• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.505-510
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• 2015

This study was performed to test the combustive properties of pinus rigida specimens treated with methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$)s and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Each pinus rigida plates were painted three times with 15 wt% $PIPEABPM^{n+}s$ or PIPEABP solutions at the room temperature. After drying specimens treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). It was indicated that the speed to peak mass loss rate ($MLR_{peak}$), (0.104~0.121) g/s for specimens treated with $PIPEABPM^{n+}s$ was lower than that of PIPEABP plate. In addition, the total smoke release rate (TSRR), $(224.4{\sim}484.0)m^2/m^2$ for $PIPEABPM^{n+}s$ treated specimens except specimen treated with PIPEABPAl3+ and $CO_{mean}$ production (0.0537~0.0628) kg/kg was smaller than that of PIPEABP plate. In particular, for the specimens treated with $PIPEABPM^{n+}$ by reducing the smoke production rate, the second-smoke production rate (2nd-SPR) $(0.0117{\sim}0.0146)m^2/s$ was lower than that of PIPEABP plate. It can thus be concluded that combustion-retardation properties of the treated $PIPEABPM^{n+}s$ were partially improved compared to those of the virgin plate.

• Fire Science and Engineering
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• v.28 no.3
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• pp.55-61
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• 2014

This study was performed to test the combustive properties of pinus rigida specimens treated with methylpiperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$)s and methylpiperazinomethyl-bis-phosphonic acid (PIPEABP). Pinus rigida Plates were painted in three times with 15 wt% $PIPEABPM^{n+}s$ and PIPEABP solutions at the room temperature respectively. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). It was indicated that the specimens treated with $PIPEABPM^{n+}s$ showed the lower speed to peak mass loss rate ($MLR_{peak}$), (0.104~0.121) g/s than that of PIPEABP plate. In adition, the specimens treated with $PIPEABPM^{n+}s$ showed both the lower total smoke release rate (TSRR), (224.4~484.0) $m^2/m^2$ and $CO_{mean}$ production (0.0537~0.0628) kg/kg than those of PIPEAB plate. Especially, for the specimens treated with $PIPEABPM^{n+}$ by reducing the smoke production rate except 2nd-smoke production rate (2nd-SPR), (0.0254~0.02270) g/s treated with $PIPEABPNi^{2+}$, 2nd-SPR (0.0117~0.0146) g/s was lower than that of PIPEABP plate. Thus, It is supposed that the combustion-retardation properties were improved by the partial due to the treated $PIPEABPM^{n+}s$ in the virgin plate.

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.39-44
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• 2016

This study was to investigate the characteristics of combustion toxic gases of pinus rigida specimens treated with chemical additives such as pyrophosphoric acid (PP)/ammonuium ion ($NH_4{^+}$), methylenepiperazinomethyl-bis-phosphonic acid (PIPEABP) and $PIPEABP/NH_4{^+}$. Each pinus rigida plates was painted in three times with 15 wt% of each chemical additives in the aqueous solution. After drying these specimens at room temperature, the production of combustion gases and smoke was examined by the cone calorimeter (ISO 5660-1). As a result, the peak mass loss rate time (PMLR time) treated with chemicals was delayed upto 10.5~47.4% compared to that of using untreated specimen. In addition, the peak production of carbon monoxide ($CO\;_{peak}$) of 32.1~71.4% and total smoke release rate (TSRR) of 15.6~43.6% for test pieces treated with the chemical additive were higher than that of using the virgin plate. In particular, for the specimens treated with the chemical additive, the rate of smoke release (RSR) 29.4~41.5% was obtained higher than that of untreated plate except the specimen treated with $PP/4NH_4{^+}$. It can thus be concluded that the treatment using the chemical additive could partially increase the combustion-retardation properties of the species when compared to those of the virgin plate.

• Applied Chemistry for Engineering
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• v.26 no.5
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• pp.609-614
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• 2015

This study was to investigate the production of combustion toxic gases of pinus rigida specimens treated with pyrophosphoric acid (PP)/4ammonuium ion ($4NH_4{^+}$), methylenepiperazinomethyl-bis-phosphonic acid (PIPEABP) and PIPEABP/$4NH_4{^+}$. Each pinus rigida plates was painted in three times with 15 wt% in the aqueous solution followed by drying the species at room temperature. Emission of combustion toxic gases was examined by the cone calorimeter (ISO 5660-1). First-time to peak mass loss rate (1st-$TMLR_{peak}$) treated with chemicals was delayed upto 66.7~250.0% compared to those of untreated specimens. For test pieces treated with the chemicals, the emission of peak carbon monoxide ($CO_{peak}$) values of 0.0136~0.0178% and peak carbon dioxide ($CO_{2\;peak}$) value of 0.04432~0.3648% were obtained, which were higher than those for the virgin plate. In particular, oxygen emission is much higher than the level of 15% which can be fatal to humans. Therefore, the resulting risk could be eliminated. However it is supposed that the combustion-toxicities were partially increased compared to those of virgin plate.