• Journal of the Korean Chemical Society
• /
• v.53 no.6
• /
• pp.671-676
• /
• 2009

Described here for the first time is an investigation on geometrical and electronic molecular structure of metol (N-methyl-p-aminophenol sulphate) as corrosion inhibitor of steel using density functional theory (DFT) calculations. Quantum chemical parameters such as highest occupied molecular orbital energy (EHOMO), lowest unoccupied molecular orbital energy (ELUMO), energy gap ((${\Delta}E$), Mulliken charges (($q_M$) and natural atomic (($q_n$) charge have been calculated both for gas and aqueous phases by using B3LYP/6-31G+(d,p) basis set. The relation between the inhibition efficiency and quantum chemical parameters have been discussed in order to elucidate the inhibition mechanism of the title compound.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.23 no.5
• /
• pp.403-407
• /
• 2010

This paper shows that the diffraction efficiency is influenced by superadditivity for the combination of the different developing agent and concentrations in the reversal bleach applied to the Slavich PFG-01 plate to be used for recording transmission holograms. The four developers based on ascorbic acid in combination with metol, phenidone, hydroquinone respectively, were studied. In diffraction efficiency aspect, the superadditivity effect of mixture of two developing agents is lower than one developing agent developer, AAC in the reversal bleach.