• Title/Summary/Keyword: Micro-SOFC

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Modeling for the Performance Analysis of a Tubular SOFC/MGT Hybrid Power System (원통형 고체산화물 연료전지와 마이크로 가스터빈 하이브리드 시스템의 성능해석을 위한 모델링)

  • Song, T.W.;Sohn, J.L.;Kim, J.H.;Kim, T.S.;Ro, S.T.;Suzuki, K.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2070-2075
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    • 2004
  • Performance of a solid oxide fuel cell (SOFC) can be enhanced by converting thermal energy of its high temperature exhaust gas to mechanical power using a micro gas turbine (MGT). A MGT plays also an important role to pressurize and warm up inlet gas streams of the SOFC. In this study, the influence of performance characteristics of the tubular SOFC on the hybrid power system is discussed. For this purpose, detailed heat and mass transfer with reforming and electrochemical reactions in the SOFC are mathematically modeled, and their results are reflected to the performance analysis. The analysis target is 220kWe SOFC/MGT hybrid system based on the tubular SOFC developed by Siemens-Westinghouse. Special attention is paid to the ohmic losses in the tubular SOFC counting not only current flow in radial direction, but also current flow in circumferential direction through the anode and cathode.

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Performance Analysis of SOFC/MGT Hybrid System

  • Kim, Jae-Hwan;Suzuki, Kenjiro
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.703-707
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    • 2001
  • A performance analysis of a SOFC/MGT hybrid system has been carried out for concept design. Thermo-dynamic models for each component being able to describe electrochemical characteristics and heat and mate-rial balance are proposed. Estimated is the power capacity of a SOFC suitable for the hybrid operation with a 5kW class MGT. Effects of current density and operating pressure are also investigated. Electric efficiency showed weak dependence on operating pressure and current density. It is desirable that the SOFC operates at high current density in manufacturing cost's point of view though operating with high current density slightly decreases the electric efficiency find specific power.

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Fabrication and Evaluation Properties of Micro-Tubular Solid Oxide Fuel Cells (SOFCs) (마이크로 원통형 SOFC 제작 및 특성평가)

  • Kim, Hwan;Kim, Wan-Je;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.749-753
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    • 2012
  • In present work, anode support for micro-tubular SOFC was fabricated with outer diameter of 3 mm and characterized with microstructure, mechanical properties and gas permeability. The microstructure of surface and cross section of a porous anode support were analyzed by using SEM (Scanning Electron Microscope) image. The gas permeability and the mechanical strength of anode support was measured and analysed by using differential pressure at the flow rates of 50, 100, 150 cc/min. and using universal testing machine respectively. The unit cell composed of NiO-YSZ, YSZ, YSZ-LSM/LSM/LSCF was fabricated and operated with reaction temperature and fuel flow rate and showed maximum power density of $1095mW/cm^2$ on the condition of $800^{\circ}C$. The performance of single cell for micro-tubular SOFC increased with the increasing the reaction temperature due to the decrement of ohmic resistance of cell by the increment of the ionic conductivity of electrolyte through the evaluation of electrochemical impedance analysis for single cell with reaction temperature.

Fabrication of YSZ-based Micro Tubular SOFC Single Cell using Electrophoretic Deposition Process

  • Yu, Seung-Min;Lee, Ki-Tae
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.315-319
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    • 2015
  • Yttria-stabilized zirconia (YSZ)-based micro tubular SOFC single cells were fabricated by electrophoretic deposition (EPD) process. Stable slurries for the EPD process were prepared by adding phosphate ester (PE) as a dispersant in order to control the pH, conductivity, and zeta-potential. NiO-YSZ anode support, NiO-YSZ anode functional layer (AFL), and YSZ electrolyte were consecutively deposited on a graphite rod using the EPD process; materials were then co-sintered at $1400^{\circ}C$ for 4 h. The thickness of the deposited layer increased with increasing of the applied voltage and the deposition time. A YSZ-based micro tubular single cell fabricated by the EPD process exhibited a maximum power density of $0.3W/cm^2$ at $750^{\circ}C$.

