• Title/Summary/Keyword: Mg solid solution

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Phase Relation Study Based on the Pyroelectric Properties and Relaxation Phenomena in $Pb(Mg _{1/3}Nb_{2/3})O_3-PbTiO_3$ Solid Solution System (초전특성 및 유전완화 거동을 통한 $Pb(Mg _{1/3}Nb_{2/3})O_3-PbTiO_3$ 고용계의 상평형 관계 연구)

  • 박재환;김병국;박재관
    • Korean Journal of Crystallography
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    • v.13 no.3_4
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    • pp.172-176
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    • 2002
  • Pyroelectric properties and relaxation phenomena in Pb(Mg /sub 1/3/Nb/sub 2/3/)O₃-PbTiO₃ solid solution system were studied to establish the phase relation of the solid solution system. The dielectric constants and the pyroelectric coefficients of (1-x)PMN-xPT (x = 0.1∼0.4) system were investigated in the phase transition temperature range of -40°C∼200°C. The freezing temperature was calculated by fitting the experimental data with the Vogel-Fulcher relation. With all the experimental data, a modified phase diagram of the (1-x)PMN-xPT system was suggested.

A Study on the Squeeze Casting of Al-7.0Si-0.4Mg Alloy for Fuel System Parts (Al-7.0Si-0.4Mg 합금 자동차 연료계 부품의 스퀴즈 캐스팅에 관한 연구)

  • 김순호
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.12
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    • pp.48-54
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg (AC4C) alloy fabricated by squeeze casting process for development of Fuel system Parts (Fuel rail). The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2$Si precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg ahoy revealed 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy have good corrosion resistance in electrochemical polarization test.

Behavior of Eutectic Si and Mechanical Properties of Sr Modified Al-7Si-0.35Mg alloy with Solid Solution Treatment for Sand Casting (Sr 개량처리된 사형주조 Al-7Si-0.35Mg 합금의 열처리에 따른 공정 Si상 변화거동 및 특성평가)

  • Kim, Myoung-Gyun;Hwang, Seok-Min
    • Journal of Korea Foundry Society
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    • v.38 no.1
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    • pp.1-8
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    • 2018
  • In this study, we focused on the correlation between the solidification structure, heat treatment and mechanical properties of the A356 alloy according to the conditions of Sr modification. The microstructural evolution of the eutectic Si and ${\alpha}-Al$ phase in the A356 alloy castings depending on the amount of Sr were investigated during solid solution heat treatment using an optical microscope, a scanning electron microscope and an image analyzer. In addition, tensile tests on the heat treated materials examined the relationship between the microstructure and the fracture surface. The as-cast A356 alloys under 40 ppm Sr showed an undermodified microstructure, but that of the added 60-80 ppm Sr had well modified structure of fine fibrous silicon. After solid solution treatment, the microstructure of the undermodified A356 alloy exhibited a partially spheroidized morphology, but the remainder showed the fragmentation of fibrous shaped silicon. The spheroidization of the eutectic silicon in the modified A356 alloys was completed during heat treatment, which was very effective in increasing the elongation. This is supported by the fracture surface in the tensile test.

A study on the squeeze casting of Al-7.0Si-0.4Mg alloy for fuel system parts

  • Kim Soon-Ho;Kim Seong-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • v.6 no.3
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    • pp.56-59
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    • 2005
  • Aluminum alloy casting is gaining increased acceptance in automotive and electronic industries and especially, squeeze casting is the most efficient method of mass manufacturing of such parts. In this study, the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C) alloy fabricated by squeeze casting process for development of fuel system parts (fuel rail) are investigated. The microstructure of squeeze cast specimen was composed of eutectic structure aluminum solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy was 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy had good corrosion resistance in electrochemical polarization test.

Optimization of Solid Solution Treatment Process for a High Pressure Die Casting Al-10Si-0.3Mg-0.6Mn alloy to avoid Blistering and Improve the Strength of the Alloy (고압 다이캐스팅으로 제조된 Al-10Si-0.3Mg-0.6Mn 합금에서 blister 발생과 강도의 균형을 고려한 최적 열처리 공정 설계)

  • Kim, Soo-Bae;Cho, Young-Hee;Jo, Min-Su;Lee, Jung-Moo
    • Journal of Korea Foundry Society
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    • v.40 no.3
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    • pp.66-75
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    • 2020
  • The aim of this study was to optimize a solid solution treatment for a high pressure die casting Al-10Si-0.3Mg-0.6Mn alloy to avoid blistering and to improve the strength of the alloy. To achieve this goal, the number density of the blisters and the strength of the alloy under various solid solution treatment (SST) conditions were evaluated. The SST was performed at 470, 490, 510 and 530℃ for 20, 60, 120, 240 and 480 min on the alloy. The number density of the blisters increased with the increasing temperature and time of the SST and the defect area fraction. The yield strength of the alloy after the T6 heat treatment increased with the increasing SST temperature and time. Based on the results, it is suggested that SST should be performed at 510℃ within 60 min. or at 470 and 490℃ within 240 min. to avoid blistering and to improve the strength.

