seawater area or seawater side area. As a result, porous concrete using recycled aggregate improved the performance of seawater purification. In this study, The performance of seawater purification of porous concrete using recycled aggregate analyzed by T-P, T-N.

• 지질공학
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• 제12권1호
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• pp.95-109
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• 2002

새로이 형성되는 이차광물들이 콘크리트의 조기 성능 저하 (열화)에 미치는 영향은 현재까지 명확히 규명되지 않고 있다. 이들 광물들은 시멘트 페이스트와 골재간의 화학적 반응의 결과로 시멘트 페이스트 내에 형성된다. 조기 성능 저하 현상을 보이는 미국 아이오와주의 콘크리트 포장의 고속도로들로부터 채취된 시료들 내의 골재와 시멘트 페이스트에서의 화학적 광물학적 변화를 규명하기 위하여 암석학적 관찰과 SEM/EDAX 분석을 실시하였다. 이러한 분석에 의거 성능 저하에 연관된 이차광물의 형성과 팽창 메카니즘에 대하여 연구하였다. 브루사이트(Brucite, Mg(OH)2)는 골재의 탈백운석화(dedolomitization) 반응의 결과로 시멘트 페이트스 내에 생성되는 잠재적인 팽창성 광물이다. 시멘트 페이스트의 균열현상은 이들 광물과 공간적인 연관성을 보여주지는 않으나, 대부분이 극 미세입자의 크기로 조기 성능 저하 현상을 나타내는 콘크리트의 시멘트 페이스트 내에 광범위하게 산재되어 나타난다. 무수한 미세공간들에서의 이들 광물 성장에 의한 팽창성 응력은 콘크리트내부의 약한 부분에서 균열로 나타난다. 에트린자이트(3CaO.Al2O3.3CaSO4.32H2O)는 많은 작은 공극들을 완전히 채우고 있으며, 큰 공극들의 가장자리에 테두리와 같은 형태로 나타난다. 미세한 에트린자이트가 많은 콘크리트 시료들의 시멘트 페이스트에 산재해서 나타나기도 한다. 조기 성능 저하의 원인이 되는 시멘트 페이스트의 심한 균열이 에트린자이트와 공간적으로 연관되어 나타나는데, 이러한 사실은 에트린자이트가 콘크리트의 성능 저하에 기여한다는 것을 지시한다. 황철석 (FeS2)이 일반적으로 골재 내에 산재하는데, 이 광물의 산화작용의 산물이 많은 콘크리트 시료들에서 관찰된다. 이런 황철석의 산화작용은 에트린자이트를 형성하기 위한 황산염을 공급하게된다.