• Title/Summary/Keyword: Mg-ferrite

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Recovery of Mg-Ferrite Powder from Acid Leaching Mg Waste by Hydrothermal Method (산 침출 Mg폐액으로부터 수열법에 의한 Mg-Ferrite 분말회수)

  • 김영순;윤기석;안찬영;이종현;원창환
    • Resources Recycling
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    • v.6 no.4
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    • pp.31-37
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    • 1997
  • The Mg-ferrite powders were recovered from acid leaching Mg waste by hydrothermal method. Recovering conditions ofMg-Ferrite were investigated m this system and the powders prepared were characterized, using X-ray analysis, chemicalanalysis, SEM. TEM, and VSM. In this study, pH of solution and the kind of neutralizer wcre important factors on thecharacteristics of the product. The optimum condition of recovering MgPenite was the mole ratio of Fe" : Mg"=2'1, reactiontemperature : ZOWC, reaction time.lhr, at pH=lZ, and Oi partial pressure af 2000 psi. And the powders ~ccovered have amonodispersed and spherelike shapes with the narrow sue distribulion.ow sue distribulion.

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A Study on the Electric-magnetic Properties of Mg-ferrite with Various Mixing Time of Raw Materials (원료 분말의 혼합 시간에 따른 소결 Mg-Ferrite의 전기.자기적 특성 변화)

  • 김성재;백종규
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.289-294
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    • 1995
  • As the results of the study on the effects of mixing time for raw materials to the electric and magnetic properties of Mg-ferrite, the fraction of spinel phase after calcination and the geometry density of sintered Mg-ferrite increased from 30% to 100% and from 2.5g/cc to 4.25g/cc respectively due to mixing-homobenity of raw materials. The AC resistivity of grains decreased and lattice parameter, saturation magnetization increased due to the increase in Fe+2 of sintered body. conclusively the characteristic of powder after calcination had strong influence on the microstructure, electric, and magnetic properties in Mg-ferrite sintered body.

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The study on the initial permeability of poly-crystalline $MgFe_{2}O_{4}$ With frequency (주파수 변화에 따른 다결정 $MgFe_{2}O_{4}$의 초기 투자율 특성 연구)

  • 김성재;정명득;백종규
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.94-99
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    • 1994
  • This work addresses the relationship between initial complex permeability and porosity in polycrystalline Mg-ferrite material. The initial permeability corresponds to Snoek theory except the sample with large grains. The frequency which initial real permeability, $\mu$' equal 1 due to domain rotation are found in the frequency range 50-80 [MHz]. Internal magnetic field which is considered as mainly anisotropy field is 100[Oe] which is obtained from the relationship between initial complex permeability and porosity in polycrystalline Mg-ferrite material. This is almost the half value of reported anisotropy field of single Mg-ferrite. The difference between them is almost due to domain wall effect in polycrystalIine Mg-ferrite material.

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Low Temperature Sintering Mg-Zn Ferrites (Mg-Zn Ferrites의 저온소결화)

  • Kwon Oh-Heung
    • Resources Recycling
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    • v.12 no.6
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    • pp.8-12
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    • 2003
  • According to the recent trend to raise the horizontal scan frequency to increase the image refinement of the High Definition TV and High Resolution Display, material with low core loss is required for the ferrite core for deflection yoke, which is secured even in the high frequency range. liking notice of the influence on the fine structure of Mg-Zn ferrite by the chemical com position and process, low temperature sintering was proceeded. Cu was added to the low loss Mg-Zn system ferrite. After select-ing MgO, ZnO, $Fe_2$$O_3$, CuO, MgO was substituted for CuO while varying the composition ratio. Then the sample was sintered for 3 hours between $980~1350^{\circ}C$ Magnetic permeability, power consumption, shrinkage rate, core loss were measured. The start-ing temperature to test the shrinkage of the sample was nearby $900^{\circ}C$, it increased according to the substitution process of Cu, and the firing temperature was lowered about $-50~-75^{\circ}C$ alongside of the process.

