• Coupled systems mechanics
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• v.5 no.4
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• pp.355-369
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• 2016

Changes in chemical structure have profound effects on the physical properties of epoxy-based materials, and eventually affect the durability of the entire system. Microscopic structural voids generally existing in the epoxy cross-linked networks have a detrimental influence on the epoxy mechanical properties, but the relation remains elusive, which is hindered by the complex structure of epoxy-based materials. In this paper, we investigate the effect of structural voids on the epoxy-based materials by using our developed mesoscale model equipped with the concept of multiscale modeling, and SU-8 photoresist is used as a representative of epoxy-based materials. Developed from the results of full atomistic simulations, the mesoscopic model is validated against experimental measurements, which is suitable to describe the elastic deformation of epoxy-based materials over several orders of magnitude in time- and length scales. After that, a certain quantity of the structure voids is incorporated in the mesoscale model. It is found that the existence of structural voids reduces the tensile stiffness of the mesoscale epoxy network, when compared with the case without any voids in the model. In addition, it is noticed that a certain number of the structural voids have an insignificant effect on the epoxy elastic properties, and the mesoscale model containing structural voids is close to those found in real systems.

• Proceedings of the KSME Conference
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• 2001.06c
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• pp.246-250
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• 2001

In resin transfer molding (RTM), resin is forced to flow through the fiber perform of inhomogeneous permeability. This inhomogeneity is responsible for the mismatch of resin velocity within and between the fiber tows. The capillary pressure of the fiber tows exacerbates the spatial variation of the resin velocity. The resulting microscopic perturbations of resin velocity at the flow front allow numerous air voids to form. In this study, a mathematical model was developed to predict the formation and migration of micro-voids during resin transfer molding. A transport equation was employed to account for the migration of voids between fiber tows. Incorporating the proposed model into a resin flow simulator, the volumetric content of micro-voids in the preform could be obtained during the simulation of resin impregnation.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.925-928
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• 2001

Recently great efforts and investment have been made in order to achieve economical production by applying new methods like minimization of man-Power into construction field. This paper describe the performance of water purification, to which living organisms can adapt, and the physical properties of porous concrete with continuous voids. Although conventional concrete has been regarded as a destroyer of nature, water and air can pass freely through concrete when it is made porous by forming continuous voids. this not only enables plants to vegetables, but also makes it possible for microscopic animals and plants, including bacteria, to attach to and inhabit uneven surface as well as internal voids when the concrete is provided in a natural water area or waterside area. As a result, Porous concrete using recycled aggregate improved the performance of water purification.

• Composites Research
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• v.17 no.3
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• pp.1-7
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• 2004

In the vacuum assisted RTM (VARTM) process that has become the center of attention for manufacturing massive composite structures, a good evacuation of air in the fiber preform is recognized as the prime factor. The microvoids, or the dry spots, are formed as a result of improper gate/vent locations and the mold geometry. The non-uniform resin velocity at the flow front leads to the formation of microvoids in the fibers, whereas the air in the microvoids can migrate along with the resin flow during mold filling. The residual air in the internal voids of a composite structure may cause a degradation of the mechanical properties as well as the structural failure. In this study, a unified macro- and micro analysis methods were developed to investigate the formation and transport of air in resin during VARTM process. A numerical simulation program was developed to analyze the three-dimensional flow pattern as well as the macro- and microscopic distribution of air in a composite part fabricated by VARTM process.

• Journal of the Mineralogical Society of Korea
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• v.4 no.1
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• pp.51-55
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• 1991

Transmission electron microscopic study including single particle electron diffraction and morphological observation using replica and thin section was carried out for the Sancheong halloysite. Halloysite tube generally consists of inner circular and outer polygonal leaves. Primary triangular or concave voids are found between inner and outer leaves. Crosssection of halloysite tubes whose diameters are smaller than 500${\AA}$ are generally circular, whereas those larger than 500${\AA}$ are polygonal. Electron diffraction pattern of thick polygonal halloysite tube shows that it has a 2-layer monoclinic structure as suggested by previous workers.