A Study on the Development for the Vehicle Engine Mountion Bracket Using Squeeze Casting (스퀴즈 캐스팅 제조법에 의한 자동차 엔진 마운틴 브래킷 개발에 관한 연구)

  • Kim, S.H.
    • Journal of Power System Engineering
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    • v.7 no.4
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    • pp.44-48
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C)alloy fabricated by squeeze casting process for development of Engine Mountain Bracket. The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy revealed 2985MPa. It was found that Al-7.0Si-0.4Mg alloy have good aging hardening effect results are presented to show the validity of the control method.

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Floating-Zone Growth of Single Crystal Olivine $[(Mg_{1-x}Fe}_{x})_2SiO_4]$ (Floating Zone법에 의한 올리빈 $[(Mg_{1-x}Fe}_{x})_2SiO_4]$단결정 성장)

  • 정광철;강승민;신재혁;한종원;최종건;오근호;박한수;문종수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.3 no.1
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    • pp.85-92
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    • 1993
  • Large single crystals of olivine were grown by using image furnace(floating zone furnace)under controlled partial pressure of oxygen. The transparent crystals have maximum sizes 65mm in length by 7mm in diameter. When partial pressure of oxygen was decreased, the portion of secondary phases in crystals were increased so that it made crystals dark brown. The secondary phases were proved to be solid solution of Mg, Si, and Fe by electron microprobe analysis. Mg was major portion and the rest was minor.

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A Study on Microstructures and Dielectric Properties in $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-BaTiO_3$ Solid Solution ($Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-BaTiO_3$ 고용체의 미세구조와 유전특성에 관한 연구)

  • Park, Hyun;Lee, Eung-Sang
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1240-1246
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    • 1994
  • While sintering the Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 system through solid-reaction route, pyrochlore(Pb3Nb4O13) phase while reduces the dielectric constant is inevitably formed. Substitution of Pb(Mg1/3Nb2/3)O3 with PbTiO3 and BaTiO3 can retard the occurrence of pyrochlore phase. The perovskite solid-solution without containing pyrochlore phase can be obtained when we consolidated the materials consisting of PbTiO3 and BaTiO3 at 1200℃ for 2 hours. The sintered body composed of 0.8Pb(Mg1/3Nb2/3)O3-0.1PbTiO3-0.1BaTiO3 composition showed the diffused phase transition(DPT) phenomena and the maximum value of dielectric constant at 0℃ (Tc') with the value of 1.3×104.

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Effects of Mg Addition on Heat Treatment and Mechanical Properties of A356 Alloy (Mg 첨가에 따른 A356 합금의 열처리 및 기계적 특성 변화)

  • Jo, Jae-Chan;Kim, Kwang-Sam;Im, In-Taek;Kim, Dae-Hwan;Shim, Sung-Yong;Lim, Su-Gun
    • Journal of Korea Foundry Society
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    • v.36 no.6
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    • pp.195-201
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    • 2016
  • The effects of Mg addition on heat treatment and mechanical properties of A356 alloy were investigated. With increased amounts of Mg addition to A356 alloy, the grain size decreased and eutectic Si was refined. And, this process can improve the mechanical properties. Solid solution heat treatment causes the spheroidizing of eutectic Si. In this study, although eutectic Si was refined with Mg addition, solid solution time increased from 2 hours to 6 hours with Mg addition, and aging time also increased, from 4 hours to 8 hours. After heat treatment, Mg2Si remained in a formation of Chinese script. And, Chinese script Mg2Si formed with Mg addition caused a reduction of the elongation of the alloys according to the stress concentration.

Reaction Mechanism in the Formation of PMN-PT-BT Solid Solution (PMN-PT-BT 고용체의 합성반응기구)

  • Park, Hyun;Lee, Eung-Sang
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1443-1448
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    • 1994
  • Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 solid solution was formed by mixed-oxide method. The phase during formation was analysed by XRD and formation mechanism was investigated. While heat-treating Pb(Mg1/3Nb2/3)O3 composition, the first, Pb2Nb2O7 and Pb3Nb2O8 pyrochlore phases are formed, and finally Pb(Mg1/3Nb2/3)O3 perovskite phase with containing Pb3Nb4O13 pyrochlore phase is obtained at 80$0^{\circ}C$. When Pb(Mg1/3Nb2/3)O3 composition is modified with PbTiO3 which have strong ionic bonding and high tolerance factor, the amount of pyrochlore phase is decreased by increasing of stability in perovskite structure.

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