• Applied Chemistry
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• v.15 no.1
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• pp.37-40
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• 2011

A chemiluminescent method with silver nanoparticles for determination of L-alanine has been presented. The chemilumiscence intensity was further enhanced by silver nanoparticles in the luminol system by its catalytic role. The silver nanoparticles enhanced chemiluminescent method is applicable for the determination of an amino acid such as alanine. When alanine was introduced to the luminol system with silver nanoparticles, chemiluminescence intensity was reduced with the concentration of the added alanine. The effects of pH, concentrations of luminol, hydrogen peroxide and silver nanoparticles on the chemiluminescence intensity were investigated. The calibration curve for L-alanine was linear over the range from 6.60×10^-8 M to 4.00×10^-7 M, coefficient of correlation was 0.996 and detection limit was 3.5×10^-9 M under the optimal conditions of 4.0×10^-3 M, 4.0×10^-2 M, 4.0×10^-4 M, 12.8 for the concentration of luminol, H₂O₂, silver nanoparticles and pH, respectively.

• Nuclear Engineering and Technology
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• v.55 no.10
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• pp.3822-3830
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• 2023

The large-area Compton camera (LACC), featuring significantly high detection sensitivity, was developed for high-speed localization of gamma-ray sources. Due to the high gamma-ray interaction event rate induced by the high sensitivity, however, the multiplexer-based data acquisition system (DAQ) rapidly saturated, leading to deteriorated energy and imaging resolution at event rates higher than 4.7 × 10³ s^-1. In the present study, a new simultaneous multi-channel DAQ was developed to improve the energy and imaging resolution of the LACC even under high event rate conditions (10⁴-10⁶ s^-1). The performance of the DAQ was evaluated with several point sources under different event rate conditions. The results indicated that the new DAQ offers significantly better performance than the existing DAQ over the entire energy and event rate ranges. Especially, the new DAQ showed high energy resolution under very high event rate conditions, i.e., 6.9% and 8.6% (for 662 keV) at 1.3 × 10⁵ and 1.2 × 10⁶ s^-1, respectively. Furthermore, the new DAQ successfully acquired Compton images under those event rates, i.e., imaging resolutions of 13.8° and 19.3° at 8.7 × 10⁴ and 10⁶ s^-1, which correspond to 1.8 and 73 μSv/hr or about 18 and 730 times the background level, respectively.

• The Journal of the Acoustical Society of Korea
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• v.43 no.2
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• pp.178-183
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• 2024

This study introduces an enhanced sound source localization technique, bolstered by a data-driven deep learning approach, to improve the precision and accuracy of direction of arrival estimation. Focused on refining Time Difference Of Arrival (TDOA) based sound source localization, the research hinges on accurately estimating TDOA from cross-correlation functions. Accurately estimating the TDOA still remains a limitation in this research field because the measured value from actual microphones are mixed with a lot of noise. Additionally, the digitization process of acoustic signals introduces quantization errors, associated with the sampling frequency of the measurement system, that limit the precision of TDOA estimation. A deep learning-based approach is designed to overcome these limitations in TDOA accuracy and precision. To validate the method, we conduct comprehensive evaluations using both two and three-microphone array configurations. Moreover, the feasibility and real-world applicability of the suggested method are further substantiated through experiments conducted in an anechoic chamber.

• The Journal of the Acoustical Society of Korea
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• v.43 no.2
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• pp.162-167
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• 2024

Low frequency noise emitted by wind turbines is one of the most noise complaints. In this study, the reliability of the models was examined by comparing the measured sound pressure levels with the predicted levels based on Denish model and commercial programs of the SounPLAN and the ENPro based on ISO 9613. As a result of applying it to representative 3 MW wind turbines, on lnad, the measured and the predicted values differed within a maximum of 5 dB in the frequency range of 12.5 Hz to 80 Hz. It may be due to the change in the acoustic power levels because the wind turbines have been in operation for more than 7 years. However, considering that the Boundary Element Method (BEM) predicted value, which is known to be the most accurate in the low frequency band, the predicted values are well matched within 2.5 dB, the models of this study are expected to be used as deviation within 3 dB.