Phase Equilibria of the Ferrous Ferrite System of $(Mg_{0.29}-yMnyFe_{0.71})_{3-}\delta$O_4$ ($(Mg_{0.29}-yMnyFe_{0.71})_{3-}\delta$O_4$ 훼라이트계의 상평형)

  • 채정훈;유한일;강선호;강대석;유병두
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.394-402
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    • 1995
  • Electrical conductivity and thermoelectric power of the ferrous ferrite system of (Mg0.29-yMnyFe0.71)3-$\delta$O4 have been measured as function of the thermodynamic variables, cationic composition(y), temperature(T) and oxygen partial pressure(Po2) under thermodynamic equilibrium conditions at elevated temperatures. On the basis of the electrical properties-phase stability correlation, the stability regions of the ferrite spinel and its neighboring phases have been subsequently located in the log Po2 vs. y and log Po2 vs. 1/T planes in the ranges of 0 y 0.29, 1100 T/$^{\circ}C$ 1400 and 10-14 Po2/atm 1. The stability region, Δlog Po2(y, 1/T), of the ferrite spinel single phase widens with increasing Mn-content(y) and the boundaries of each region are linear against 1/T with negative slopes.

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The Study of Magnetic Structure of Ni1-xMgxFe2O4 Ferrite System by Mössbauer Spectroscopy (Mössbauer 분광법에 의한 Ni1-xMgxFe2O4 Ferrite의 자기구조 연구)

  • Yoon, In-Seop;Baek, Seung-Do
    • Journal of the Korean Magnetics Society
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    • v.19 no.3
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    • pp.106-112
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    • 2009
  • $Ni_{1-x}Mg_xFe_2O_4$ ferrite system was studied by using X-ray diffraction and $M{\ddot{o}}ssbauer$ spectroscopy. The samples were prepared by ceramic sintering method with Mg content x. The X-ray diffraction patterns of samples show phase of cubic spinel structure. There are no remarkable changes of lattice constants in $Ni_{1-x}Mg_xFe_2O_4$ ferrite system. The $M{\ddot{o}}ssbauer$ spectra were consisted of two sets of six lines, respectively, corresponding to $Fe^{3+}$ at tetrahedral and octahedral sites. The magnetic hyperfine field of samples was decreased as increasing Mg contents x in both sites and it was shown Yafet-Kittel magnetic structure. $NiFe_2O_4$ was shown complete inverse spinel, but $NiFe_2O_4$ was shown partial inverse spinel which absorption area ratio (oct/tet) was 1.449 in $M{\ddot{o}}ssbauer$ spectrum.

Effect of the Addition of CuO and MgO on the magnetic characteristics of Mg-ZnFerrite (CuO 및 MgO 첨가가 Mg-Zn Ferrite의 자기적 특성에 미치는 효과)

  • Lee, Joon-Mo;Choi, Kyu-Man;Gwon, Hyeok-Sang;Lee, Yun-Sik;Lee, Ho-Jin;Lee, Sang-Hun
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.495-496
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    • 2008
  • The magnetic characteristics of Mg-Zn ferrite that was fired at $1150^{\circ}C$ for 1hour and sintered at $1250^{\circ}C$ for 3hours was examined. The composition ratio of the ferrite was changed after sintering. In that case the composition ratio of ${Fe_2}{O_3}$ was increased but that of CuO was decreased. When the addition quantity of CuO was 3.8 mole%, it's shrinkage rate had maximum value. Magnetic permeability was decreased as the addition rate of CuO was increased and MgO was decreased. When the composition rate of CuO was 2.3 mol% and MgO was 10.9 mol%, the firing density had maximum value. In case that CuO was 2.8mol% and MgO was 10.4mol%, PL had minimum value.

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Microstructure, Electric, and Magnetic Properties of Mg-Ferrite with Various Calcination Temperature (하소온도에 따른 Mg-페라이트 소결체의 미세구조 및 전기.자기적 특성 연구)

  • 김성재;정명득;백종규
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.1-10
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    • 1995
  • Effects of calcination temperature on microstructure and electric-magnetic properties of Mg-ferrite were investigated. As the calcination temperature increase, the green density and the sintered density increase due to the enhancement of densification of calcined powder. The grain size in the sintered ferrite increases with increasing the calcination temperatures from 800 to 100$0^{\circ}C$, but decreases from 1000 to 120$0^{\circ}C$. The resistivity decreases with increasing the calcination temperatures from 800 to 110$0^{\circ}C$, but increases from 1100 to 120$0^{\circ}C$ due to the microstructure which consists of small, uniform grian size and pores at grain boundaries. Magnetization increases slightly due to the increasement of the sintered density while Curie temperature is almost constant regardless of calcination temperatures.

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