• Title/Summary/Keyword: Micro pore

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Heat treatment induced morphological changes of $Ca^{++}$ implanted single crystal $Al_2O_3$ ($Ca^{++}$를 implant한 단결정 $Al_2O_3$에서 열처리에 의한 형태학적 변화)

  • 김배연
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.3
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    • pp.327-333
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    • 1999
  • Controlled Ca impurity implanted inner crack-like pore in the high purity alumina bi-crystal had been created by micro-fabrication technique, which includes ion implantation, photo-lithography, Ar ion milling, and hot press. The morphological change and the growth od crystals formed by heat treatment in Ca doped high purity single crystal alumina, were observed using optical microscopy. The dot was developed and hexagon like crystal appeared on inner surface of crack-like pore after heat treatment. Bar type crystals, probably CaO . $6Al_2O_3$, were observed on the inner surface of 100ppm Ca implanted specimen after 1 hour heat treatment at $1,500^{\circ}C$, but this bar type crystal disappeared after 1 hour heat treatment at $1,600^{\circ}C$. This disappearance means that there should be little increase of Ca solubility limit to alumina and/or changes of diffusion coefficient of Ca in alumina around this temperature.

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An Analysis of Pore Network of Drilling Core from Pohang Basin for Geological Storage of CO2 (이산화탄소 지중저장을 위한 포항분지 시추코어의 공극구조 분석)

  • Park, Jihwan;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.26 no.3
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    • pp.181-191
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    • 2016
  • In geological storage of $CO_2$, the behavior of $CO_2$ is influenced by pore network of rock. In this study, the drilling cores from Pohang Basin were analyzed quantitatively using three-dimensional images acquired by X-ray micro computed tomography. The porosities of sandstone specimens around 740 m-depth (T1), 780 m-depth (T2) and 810 m-depth (T3) which were target strata were 25.22%, 23.97%, 6.28%, respectively. Equivalent diameter, volume, area, local thickness of pores inside the sandstone specimens were analyzed. As a result, the microstructural properties of T1 and T2 specimens were more suitable for geological storage of $CO_2$ than those of T3 specimens. The result of the study can be used as input data of the site for decision of injection condition, flow simulation and so on.

An Experimental Study on the Water Repellent Property of Mortar Applied Water Repellent Agent of Inorganic Polymer Type (무기질 폴리머계 흡수방지재를 도포한 모르터의 발수성능 평가에 관한 실험적 연구)

  • 이일형;엄덕준;오상근
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2004.05a
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    • pp.33-37
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    • 2004
  • Recently, Growing tendency for structure surface to use water repellent agent has increased steadily. But investigation of it's protection and durability property is not sufficient. Therefore, this paper shows the investigation about repellent property and micro structure's change in surface layer of mortar that is applied by water repellent agent. Water repellent property, absorption coefficient, air permeability, porosity and observation of micro construct was investigated according to water repellent agent type. The test results indicated that mortar applied water repellent agent appears tiny absorption coefficient, but air permeability is maintained. The reason is because silane solution is coating at capillary surface of a wall and minute pore structure is changeless.

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Preparation and Properties of Waterborne Polyurethane-Urea/Poly(vinyl alcohol) Blends for High Water Vapor Permeable Coating Materials

  • Yun, Jong-Kook;Yoo, Hye-Jin;Kim, Han-Do
    • Macromolecular Research
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    • v.15 no.1
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    • pp.22-30
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    • 2007
  • High water vapor permeable coating materials were prepared by blending aqueous poly(vinyl alcohol) (PVA) solution with waterborne polyurethane-urea (WBPU) dispersions synthesized by prepolymer mixing process. Stable WBPU/PVA dispersions were achieved at PVA content below 30 wt%. As the water soluble polymer PVA content increased, the number and density of total micro-pores (tunnel-like/isolated micro-pores) formed after the dissolution of PVA in water increased, and the water vapor permeability of coated Nylon fabric also increased significantly. Using WBPU/water soluble polymer PVA blends as a coating material and then dissolving PVA in water was confirmed to be an effective method to obtain prominent breathable fabrics.

A Pilot study of poroelastic modulus measurement in micro-bone tissue (미세 골조직의 공극탄성계수 측정을 위한 예비 연구)

  • 박영환;홍정화
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1038-1041
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    • 2004
  • In this study, developed a micro-level experimental setup to measure pore pressure and poroelastic modulus in various strain and strain rate about a stress in micro-structure of bone tissue. It is essential device in the development of the model to analysis the interstitial bone fluid flow of the lacuno-canalicular system to be known that would effect on the bone remodeling. The constitution of the experimental setup is as follows, microscopic image processing system; actuator control unit; load measurement system. A pilot study was used an artificial chemical wood to have similar poroelastic property of bone matrix and conducted to validate the suitability of the measurement system.

