• Title/Summary/Keyword: MgO/Fe ratio

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Fabrication and Magnetic Properties of Mg and BaFe12O19 Ferromagnetic Composite Powders by Mechanical Alloying (기계적합금화법에 의한 Mg-BaFe12O19 계 강자성 복합분말의 제조 및 자기특성)

  • Lee, Chung-Hyo
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.61-67
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    • 2021
  • Fabrication of a ferromagnetic composite powder for the magnesium and BaFe12O19 system by mechanical alloying (MA) is investigated at room temperature. Mixtures of Mg and BaFe12O19 powders with a weight ratio of Mg:BaFe12O19 = 4:1, 3:2, 2:3 and 1:4 are used. Optimal MA conditions to obtain a ferromagnetic composite with fine microstructure are investigated by X-ray diffraction, differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM) measurement. It is found that Mg-BaFe12O19 composite powders in which BaFe12O19 is dispersed in Mg matrix are successfully produced by MA of BaFe12O19 with Mg for 80 min. for all compositions. Magnetization of Mg-BaFe12O19 composite powders gradually increases with increasing the amounts of BaFe12O19, whereas coercive force of MA powders gradually decreases due to the refinement of BaFe12O19 powders with MA time for all compositions. However, it can be seen that the coercivity of Mg-BaFe12O19 MA composite powders with a weight ratio of Mg:BaFe12O19=4:1 and 3:2 for MA 80 min. are still high, with values of 1260 Oe and 1320 Oe compared to that of Mg:BaFe12O19=1:4. This clearly suggests that the refinement of BaFe12O19 powders during MA process for Mg:BaFe12O19=4:1 and 3:2 tends to be suppressed due to ductile Mg powders.

Compositional Change of MgO Barrier and Interface in CoFeB/MgO/CoFeB Tunnel Junction after Annealing

  • Bae, J.Y.;Lim, W.C.;Kim, H.J.;Kim, D.J.;Kim, K.W.;Kim, T.W.;Lee, T.D.
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.25-29
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    • 2006
  • Recent experiments have demonstrated high TMR ratios in MTJs with the MgO barrier [1,2]. The CoFeB/MgO/CoFeB junctions showed better properties than the CoFe/MgO/CoFe junctions because the MgO layer had a good crystalline structure with (001) texture and smooth and sharp interface between CoFeB/MgO [3]. The amorphous CoFeB with 20 at%B starts the crystallization at $340^{\circ}C$ [4] and this crystallization of the CoFeB helps obtaining the high TMR ratio. In this work, the compositional changes in the MgO barrier and at the interface of CoFeB/MgO/CoFeB after the CoFeB crystallization were studied in annealed MTJs. XPS depth profiles were utilized. TEM analyses showed that the MgO barrier had (100) texture on CoFeB in the junctions. B in the bottom CoFeB layer diffused into the MgO barrier and B-oxide was formed at the interface of CoFeB/MgO/CoFeB after the CoFeB crystallization.

Synthetic Properties of Fe/MgO Catalyst on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.3
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    • pp.133-141
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    • 2004
  • The synthetic behaviors of carbon nanotubes (CNTs) by Fe/MgO catalysts were investigated in 0~90 wt.% range of MgO mixture ratios by catalytic chemical vapor deposition (CCVD) process. The CNTs were synthesized with 40 minutes of synthetic time, and 923 K of synthetic temperature using 0.1 L/min of ethylene gas and 1.0 L/min of hydrogen gas as synthetic and carrier gas, respectively. As the increase of synthetic temperatures and times, the diameters of CNTs become thicker. The carbon yield showed in a parabolic curve as MgO content increased and the maximum carbon yield was obtained at 30 wt.% of MgO. There were no obvious changes in the diameters of CNTs respect to the change of MgO content. Fe/MgO CNTs showed good crystalinity by High Resolution Transmission Electron microscope (HR-TEM) analysis. The behaviors of Fe/MgO CNTs have a tendency of depending on synthetic time and temperature rather than MgO content.

