• Journal of the Korean Wood Science and Technology
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• 제20권4호
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• pp.57-64
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• 1992

The unique cell wall micropores of pulp fiber can be utilized as loading site in variety of important practical application which could be the basis of new papermaking technologies. One of these includes the manufature of paper containing higher levels of in situ filler precipitated. Hardwood pulp fiber were first impregnated with the solution of sodium carbonate($Na_2CO_3$). The micropores in cell wall of pulp fibers were filled with the liquid salt solution. The second calcium nitrate($Ca(NO_3)_2$) solution formed an insoluble calcium carbonate($CaCO_3$) precipitate within the cell wall micropores by interacting with the first sodium carbonate solution. The effects of chemical concentration and dryness of pulp fibers on the retention of cell wall micropore loaded filler were investigated. The paper properties of cell wall micropore loaded pulp fibers were compared with those of conventionally loaded and lumen loaded pulp fibers. Also the presense of the fillers within the cell wall micropore was observed by SEM. Increasing the chemical concentration to generate the calcium carbonate increased the retention of filler in cell wall micropore loaded pulp fibers. The particle size distribution of precipitated calcium carbonate ranged from $0.1{\mu}m$ to $80{\mu}m$. But, the average particle size of cell wall micropore loaded calcium carbonate was $4{\mu}m$. The paper made from never dried pulp fibers, the cell wall micropores which were filled with calcium carbonate, had better mechanical and optical properties than those of conventionally loaded or lumen loaded pulp fibers.

• Carbon letters
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• 제13권4호
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• pp.236-242
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• 2012

Poly(vinylidene chloride) (PVDC)-derived nanoporous carbons were prepared by various activation methods: heat-treatment under an inert atmosphere, steam activation, and potassium hydroxide (KOH) activation at 873, 1073, and 1273 K. The pore structures of PVDC-derived nanoporous carbons were characterized by the $N_2$ adsorption technique at 77 K. Heat treatment in an inert atmosphere increased the specific surface area and micropore volume with elevating temperature, while the average micropore width near 0.65 nm was not significantly changed, reflecting the characteristic pore structure of ultramicroporous carbon. Steam activation for PVDC at 873 and 1073 K also yielded ultramicroporosity. On the other hand, the steam activated sample at 1273 K had a wider average micropore width of 1.48 nm, correlating with a supermicropore. The KOH activation increased the micropore volume with elevating temperature, which is accompanied by enlargement of the average micropore width from 0.67 to 1.12 nm. The average pore widths of KOH-activated samples were strongly governed by the activation temperature. We expect that these approaches can be utilized to simply control the porosity of PVDC-derived nanoporous carbons.

• 한국진공학회지
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• 제2권4호
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• pp.491-500
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• 1993

The adsorption of nitrogen (77K) and carbon dioxide(273K) was performed on a series of activated carbon fiber. Theadsorption iotherm of nitrogen was typical type 1 and that of carbon dioxide was convex. As the specific surface area increases, there are linear increases in BET constant C mean pore diameter, the width of pore size distribution, wide micropore volume, total micropore volume, total pore volume and external surface area, however, narrow micropore volume was nealy constant . The total micorpore volume fraction in total pore volume is above 97%.

• Carbon letters
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• 제7권3호
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• pp.161-165
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• 2006

Activated carbon fiber could be prepared at 973 K by catalytic activation using potassium hydroxide. Phenol resin fiber (Kynol) was impregnated with potassium hydroxide ethanol solution, carbonized and activated at 973 K, resulting in activated carbon fibers with different porosities. The potassium hydroxide accelerated the activation of the fiber catalytically to form narrow micropore preferentially in carbon dioxide atmosphere. The narrow micropore volume of 0.3~0.4 cc/g, total pore volume of 0.3~0.8 cc/g, mean pore width of 0.5~0.7 nm was obtained in the range of 20~50% burnoff.

• 한국산업보건학회지
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• 제24권2호
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• pp.193-200
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• 2014

Objectives: To develop domestic charcoal tubes with good adsorption capacity, breakthrough experiments were performed on four types of activated charcoal. Materials: The adsorption capacity and the adsorption rate were determined using a modified Wheeler equation after the breakthrough experiment. For four types of charcoal (J, K, S and SKC Inc. 226-01), 100 mg were used in the breakthrough experiment. The test was done on benzene, toluene, n-hexane, and acetone in a dynamic chamber. Results: K charcoal had the greatest surface area and the highest micropore volume. J charcoal had a similar surface area and micropore volume to SKC charcoal. S charcoal had the lowest surface area and micropore volume. J charcoal had the highest adsorption capacity at 101, 252 and 609 ppm of benzene. The gap in benzene adsorption capacity among the types of charcoal was the least at 609 ppm and the greatest at 101 ppm. J charcoal showed the highest adsorption capacity at 54, 106, 228 and 508 ppm of toluene. J charcoal and SKC charcoal had a similar adsorption capacity for acetone. J charcoal had the highest adsorption capacity for n-hexane. In the experiment featuring 10% breakthrough volume, 10% breakthrough occurred at 18 liters at $2065.9mg/m^3$ for J charcoal and at 20 liters at $1771.2mg/m^3$ for K charcoal. It was difficult to judge adsorption capacity by surface area and micropore volume of charcoal. J charcoal, which was similar to SKC charcoal in surface area and micropore volume, showed good adsorption capacity at common workplace concentrations. Conclusions: The adsorption capacity of J and K charcoal was superior compared with SKC charcoal. J and K charcoal can be considered appropriate for use as sampling media based on this result.