In-Situ Fabrication of Micro-channeled Multi Tubular Solid Oxide Fuel Cell using Multi-pass Extrusion Process (다중압출 공정을 이용한 마이크로 채널 다중 원통형 고체산화물 연료전지의 in-situ 제조)

  • Byun, Ki-Cheon;Rahman, AHM Esfakur;Kim, Jong-Hee;Lee, Byong-Taek
    • Korean Journal of Materials Research
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    • v.17 no.6
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    • pp.313-317
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    • 2007
  • In-situ micro-channeled multi tubular solid oxide fuel cell(SOFC) was fabricated using multi-pass extrusion process with out side diameter of 2.7 mm and active length of 5 mm that contained 61 individual cells. Cell materials used in this work were NiO-YSZ (50 : 50 vol.%), 8 mol% yttria-stabilized zirconia(8YSZ), $La_{0.8}Sr_{0.2}MnO_3(LSM)$ as anode, electrolyte, and cathode, respectively. The arrangement of each electrode and electrolyte layer in green bodies showed uniformity and integrity after extrusion and sintering. The XRD analysis confirmed that no reaction phases appeared and the microstructure of the electrolyte was fairly dense (relative density > 96%) after sintering.

Performance Modeling of Single-Chamber Micro SOFC (단실형 마이크로 고체 산화물 연료전지의 작동특성 전산모사)

  • Cha, Jeong-Hwa;Chung, Chan-Yeup;Chung, Yong-Chae;Kim, Joosun;Lee, Jongho;Lee, Hae-Weon
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.854-859
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    • 2005
  • Performance of micro scale intermediate temperature solid oxide fuel cell system has been successfully evaluated by computer simulation based on macro modeling. Two systems were studied in this work. The one is designed that the ceria-based electrolyte placed between composite electrodes and the other is designed that electrodes alternately placed on the electrolyte. The injected gas was composed of hydrogen and air. The polarization curve was obtained through a series of calculations for ohmic loss, activation loss and concentration loss. The calculation of each loss was based on the solving of mathematical model of multi physical-phenomena such as ion conduction, fluid dynamics and diffusion and convection by Finite Element Method (FEM). The performance characteristics of SOFC were quantitatively investigated for various structural parameters such as distance between electrodes and thickness of electrolyte.

Evaluation of Micro-Tubular SOFC: Cell Performance with respect to Current Collecting Method (마이크로 원통형 SOFC 특성평가: 집전방식에 따른 단위전지의 전기화학적 특성)

  • Kim, Hwan;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.1
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    • pp.43-48
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    • 2012
  • This paper presents the characterization of micro-tubular SOFCs using three different anode current collecting methods of inlet current collection (IC), both current collection (BC) and total current collection (TC). The maximum power densities of SOFCs at $750^{\circ}C$ using IC, BC and TC were 56 mW/$cm^2$ (0.43 V, 0.13 A/$cm^2$), 236 mW/$cm^2$ (0.43 V, 0.55 A/$cm^2$) and 261 mW/$cm^2$ (0.43 V, 0.61 A/$cm^2$) respectively. It was confirmed by impedance spectroscopy that both the polarization resistance and the ohmic resistance were dramatically increased at SOFC with IC.

Gas Turbine and Fuel Cell Hybrid System for Distributed Power Generation (분산발전을 위한 가스터빈-연료전지 하이브리드 시스템)

  • Kim, Jae Hwan;Sohn, Jeong L.;Ro, Sung Tack;Kim, Tong Seop
    • 유체기계공업학회:학술대회논문집
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    • 2001.11a
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    • pp.354-360
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    • 2001
  • Hybrid energy system of fuel cell and gas turbine is discussed as the system to be used in the distributed power generation. Discussion is first directed to the distributed power generation system which is expected to be more popularly introduced both in urban and isolated areas. In the next some characteristic features of fuel cell and micro gas turbine are shortly described. In the last discussion is turn to the fuel cell and micro gas turbine hybrid system. In particular, performance characteristics of a representative SOFC/MGT hybrid system are investigated through the concept design at various power capacity levels.

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A Numerical study on current density and temperature distributions of IT-SOFC (IT-SOFC의 전류밀도 및 온도분포에 관한 수치해석 연구)

  • Sohn, Sang-Ho;Lee, Kyu-Jin;Nam, Jin-Hyun;Kim, Charn-Jung
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3067-3072
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    • 2008
  • A two-dimensional model for anode-supported IT-SOFCs is proposed in order to accurately consider the heat and mass transport processes with a fully-developed axial velocity profile in channel flow. A comprehensive micro model is employed to describe the electrochemical reaction in anode and cathode of SOFCs. This paper investigates the effects of operational parameters (inlet temperature, the amount of flow rate, and air flow rate) including flow configurations (co-flow and counter-flow) on the current density and temperature distributions in the IT-SOFCs.

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