• The Journal of the Acoustical Society of Korea
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• v.43 no.3
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• pp.344-350
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• 2024

A Reference Sound Source (RSS) is an important standard device employed in measuring sound power. The specifications of RSS is specified in international standards, and it is classified as a major calibration item in the field of acoustic metrology. Since the output power of RSS is affected by the supply voltage, each country needs to secure its own calibration service system. In this study, a procedure for calibrating a RSS is established based on the reverberant room conditions and uncertainty evaluation is conducted. Basically, the calibration procedure can apply a precision measurement process of acoustic power, and here, the measurement method using the reverberation chamber of ISO 3741 is applied. For this purpose, a measurement system is constructed, measurements are conducted with two types of RSS, and measurement uncertainty is evaluated. Through measurement examples, it is confirmed that the non-uniformity of the sound pressure distribution in the reverberation room and the volume measurement uncertainty contributed significantly to the overall uncertainty. Additionally, the influence of input voltage is experimentally examined to examine the uncertainty contribution that can be reflected in acoustic power measurements.

• The Journal of the Acoustical Society of Korea
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• v.43 no.1
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• pp.72-77
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• 2024

Recently, the necessity for sound source localization has grown significantly across various industrial sectors. Among the sound source localization methods, sound intensimetry has the advantage of having high accuracy even with a small microphone array. However, the increase in localization error at high Helmholtz numbers have been pointed out as a limitation of this method. The study proposes a method to compensate for the bias error of the measured sound intensity vector according to the Helmholtz numbers by applying deep learning. The method makes it possible to estimate the accurate direction of arrival of the source by applying a dense layer-based deep learning model that derives compensated sound intensity vectors when inputting the sound intensity vectors measured by a tetrahedral microphone array for the Helmholtz numbers. The model is verified based on simulation data for all sound source directions with 0.1 < kd < 3.0. One can find that the deep learning-based approach expands the measurement frequency range when implementing the sound intensimetry-based sound source localization method, also one can make it applicable to various microphone array sizes.

• Journal of Sensor Science and Technology
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• v.7 no.3
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• pp.154-162
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• 1998

A planar Bi-Sb multijunction thermal converter with high thermal sensitivity and small ac-dc transfer error has been fabricated by preparing the bifilar thin film Pt-heater and the hot junctions of thin film Bi-Sb thermopile on the $Si_{3}N_{4}/SiO_{2}/Si_{3}N_{4}$-diaphragm, which functions as a thermal isolation layer, and the cold junctions on the dielectric membrane supported with the Si-substrate, which acts as a heat sink, and its ac-dc transfer characteristics were investigated with the fast reversed dc method. The respective thermal sensitivities of the converter with single bifilar heater were about 10.1 mV/mW and 14.8 mV/mW in the air and vacuum, and those of the converter with dual bifilar heater were about 5.1 mV/mW and 7.6 mV/mW, and about 5.3 mV/mW and 7.8 mV/mW in the air and vacuum for the inputs of inside and outside heaters, indicating that the thermal sensitivities in the vacuum, where there is rarely thermal loss caused by gas, are higher than those in the air. The ac-dc voltage and current transfer difference ranges of the converter with single bifilar heater were about ${\pm}1.80\;ppm$ and ${\pm}0.58\;ppm$, and those of the converter with dual bifilar heater were about ${\pm}0.63\;ppm$ and ${\pm}0.25\;ppm$, and about ${\pm}0.53\;ppm$ and ${\pm}0.27\;ppm$, respectively, for the inputs of inside and outside heaters, in the frequency range below 10 kHz and in the air.