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A Fundamental Characteristics for MiDF by Hydro-thermal Synthesis Reaction according to C/S Mole Ratio (수열합성된 MiDF의 C/S 몰비에 따른 기초특성)

  • Kim, Jin-Man;Choi, Sun-Mi;Lee, Do-Heun;Cho, Hong-Kwan;Choi, Young-Woo;Kang, Eun-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.75-76
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    • 2018
  • MiDF, Micro Defect Free concrete, is the concrete made for high strength development by minimizing the defects such as micro pore and ITZ. Since MiDF exhibits strength through hydro-thermal synthesis reaction, it is essential to select the optimum C/S mole ratio. In this study, the basic characteristics of MiDF were evaluated by controlling the C/S mole ratio by SF and QP.

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Net-shape Manufacturing of Micro Porous Metal Components by Powder Injection Molding

  • Nishiyabu, Kazuaki;Matsuzaki, Satoru;Tanaka, Shigeo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.93-94
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    • 2006
  • A novel production method for porous metal components has been developed by applying powder space holder (PSH) method to metal powder injection molding (MIM) process. The PSH-MIM method has an industrial competitive advantage that is capable of net-shape manufacturing the micro-sized porous metal products with complicated shapes and controlled porosity and pore size. In this study, the small impeller with homogeneous micro-porous structure was manufactured by the PSH-MIM method. The effects of combinations in size and fraction of PMMA particle on dimensional tolerance and variation of sintered porous specimens were investigated. It was concluded that the PSH-MIM method could manufacture commercially microporous metal components with high dimensional accuracy.

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Water Treatment Application of a Large Pore Micro-Filtration Membrane and Its Problems (대기공 정밀여과막의 수처리 응용 및 문제점)

  • Yun, Chang-Han;Kim, Jeong-Hak;Lee, Kang Won;Park, Sung Ho
    • Membrane Journal
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    • v.24 no.3
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    • pp.194-200
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    • 2014
  • The purpose of this study was to evaluate the performance of newly developed Large Pore Micro-Filtration (LPMF) membrane in Lab size for the application of water treatment, and to find its problems with solutions. The out-to-inside filtration hollow fiber LPMF membrane of which average pore size was $5{\mu}m$ was used at this study and its material was the PET braid reinforced PVDF. Filtration tests were done through gravity with 30 cm water head difference or pressure below 1.5 bar, and the backwash was done instantaneously with the filtrate after pressurizing it to about 4 bar. The water flux of the LPMF membrane with 0.2 bar TMP (Trans Membrane Pressure) was 2 times higher than $0.4{\mu}m$ MF membrane with $0.05{\mu}m$ UF filtrate of the tap water and it was measured also with 20~30 cm water head difference which showed over 800 LMH at 30 cm water head difference. And Time-To-Filter (TTF) was performed by using $5{\mu}m$ filter paper to optimize coagulants and dosage which enhanced filtrate's turbidity and stabilized filtration flux. When the LPMF was operated with 30 cm gravity with very high dose of inorganic coagulants, the flux was maintained over 80 LMH with 93.5~99.5% turbidity removal. Especially, the filtration was maintained stably in the flux and about 97% of the recovery rate by instantaneous pressurized backwash with about 4 bar of the filtrate when the packing density was about 19%. But there was instability in filtration, since the TMP was continuously going up by inefficient backwash when the packing density was 43%.

CNN Model for Prediction of Tensile Strength based on Pore Distribution Characteristics in Cement Paste (시멘트풀의 공극분포특성에 기반한 인장강도 예측 CNN 모델)

  • Sung-Wook Hong;Tong-Seok Han
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.5
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    • pp.339-346
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    • 2023
  • The uncertainties of microstructural features affect the properties of materials. Numerous pores that are randomly distributed in materials make it difficult to predict the properties of the materials. The distribution of pores in cementitious materials has a great influence on their mechanical properties. Existing studies focus on analyzing the statistical relationship between pore distribution and material responses, and the correlation between them is not yet fully determined. In this study, the mechanical response of cementitious materials is predicted through an image-based data approach using a convolutional neural network (CNN), and the correlation between pore distribution and material response is analyzed. The dataset for machine learning consists of high-resolution micro-CT images and the properties (tensile strength) of cementitious materials. The microstructures are characterized, and the mechanical properties are evaluated through 2D direct tension simulations using the phase-field fracture model. The attributes of input images are analyzed to identify the spot with the greatest influence on the prediction of material response through CNN. The correlation between pore distribution characteristics and material response is analyzed by comparing the active regions during the CNN process and the pore distribution.

Characterization of metal-containing activated carbon derived from phenolic resin (페놀 수지로부터 유도된 금속이 함유된 활성탄의 특성화)

  • Oh, Won-Chun;Jang, Won-Cheoul;Kim, Bum-Soo
    • Analytical Science and Technology
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    • v.14 no.4
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    • pp.349-355
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    • 2001
  • A series of micro- and mesoporous activated carbons were prepared from phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than $962.3m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides($CdCl_2$, $CuCl_2$). Pore evolvement was shown to be most effected by the incremental addition of metal chloride. From the thermodynamic DSC data, enthalpy formations(${\Delta}H$) of first endothermic reaction were increase with the incremental addition of metal chloride.

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