• Title/Summary/Keyword: Microcellular polymer

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Effect of the $CO_2$ on Viscosity Change in Continuous Microcellular Foaming Processing (초미세 발포 연속공정을 위한 $CO_2$ 사용이 재료의 점도변화에 미치는 영향)

  • 문용락;차성운
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1394-1397
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    • 2003
  • The first thing in developing injection molding and extrusion with microcellular foaming process is to get a grip on one phase state's rheology of gas and polymer solution. Understanding rheology is essential to design mold or die. and it is so important to control the condition of process. Also, this data is got the utmost out of simulation carrying out. In this paper, we will see the measurement of rheology in one phase that mixed polypropylene which contains talc with carbon dioxide of super critical fluid state, and will compare its result with the simulation result.

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The Viscosity Change of ABS Resin According to Inert Gas Amount (가스의 용해량에 따른 ABS 수지의 점도 변화)

  • 정태형;하영욱;정대진
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.585-590
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    • 1997
  • Conventional foaming process has defects such as lower mechanical properties than ur~foaming material due to non-uniform cell distribution and environmental pollution problem caused by chemical blowing agency. So, a new foaming process such as Microcelluar plastics has been introduced to use inactive gases as a foaming agency. In order to apply Microcellular plastics for mass production process system such as extrusion, injection molding and blow molding, it needs to predict the change in material properties of polymer according to the amount of meltingas. In Polymer molding applying Microcelluar plastics, the change of viscosity among several material properties is the most important factor. Therefore, this paper is aimed to establish the method which not only finds out but also predicts the change of viscosity of ABS(Acrylonitri1e Butadiene Styrene) resin according to inert gas amount in extrusion molding.

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The Foaming Characteristics of Microcellular Processing with Polypropylene in Semicrystalline States (결정성 수지의 발포특성)

  • Lee, Bo-Hyoung;Cha, Sung-Woon;Yoon, Jae-Dong
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1828-1833
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    • 2003
  • In a foaming process of microcellular plastics (MCPs) with a batch process, amorphous plastics and crystalline plastics have different characteristics for a foaming temperature. It is known that a foaming of amorphous plastics occurs at the temperature above a glass transition temperature, however, it is discovered that crystalline plastics do not take place above a glass transition temperature without exception, and even though the foaming occurs, it does not in all the range. In this research, to measure foaming temperature of crystalline polymer, a foaming experiment was performed using one of the typical crystalline polymer, polypropylene. To analyze whether the foaming occurs both at amorphous and crystalline fields, SEM was applied

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Measurement of Gas Solubility and Mechanical Property for Bumper Polymer (범퍼용 수지의 gas용해도 및 물성 측정)

  • 이정주;차성운;이경수
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1366-1369
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    • 2003
  • Today, the industries use polymer material for many purpose. Specially, it is important in automobile industry because tile costs of polymer hold high proportion of the overall cost. If we reduce the weight of automobile, fuel efficiency of car is raised and cost of bumper is lower. Therefore there are many efforts to reduce of car currently. The purpose of this paper is to reduce polymer used in car bumper.

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Preparation and Characterization of Polypropylene/Waste Ground Rubber Tire Powder Microcellular Composites by Supercritical Carbon Dioxide

  • Zhang, Zhen Xiu;Lee, Sung-Hyo;Kim, Jin-Kuk;Zhang, Shu Ling;Xin, Zhen Xiang
    • Macromolecular Research
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    • v.16 no.5
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    • pp.404-410
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    • 2008
  • In order to obtain 'value added products' from polypropylene (PP)/waste ground rubber tire powder (WGRT) composites, PP/WGRT microcellular foams were prepared via supercritical carbon dioxide. The effects of blend composition and processing condition on the cell size, cell density and relative density of PP/WGRT micro-cellular composites were studied. The results indicated that the microcellular structure was dependent on blend composition and processing condition. An increased content of waste ground rubber tire powder (WGRT) and maleic anhydride-grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) reduced the cell size, and raised the cell density and relative density, whereas a higher saturation pressure increased the cell size, and reduced the cell density and relative density. With increasing saturation temperature, the cell size increased and the relative density decreased, whereas the cell density initially increased and then decreased.

Foaming of Poly(butylene succinate) with Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 Poly(butylene succinate) 발포)

  • Son, Jae-Myoung;Song, Kwon-Bin;Kang, Byong-Wook;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.34-40
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    • 2012
  • The foaming of poly(butylene succinate) (PBS) using supercritical $CO_2(scCO_2)$ was studied. In order to improve the melt strength, PBS was modified using the reactive compounding technique. Rapid decompression of $scCO_2$-saturated PBS at a temperature above the depressed $T_m$ yielded expanded microcellular foams. The resulting foam structure could be controlled by manipulating process conditions. Experiments varying the foaming temperature while holding other variables constant showed that higher temperatures produced larger cells and reduced cell densities. Higher saturated pressures led to higher nucleation densities and smaller cell sizes. Decreasing the rate of depressurization permitted a longer period of cell growth and therefore larger cells were obtained.

Morphology and Properties of Microcellular foams by High Infernal Phase Emulsion Polymerization: Effect of Emulsion Compositions (HIPE 중합에 의한 미세기공 발포체의 모폴로지 및 물성: 유화계 조성의 영향)

  • 정한균;지수진;이성재
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.759-766
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    • 2002
  • Regular, spherical and isotropic open-microcellular foams having low density were prepared by the high internal phase emulsion (HIPE) polymerization mainly composed of styrene monomer and water The effects of Polymerization conditions. such as the content of water, divinylbenzene as a crosslinking agent and dodecane as a chain transfer agent, were investigated based on the tell size and foam properties. The microstructural morphology was observed using scanning electron microscopy (SEM) and the compression modulus of the foam was evaluated using compression test. The dropwise feeding of the aqueous phase into the oil phase was more effective than the batch feeding in producing the uniform and stable foam. Agitation speed and surfactant strongly influenced on the cell size and the window size between water droplets. Introduction of chain transfer agent increased the cell size, whereas it decreased the window size. Compression modulus increased with the crosslinking agent, but decreased with the chain transfer agent.