• 환경위생공학
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• 제17권3호
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• pp.99-109
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• 2002

Charcoal $tube/CS_2$ method are more popularly used than any other in the measurement of the working environment for the exposure evaluation of organic solvent, but it is some weak points that the lower accuracy can be obtained on the polar materials and within the range of the low concentration. Thus solvent desorption method has been developed to make accuracy higher and to overcome some weak points. However, because of high price of adsorption tube for thermal desorption and the short of study on its application to the working environment, it is not popularly used in the domestic industrial hygiene fields. This dissertation aims to develop thermal desorption and adsorption tubes for measuring organic solvents in the working environment, by comparing and analyzing breakthrough condition and adsorption capacity with ACF. Specific surface area of ACF used in this study is wider than the one of AC and micropore of ACF related with adsorption has been developed, and adsorption velocity and adsorption amount are very excellent by linking a pore of surface and an inside well into micropore. 1. Result of analysis on physical characteristics of adsorbent, the specific surface area of ACF was 1.3 times higher than that of AC. Distribution ratio of micropore related to adsorption was 94% on ACF and AC. Result of SEM, micropore of the AC is opened to the surface. In contrast, ACF shows that extremely fast adsorption speed. Because of micropore are exposed on the surface and penetrate through each other. 2. Breakthrough characteristics of adsorbents was not different from slop of breakthrough curve. The effluent concentration reaches 10% of initial concentration($C_{out}/C_{in}=0.1$, break point) of ACF was 30~316min longer than that of AC. Therefore, the adsorption capacities of ACF was 1.1~4.6 times higher than that of AC. ACF can be used as a proper adsorbent for measurement of organic solvent.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1507-1510
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• 2011

In this study, mercury vapor adsorption behaviors for some kinds of porous materials having various pore structures were investigated. The specific surface area and pore structures were studied by BET and D-R plot methods from $N_2$/77 K adsorption isotherms. It was found that the micropore materials (activated carbons, ACs) showed the highest mercury adsorption capacity. In a comparative study of mesoporous materials (SBA-15 and MCM-41), the adsorption capacity of the SBA-15 was higher than that of MCM-41. From the pore structure analysis, it was found that SBA-15 has a higher micropore fraction compared to MCM-41. This result indicates that the mercury vapor adsorptions can be determined by two factors. The first factor is the specific surface area of the adsorbent, and the second is the micropore fraction when the specific surface areas of the adsorbent are similar.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 추계 학술논문 발표대회
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• pp.129-130
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• 2014

In the case of concrete structures which have been recently exposed to the marine environment, durability is greatly reduced by the freezing-thawing action. When it is used by appropriately replacing the ground granulated blast-furnace slag(GGBS) that is a industrial by-product, the concrete structure of marine environment is known to have a durability to freezing-thawing resistance. In this experiment, micropore in accordance with a replacement ratio of GGBS was confirmed to show different results respectively. The freeze-thaw resistance was showed different aspects respectively because it is different the amount of water in the pore due to the difference of micropore. Therefore, in this study, the freezing-thawing resistance of sea water by variation of micropores of slag concrete had been evaluated.

• 한국연초학회지
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• 제16권2호
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• pp.181-190
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• 1994

Various active carbons were made from plant sources of coconut shell, pine tree, oak tree and lignite coal. Pore characteristics of these adsorbents were investigated. 1, With increasing activation time, specific surface area and pore volume increased, but the development of micropores was limited at a certain level. The average pore diameter, by BET, of coconut active carbon was 15.5-21.8$\AA$ and that of lignite carbon was 15.6-31.3$\AA$. The pore diameters of silica-gel, sepiolite and zeolite was 30.9$\AA$, 58.6$\AA$ and 55.7$\AA$, respectively. 2. The Horvath - Kawazoe micropore diameter of coconut shell active carbon was under 10.5$\AA$ and that of the other active carbon was under 20.9$\AA$ but silica-gel 33$\AA$, sepiolite 103 $\AA$ and zeolite was unexpectedly large to be 175$\AA$. From the difference between BET micropore diameter and Howath - Kawazoe diameter, it could be said that silica - gel has comparatively uniform pore diameter but sepiolite and zeolite have very uneven diameter. 3. Total pore volume of coconut shell active carbon was 0.27-1.04 cm3/g but that of the other active carbon, 0.23-0.62 cm3/g, was much lower than that of coconut shell active carbon. Hydrophilic adsorbent silica - gel and sepiolite showed big difference in specific surface area, but pore volumes of these were 0.47 and 0.56 cm3/g showing similar value and micropore volumes of these were, respectively, 0.06 cm3/g and 0.04 cm3/g. Total pore volume of zeolite was 0.1 cm3/g and that of micropore was only 0.02 cm3/g.

• 분석과학
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• 제13권1호
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• pp.89-95
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• 2000

식물섬유, 합성섬유 및 혼합섬유를 원료로 하여 3등급의 활성탄소섬유를 제조하고 미세기공 및 세공특성을 검토하였다. 제조한 활성탄소섬유의 흡착등온선은 모두 $20{\AA}$ 이하의 기공크기를 나타내는 Type I을 보였으며 미세기공 직경은 $5.6{\pm}0.3{\AA}$ 이내에서 최대 분포를 나타냈다. 활성탄소섬유의 질소 또는 아르곤 흡착에 의한 비표면적($S_{BET}$), 산화율, 액상 요오드흡착에 대한 상관 관계를 조사한 결과 비표면적이 $1600m^2g^{-1}$까지는 비표면적의 증가와 액상 요오드흡착량이 직선 관계를 나타냈으나 그 이상의 비표면적에서는 요오드 흡착량이 낮은 결과를 보이고, 비표면적이 증가할수록 제품의 burn-off가 크게 나타났다.