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Effect of Fe2+/Fe3+ Ratio on the Crystallization of the Scoria Glass (CaO-MgO-Al2O3-SiO2 System) (Scoria 유리(CaO-MgO-Al2O3-SiO2계)의 결정화에 미치는 Fe2+/Fe3+비 효과)

  • 최병현;지응업
    • Journal of the Korean Ceramic Society
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    • v.26 no.5
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    • pp.705-711
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    • 1989
  • The glass-ceramics was prepared with the scoria(CaO-MgO-Al2O3-SiO2 system) of the locally occurring volcanic ejecta containing 10-13w/o of (FeO+Fe2O3) by melting at 140$0^{\circ}C$ for 4 hours and thermally treated for nucleation and crystallization. The sucrose was added to the scoria to adjust the Fe2+/Fe3+ ratio during the melting process. The addition of 1-2w/o of sucrose showed the glass-ceramics body with the finest particle developed and dispersed over the entire range. It is concluded that the impurity content of iron oxide and titanium oxide play the most-influencial effect on the crystallization. When 1-2w/o of sucrose was added to the scoria, the value of Fe2+/Fe3+ ratio was 0.93-1.32 and showed the best result of crystallization. The nucleation temperature and time were calculated by the measurements of exothermic peak temperatures of DTA for quenched and thermally treated glasses. The nucleation temperature of scoria glass without the addition of sucrose was estimated as 75$0^{\circ}C$, but the addition of sucrose by 2w/o showed the nucleation temperature 6$25^{\circ}C$. The nucleation time was calculated with the same DTA curves. The nucleation times estimated were about 150min. for both of glasses without and with sucrose added. Finally, the activation energies for crystallization were calculated with the DTA data. The calculated activation energies were 143 Kcal/mole for the glass without addition of sucrose and 90Kcal/mole, 87Kcal/mole, 85Kcal/mole and 71Kcal/mole for the glasses of 1w/o, 2w/o, 3w/o and 4w/o addition respectively.

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A study for use a vanadium oxide in steel manufacture (제강 공정중 산화바나듐활용 연구)

  • Choi, Young-Key
    • Journal of environmental and Sanitary engineering
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    • v.24 no.3
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    • pp.55-61
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    • 2009
  • Fe-V is used as raw material of vanadium in the steel making process. The purpose of this study, Fe-V is to replace the $VO_{4}$. So the distribution behavior of vanadium in $VO_{4}$ of the steel investigated. The distribution ratio of the vanadium where potential of the free oxygen ion will increase in slag decreased. When CaO and MgO content which is a basic oxide from CaO-$SiO_2$-FetO-MgOsatd. slag increases, S distribution ratio increases. CaO-$SiO_2$-FetO-MgOsatd. slag better than CaO-$SiO_2$-$Al_2O_3$-MgO slag is the recovery of vanadum and desulfurization.

Epitaxial Growth of MgO and CoFe/MgO on Ge(001) Substrates by Molecular Beam Epitaxy

  • Jeon, Kun-Rok;Park, Chang-Yup;Shin, Sung-Chul
    • Proceedings of the Korean Magnestics Society Conference
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    • 2009.12a
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    • pp.190-190
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    • 2009
  • We report the epitaxial growth of MgO and CoFe/MgO on Ge (001) substrates using molecular beam epitaxy. It was found that the epitaxial growth of a MgO film on Ge could be realized at a low growth temperature of $125{\pm}5^{\circ}C$ and the MgO matches the Ge with a cell ratio of $\sqrt{2}$:1 which renders MgO rotated by $45^{\circ}$ relative to Ge. In-situ and ex-situ structural characterizations reveal the epitaxial crystal growth of bcc CoFe/MgO on Ge with the in-plane crystallographic relationship of CoFe(001)[100] || MgO(001)[110] || Ge(001)[100], exhibiting sharp interfaces in the (001) matching planes. The saturation magnetization of the sample is $1430{\pm}20$ emu/cc, which is comparable to the value of bulk CoFe.

