• Journal of the Korean Society for Precision Engineering
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• v.17 no.3
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• pp.108-113
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• 2000

An important process for making a new class of polymeric material is called microcellular plastics invented at the Massachusetts Institute of Technology. Many researches for microcellular plastics have been done in various ways and fields. But a research for the polymer which has previous history has not been tried yet. In this paper, weight gain of $CO_2$ was measured in a polymer matrix which had previous history and no history. In each case, experimental data for solubility and diffusivity was shown. A model for $CO_2$ solution process in molecular range was made. The conclusion of this paper is that the previous history has an effect on diffusivity but not solubility and the previous history made by $CO_2$ in supercritical state makes diffusivity of $CO_2$ larger.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.10
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• pp.186-191
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• 2000

We use so many plastic products in everyday. Because polymer materials have a lot of merits including low cost and easiness of forming, they are widely using at many manufacturing industries. Microcellular foaming process appeared at MIT in 1980's to save a quantity of material and increase mechanical properties. The information about the thickness of cavity plays an important role in appling microcellular foaming process to the conventional injection molding process. It is essential to make an effective foam. The goal of this research is to measure the relation between the change of cavity's thickness and foaming magnitude made after inserting a gas. R/t is a conception that indicate proportion between radius and thickness of cavity in mold system. By means of SEM observation of side surface of cavity sample, foaming magnitude of cavity is mold system. By means of SEM observation of side surface of cavity sample, foaming magnitude of polymer in microcellular foaming process is decreasing gradually as the value of R/t is increasing. The proposed foaming magnitude changes data of polymer in relation to mold system can be applied in more extensive injection molding process, such as optimum design of mold for microcellular foaming process.

• Journal of the Korean Society for Precision Engineering
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• v.25 no.9
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• pp.71-77
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• 2008

Microcellular foaming plastics create a sensation at polymer industrial for lowering product costs and overcoming a lowering of mechanical intensity. Among many advantages, microcellular foaming plastics is well known to have a good acoustical properties. This research based on the experiment of sound absorption and transmission characteristics inquire into acoustical properties of microcellular foaming plastics. Difference of transmission loss of microcellular foaming plastics and solid materials was defined as cell effect. Also, cell effect is expressed by sound reflection and sound absorption. This study is expected to fundamental research to present economical, functional alternative plan for products using sound absorption and transmission materials.

• Polymer(Korea)
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• v.36 no.5
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• pp.579-585
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• 2012

Polystyrene/carbon nanotube (CNT) microcellular foams were prepared to have electrically conductive properties via high internal phase emulsion polymerization. In this study, we have investigated the effects of surface modification of CNT, surfactant content and dispersion time to improve the stability of emulsion and the electrical conductivity of foam. Acid treatment and a surfactant were used to effectively disperse CNTs in the aqueous phase. In the organic phase, CNTs were used after a surface modification with organic functional groups. The degree of dispersion of CNTs was estimated by the electrical conductivity of resultant microcellular foams. With raw CNTs dispersed with the surfactant in the aqueous phase, substantial conductivity increase was observed but the foams were slightly shrunk. The foams prepared with organically modified CNTs dispersed in the organic phase showed stable cell morphology without shrinkage, but displayed limitation to improve the conductivity.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.101-102
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• 2006

Processing techniques for producing microcellular silicon carbide, mullite, and cordierite ceramics have been developed by a reaction method that incorporates a polysiloxane and reactive fillers. The techniques developed in this study offer substantial flexibility for producing microcellular ceramics whereby cell size, cell density, degree of interconnectivity, composition, and porosity can all be effectively controlled. It is demonstrated that the adjustment of filler composition enables the possibility of tailoring the composition and properties of the microcellular ceramics. The present results suggest that the proposed novel processing techniques are suitable for the manufacture of microcellular ceramics with high morphological uniformity.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2007.06a
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• pp.423-424
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• 2007

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.6
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• pp.726-733
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• 2004

The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1114-1119
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• 2004

In a foaming process of microcellular plastics (MCPs) with a injection molding, research on the viscosity change that occurs when the gas is injected to the polymer has received little attention despite its importance. The purpose of this paper is to provide the basic data required to determine the processing condition by measuring viscosity changes against the gas injection rates of the blowing agent, and to verify the influence of the viscosity change on the flow condition of polymer inside the mold at the injection process.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.174-179
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• 2004

The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.4
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• pp.637-644
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• 2001

Polymer materials have a lot of merits including the low cost and the easiness of forming. For these reasons they are widely using at many manufacturing industries. Microcellular foaming process appeared at MIT in 1980s to save a quantity of material and increase mechanical properties. There are many process variables in appling microcellular foaming process to the conventional injection molding process. They can be solved by using Axiomatic Design Method which is very useful design method for designing a new product. Its main character is scientific and analytical. The information about the thickness of cavity plays an important role in making an effective foam. The goal of this research is to design mold system for advance of foaming magnitude with axiomatic design method. There is a relation between the change of cavitys thickness and foaming magnitude made after inserting a gas. R/t is a conception that indicate proportion between radius and thickness of cavity in mold system. By means of SEM observation of side surface of cavity sample, foaming magnitude of polymer in microcellular foaming process is decreasing gradually as the value of R/t is increasing. In this paper, an advanced mold system was presented by mapping the relation between functional requirements and design parameters.