• Advances in concrete construction
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• v.16 no.3
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• pp.141-153
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• 2023

In order to develop and take full advantage of pasture fiber and waste concrete, this article studied how different amounts of pasture fiber influenced the toughness and pore structure of concrete with different replacement rates of recycled fine aggregate. Pasture fiber recycled concrete constitutive equations were established under idealized stiffness and toughness damage rate, based on fracture energy and damage mechanics theories. The relationship between pore structure and toughness was studied utilizing nuclear magnetic resonance and fractal theory. The toughness of text groups (0% (JZ), 10% (ZS10), 20% (ZS20)) first increased and then decreased with increasing amounts of pasture fiber, based on the damage rate of toughness. The toughness of concrete samples with recycled fine aggregate and pasture fiber is negatively correlated to the fractal dimension of small and medium-sized pores with a pore size of 0-500 nm. At a replacement rate of 10% of the recycled fine aggregate, the fractal dimension of the air voids (r: 500-9000 nm, i.e., Lg(r) ∈ [2.7, 3.9]) shows a gradual decrease with the increase of grass fiber dosage, indicating that with such a replacement rate of the recycled fine aggregate, the increase of pasture fiber can reduce the complexity of the pore structure of the air voids (500-9000 nm).

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.85-92
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• 2003

Generally, ordinary portland cement(OPC) is widely used for grouting to reduce permeability of ground under the foundations of structures. But, it is hard to be injected into the microscopic voids, fissures and crevices in soil or rock formation for the OPC material. Therefore new method what is called MSG(Micro Silica Grouting) has been developed recently to improve the weak point of the OPC material. In this case study, in order to verify performance of the MSG's water cut-off, trial injections were performed in rear of CIP(Cast in Place Pile) on the site A(weathered soil) and B(alluvial soil) that are constructed for the subway No. 9 nowadays. To take the proper grouting method of the MSG in the trial injecting, the injections are carried out for grouting types(constant pressure or fixed Quantity) and grouting methods(1.5shot or 2.0shot) and to confirm the effects of water cut-off and the injection range of the MSG, the tests of permeability and indicator(phenolphthalein) response were performed before and after the injection. Through the tests results, we could affirm the effects of water cut-off of the MSG and the injection range for the weathered and alluvial soil layers near the Han River. Finally we could make sure the application of the MSG method in actual construction under the layers.

• Transactions of Materials Processing
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• v.19 no.8
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• pp.480-485
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• 2010

In this work, the closing behavior of cylindrical-shaped voids was experimentally investigated according to various parameters such as reduction ratio in height, initial void size and billet rotation during hot open die forging process. The reduction ratio in height, number of path, and billet rotation were chosen as key process parameters which influence the void closing behavior including the change of void shape and size. On the other hand, values of die overlapping and die width ratio were set to be constant. Void closing behavior was estimated by microscopic observation. Based on the observations, it was confirmed that application of billet rotation is more efficient to eliminate the void with less reduction ratio in height. The experimental results obtained from this study could be helpful to establish the optimum path schedule of open die forging process.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.649-652
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• 2006

This paper describe the performance of seawater purification, to which living organisms can adapt, and the physical properties of porous concrete with continuous void. Although conventional concrete has been regarded as a destroyer of nature, seawater and air can pass freely through concrete when it is made porous by forming continuous void. This not only enables plants to vegetables, but also makes it possible for microscopic animals and plants, including bacteria, to attach to and inhabit uneven surface as well as internal voids when the concrete is provided in a natural seawater area or seawater side area. As a result, porous concrete using recycled aggregate improved the performance of seawater purification. In this study, The performance of seawater purification of porous concrete using recycled aggregate analyzed by T-P, T-N.

• The Journal of Engineering Geology
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• v.12 no.1
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• pp.95-109
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• 2002

A significant question is what role does newly-formed expansive mineral growth play in the premature deterioration of concrete. These minerals formed in cement paste as a result of chemical reactions involving cement paste and coarse/fine aggregate. Petrographic observations and SEM/EDAX analysis were conducted in order to determine chemical and mineralogical changes in the aggregate and cement paste of samples taken from lowa concrete highways that showed premature deterioration. Formation and expansive mechanisms involved in deterioration were Investigated. Brucite, Mg(OH)$_2$, is potentially expansive mineral that farms in cement paste of concretes containing reactive dolomite aggregate as a result of partial dedolomitization of the aggregate. No cracking was observed to be spatially associated with brucite, but most brucite was microscopic in size and widely disseminated in the cement paste of less durable concretes. Expansion stresses associated with its growth at innumerable microlocations may be retrieved by cracking at weaker locations in the concrete. Ettringite, 3CaO.Al$_2$O$_3$.3CaSO$_4$.32$H_2O$, completely fills many small voids and occurs as rims lining the margin of larger voids. Microscopic ettringite is common disseminated throughout the paste in many samples. Severe cracking of cement paste causing premature deterioration is often closely associated with ettringite locations, and strongly suggests that ettringite contributed to deterioration. Pyrite, FeS2, is commonly present in coarse/fine aggregates, and its oxidation products is observed in many concrete samples. Pyrite oxidation provides sulfate ions for ettringite formation.