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A Study on the Effect of Reducing the Saturation Magnetization by Substituting the Non magnetic Ion in Mg Mn Ferrites (Mg-Mn훼라이트의 비자성 이온첨가에 의한 포화자화 감소효과)

  • Yu, Byeong-Du;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.117-124
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    • 1994
  • The reduction of saturation magnetization in the Mg-Mn microwave ferrites was achieved by substituting the non-magnetic A1 ion for Fe ion. It is necessary for extending the operation frequencies that there is no change in other properties of the microwave ferrites. The electrical and magnetic properties are characterized where the composition of the ferrites studied was given by the general formula $(MgO)_{1.0}(MnO)_{0.1}(Al_xFe_{1.9-x}O_{2.85}$ with x ranging from 0.1 to 0.4. The saturation magnetization and the ferromagnetic resonance linewidth was decreased by the substituting amount of $Al_2O_3$. The value of coercive field was low enough over the composition of x=O.2 and the high squareness ratio was obtained all over the amount of substitution. It is feasible to select the proper application area with the combination of various properties ; that is, low coercive field, high squareness ratio, optimum saturation magnetization and ferromagnetic resonance linewidth.

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The Study on Microstructure and Magnetic Properties of Ferrite with Various Fe Contents in $Mg_{1.9-2x}Mn_{0.05}Fe_{4x}O_{4+${\gamma}$}+2_{wt%} Al_2O_3$ ($Mg_{1.9-2x}Mn_{0.05}Fe_{4x}O_{4+${\gamma}$}+2_{wt%} Al_2O_3$ 조성내 Fe량 변화에 따른 페라이트의 미세구조 및 자기적 특성 연구)

  • 김성재;정명득;강대석
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.235-240
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    • 1994
  • The electric and magnetic properties of Mg1.9-2xMn0.05Fe4xO4+${\gamma}$+2wt% Al2O3, and its microstructure have been investigated as a function of ferrite composition (x=0.45, 0.5, 0.55). The microstructure turned out to be independent on the ferrite composition. The resistivity was decreased with increasing Fe contents, whereas the Curie temperature decreased. Saturation magnetization was varied from 1741 to 2022 G with composition, and squareness ratio (SR), coercive force (BHc) were decreased and increased with increasing Fe contents respectively, so the sample which SR and BHc were 0.97 Oe and 1.49 Oe can be attainable at x=0.45.

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The Study of Magnetic Structure of Ni1-xMgxFe2O4 Ferrite System by Mössbauer Spectroscopy (Mössbauer 분광법에 의한 Ni1-xMgxFe2O4 Ferrite의 자기구조 연구)

  • Yoon, In-Seop;Baek, Seung-Do
    • Journal of the Korean Magnetics Society
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    • v.19 no.3
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    • pp.106-112
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    • 2009
  • $Ni_{1-x}Mg_xFe_2O_4$ ferrite system was studied by using X-ray diffraction and $M{\ddot{o}}ssbauer$ spectroscopy. The samples were prepared by ceramic sintering method with Mg content x. The X-ray diffraction patterns of samples show phase of cubic spinel structure. There are no remarkable changes of lattice constants in $Ni_{1-x}Mg_xFe_2O_4$ ferrite system. The $M{\ddot{o}}ssbauer$ spectra were consisted of two sets of six lines, respectively, corresponding to $Fe^{3+}$ at tetrahedral and octahedral sites. The magnetic hyperfine field of samples was decreased as increasing Mg contents x in both sites and it was shown Yafet-Kittel magnetic structure. $NiFe_2O_4$ was shown complete inverse spinel, but $NiFe_2O_4$ was shown partial inverse spinel which absorption area ratio (oct/tet) was 1.449 in $M{\ddot{o}}ssbauer$ spectrum.

Magnetoresistance in Hybrid Type YBCO-NiO/NiFe/Cu/NiFe Film Structure

  • Lee, S.S;Rhee, J.R;Hwang, D.G;Rhie, K
    • Journal of Magnetics
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    • v.6 no.3
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    • pp.83-85
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    • 2001
  • The magnetoresistance properties of NiO/NiFe/Cu/NiFe spin valve film deposited on MgO(100) substrate with YBa$_2$$Cu_3O_7$(YBCO) film were investigated at room temperature and at 77 K. The magnetoresistance (MR) curves of the hybrid superconductor-magnetoresistor film structure showed an exchange coupling field of 300 Oe and an inverse magnetoresistance ratio of -6.5%. The magnetization configurations of the two magnetic layers in the NiO spin valve were antiparallel due to an increment in the conduction electron flow to superconductor YBCO film. This sample showed an inverse MR ratio.

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