• 제목/요약/키워드: Microcellular polymer

검색결과 46건 처리시간 0.033초

초미세 발포 연속공정을 위한 $CO_2$ 사용이 재료의 점도변화에 미치는 영향 (Effect of the $CO_2$ on Viscosity Change in Continuous Microcellular Foaming Processing)

  • 문용락;차성운
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.1394-1397
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    • 2003
  • The first thing in developing injection molding and extrusion with microcellular foaming process is to get a grip on one phase state's rheology of gas and polymer solution. Understanding rheology is essential to design mold or die. and it is so important to control the condition of process. Also, this data is got the utmost out of simulation carrying out. In this paper, we will see the measurement of rheology in one phase that mixed polypropylene which contains talc with carbon dioxide of super critical fluid state, and will compare its result with the simulation result.

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가스의 용해량에 따른 ABS 수지의 점도 변화 (The Viscosity Change of ABS Resin According to Inert Gas Amount)

  • 정태형;하영욱;정대진
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 추계학술대회 논문집
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    • pp.585-590
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    • 1997
  • Conventional foaming process has defects such as lower mechanical properties than ur~foaming material due to non-uniform cell distribution and environmental pollution problem caused by chemical blowing agency. So, a new foaming process such as Microcelluar plastics has been introduced to use inactive gases as a foaming agency. In order to apply Microcellular plastics for mass production process system such as extrusion, injection molding and blow molding, it needs to predict the change in material properties of polymer according to the amount of meltingas. In Polymer molding applying Microcelluar plastics, the change of viscosity among several material properties is the most important factor. Therefore, this paper is aimed to establish the method which not only finds out but also predicts the change of viscosity of ABS(Acrylonitri1e Butadiene Styrene) resin according to inert gas amount in extrusion molding.

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결정성 수지의 발포특성 (The Foaming Characteristics of Microcellular Processing with Polypropylene in Semicrystalline States)

  • 이보형;차성운;윤재동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1828-1833
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    • 2003
  • In a foaming process of microcellular plastics (MCPs) with a batch process, amorphous plastics and crystalline plastics have different characteristics for a foaming temperature. It is known that a foaming of amorphous plastics occurs at the temperature above a glass transition temperature, however, it is discovered that crystalline plastics do not take place above a glass transition temperature without exception, and even though the foaming occurs, it does not in all the range. In this research, to measure foaming temperature of crystalline polymer, a foaming experiment was performed using one of the typical crystalline polymer, polypropylene. To analyze whether the foaming occurs both at amorphous and crystalline fields, SEM was applied

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범퍼용 수지의 gas용해도 및 물성 측정 (Measurement of Gas Solubility and Mechanical Property for Bumper Polymer)

  • 이정주;차성운;이경수
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.1366-1369
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    • 2003
  • Today, the industries use polymer material for many purpose. Specially, it is important in automobile industry because tile costs of polymer hold high proportion of the overall cost. If we reduce the weight of automobile, fuel efficiency of car is raised and cost of bumper is lower. Therefore there are many efforts to reduce of car currently. The purpose of this paper is to reduce polymer used in car bumper.

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Preparation and Characterization of Polypropylene/Waste Ground Rubber Tire Powder Microcellular Composites by Supercritical Carbon Dioxide

  • Zhang, Zhen Xiu;Lee, Sung-Hyo;Kim, Jin-Kuk;Zhang, Shu Ling;Xin, Zhen Xiang
    • Macromolecular Research
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    • 제16권5호
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    • pp.404-410
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    • 2008
  • In order to obtain 'value added products' from polypropylene (PP)/waste ground rubber tire powder (WGRT) composites, PP/WGRT microcellular foams were prepared via supercritical carbon dioxide. The effects of blend composition and processing condition on the cell size, cell density and relative density of PP/WGRT micro-cellular composites were studied. The results indicated that the microcellular structure was dependent on blend composition and processing condition. An increased content of waste ground rubber tire powder (WGRT) and maleic anhydride-grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) reduced the cell size, and raised the cell density and relative density, whereas a higher saturation pressure increased the cell size, and reduced the cell density and relative density. With increasing saturation temperature, the cell size increased and the relative density decreased, whereas the cell density initially increased and then decreased.

초임계 이산화탄소를 이용한 Poly(butylene succinate) 발포 (Foaming of Poly(butylene succinate) with Supercritical Carbon Dioxide)

  • 손재명;송권빈;강병욱;이광희
    • 폴리머
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    • 제36권1호
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    • pp.34-40
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    • 2012
  • 초임계 $CO_2(scCO_2)$를 사용하여 poly(butylene succinate) (PBS)를 발포하였다. PBS는 용융 강도를 높이기 위하여 반응 컴파운딩 기법으로 개질하였다. $scCO_2$로 포화된 PBS를 강하 융점 이상의 온도에서 빠르게 압력을 낮춤으로써 미세기포 발포체를 제조하였다. 발포체의 구조는 공정 조건을 변화시켜 제어할 수 있었다. 다른 변수들은 고정하고 발포 온도만 변화시킨 실험은 발포 온도가 높을수록 셀 크기는 증가하고, 셀 밀도는 감소함을 보여주었다. 포화 압력이 클수록 기핵 밀도가 높아졌으며, 그 결과로 셀의 크기는 감소하였다. 감압 속도가 느린 경우에는 셀이 장시간 동안 팽창함으로써 보다 큰 셀이 얻어졌다.

HIPE 중합에 의한 미세기공 발포체의 모폴로지 및 물성: 유화계 조성의 영향 (Morphology and Properties of Microcellular foams by High Infernal Phase Emulsion Polymerization: Effect of Emulsion Compositions)

  • 정한균;지수진;이성재
    • 폴리머
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    • 제26권6호
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    • pp.759-766
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    • 2002
  • 스티렌과 물이 주된 원료로 구성된 혼합물을 high internal Phase emulsion (HIP보) 중합을 통하여 균일한 구형의 등방성 구조로 이루어진 저밀도의 열린 구조 미세기공 발포체를 제조하였고, 물, 가교결합제인 divinylbenzene, 사슬이동제인 dodecane의 함량 변화 등의 중합조건이 미세기공발포체의 기공 크기 및 물성에 미치는 영향을 조사하였다. 제조한 HIPE 발포체의 미세구조 모폴로지를 확인하기 위하여 SEM 사진으로 관찰하였고 기계적 물성을 평가하기 위하여 압축시험으로 압축 탄성률을 측정하였다. 연구 결과 오일 상에 수용액 상을 주입할 때 한 방울씩 연속적으로 주입하는 연속투여 방식의 경우가 한번에 주입하는 일괄투여 방식의 경우보다 균일하고 안정한 발포체를 제조하는데 효과적이었다. 교반속도와 계면활성제는 기공 크기와 계면의 window 크기에 상당한 영향을 끼쳤다. 사슬이동제의 첨가는 기공 크기를 증가시켰지만 window 크기는 오히려 감소시켰다. 발포체의 압축 탄성률은 가교결합제의 함량이 증가할수록, 사슬이동제의 함량이 감소할수록 증가하였다.