• Journal of the Korean Ceramic Society
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• v.39 no.9
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• pp.863-870
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• 2002

The Single phase $Pb(Fe_{1/2}Ta_{1/2})O_3$ (x=0.0∼1.0) solid solutions were successfully synthesized and their ordering structures as well as dielectric properties were investigated ${{r(Nb^{5+})=r(Ta^{5+})=0.78 {\AA},\;AW(Nb^{5+})=92.91,\;AW(Ta^{5+})=180.95}}$. While $Pb(Fe_{1/2}Ta_{1/2})O_3$ showed typical relaxor ferroelectric characteristics such as dielectric relaxation and diffuse phase transition, the sharpeness of the phase transition increased as $Ta^{5+}$ was replaced by $Nb^{5+}$ and finally $Pb(Fe_{1/2}Nb_{1/2})O_3$ showed normal ferroelectric characteristics with no dielectric relaxation. By using Raman spectroscopy, it was revealed that the $Fe^{3+}\;and\;Ta^{5+}\;of\;Pb(Fe_{1/2}Ta_{1/2})O_3$ were stoichiometrically 1:1 ordered within the short range which can be hardly probed even by TEM. Also, The degree of ordering in $Pb(Fe_{1/2}Ta_{1/2})O_3$ decreased as $Ta^{5+}$ was replaced by $Nb^{5+}$ and finally $Fe^{3+}\;and\;Nb^{5+}\;of\;Pb(Fe_{1/2}Nb_{1/2})O_3$ were completely disordered. The relaxor ferroelectric characteristics of $Pb(Fe_{1/2}Ta_{1/2})O_3$ could be correlated with the stoichiometric 1:1 ordering of B-site cations within the short range which can be hardly probed even by TEM. Also, the decrease of the relaxor ferroelectric characteristics with the replacement of $Ta^{5+}\;by\;Nb^{5+}$ could be correlated with the weakening of the ordering and the normal ferroelectric characteristics of $Pb(Fe_{1/2}Nb_{1/2})O_3$ could be correlated with the complete disordering of B-site cations.

• Journal of Dental Rehabilitation and Applied Science
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• v.31 no.4
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• pp.316-328
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• 2015

Purpose: The objects of this study was to evaluate the accuracy of the dental stone casts made from alginate impressions according to storage condition and stone pouring time. Materials and Methods: Each of upper and lower impressions of dental model was taken. The dental stone models were made immediately, 10, 30, 60, 180, 360 minutes after the impressions were taken at each storage condition. 3D models were constructed by scanning the stone model using 3D laser scanner. With Reference points, positioned on digital models, linear measurements of the dimensional change were compared by 3D metrology software, 3D average models were made and superimposition to identify the specific site of dimensional change and to measure surface deviation (mm). Results: Dental stone models which were made immediately after taking the impression showed the smallest linear dimensional change. As the stone pouring time was prolonged, the linear dimensional change was increased. More than 180 minutes after impression taking, linear dimensional change and surface distortion increased in the posterior molar region, regardless of the storage condition. Conclusion: For the optimum accuracy of the dental stone casts, alginate impression should be poured as soon as possible. If there were a need for storing, a humidor with 100% relative humidity must be used and be stored less than 180 minutes to fabricate the accurate dental model.

• Analytical Science and Technology
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• v.25 no.6
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• pp.350-363
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• 2012

To determine ionic species in snowpit samples using ion chromatography system, we described the performance of ion chromatography(IC) system, cleaning method of bottle, and interference by filtering procedure. The limit of detection, reproducibilities, and accuracies determined with BCR$^{(R)}$-408 were 0.01-0.26 ${\mu}g$/L, 0.4-17.4%, 4.5-12.0% for cations and 0.02-0.26 ${\mu}g/L$, 0.1-27.6%, 1.3-5.6% for anions, respectively. Lab blank test for sample bottle indicated that $CH_3CO_2{^-}$, $HCO_2{^-}$, and $NH_4{^+}$ can be easily contaminated in the lab environment. The positive interferences of $NO_3{^-}$ were partly attributed to the cleaning method of bottle. The filtering of melted snow sample should be carefully applied because it can positively affect the concentration levels of some ionic species. Finally, this method was applied to measure ionic species in snowpit samples from the upward area near NEEM camp and the uncertainties of measurement data of $F^-$ were also estimated.