• Asian Journal of Atmospheric Environment
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• v.2 no.2
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• pp.116-124
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• 2008

In this study, the Tier 2 method recommended by the Intergovernmental Panel on Climate Change (IPCC) was used to predict the methane generation rate at two landfill sites, designated as Y and C for purposes of this study, in South Korea. Factors such as the average annual waste disposal, methane emissions ($L_0$) and methane gas generation rate constant (k) were estimated by analyses of waste and the historical data for the landfills. The value of k was estimated by field experiments and then the changes in the methane generation rate were predicted through the year 2050, based on the value of k. The Y landfill site, which was in operation until the year 2008, will generate a total of 17, 198.7 tons by the end of 2018, according to our estimations. At the C landfill site, which will not be closed until the end of 2011, the amount of methane gas generated in 2011 will be 3,316 tons and the total amount of gas generated by 2029 will be 61,200 tons. The total production rate of methane gas at the C landfill is higher than that of the Y landfill. This indicates that the capacity of a landfill site affects the production rate of methane gas. However, the interrelation between the generation rate of methane and the value of k is weak. In addition, the generation of methane gas does not cease even when the operations at a landfill site come to a close and the methane gas production rate is at its highest at end of the operating life of a landfill site.

• Environmental Engineering Research
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• v.22 no.4
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• pp.339-346
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• 2017

The objective of this study is the evaluation of the performance of a large-scale respirometer (LSR) of 17.7 L in the determination of the methane generation rate constant (k) values. To achieve this objective, a comparison between anaerobic (GB21) and LSR tests was conducted. The data were modeled using a linear function, and the resulting correlation coefficient ($R^2$) of the linear regression is 0.91. This result shows that despite the aerobic conditions, the biodegradability values that were obtained from the LSR test produced results that are similar to those from the GB21 test. In this respect, the LSR test can be an indicator of the anaerobic biodegradability for landfill waste. In addition, the results show the high repeatability of the tests with an average coefficient of variance (CV) that is lower than 10%; furthermore, the CV for the LSR is lower than that of the GB21, which indicates that the LSR-test method could provide a better representation of waste samples. Therefore, the LSR method allows for both the prediction of the long-term biodegradation potential in a shorter length of time and the reduction of the sampling errors that are caused by the heterogeneity of waste samples. The k values are $0.156y^{-1}$ and $0.127y^{-1}$ for the cumulative biogas production (GB21) and the cumulative oxygen uptake for the LSR, respectively.

• Journal of the Korean GEO-environmental Society
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• v.15 no.5
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• pp.5-11
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• 2014

In this study, greenhouse gas emission for small scale landfill (H and Y landfill) was investigated to deduce special the methane generation rate constant(k). To achieve the purpose, the data of physical composition was collected and amount of LFG emission was calculated by using FOD method suggested in 2006 IPCC GL. Also, amount of LFG emission was directly measured in the active landfill sites. By comparing the results, the methane generation rate constant(k), which was used as input variable in FOD method suggested in 2006 IPCC GL, was deduced. From the results on the physical composition, it was shown that the ranges of DOC per year in H (1997~2011) and Y (1994~2011) landfill sites were 13.16 %~23.79 % ($16.52{\pm}3.84%$) and 7.24 %~34.67 % ($14.56{\pm}7.30%$), respectively. The DOC results showed the differences with the suggested values (= 18 %) in 2006 IPCC GL. The average values of methane generation rate constant(k) from each landfill site were $0.0413yr^{-1}$ and $0.0117yr^{-1}$. The results of methane generation rate constant(k) was shown big difference with 2006 IPCC GL defualt value (k = 0.09). It was confirmed that calculation results of greenhouse gas emission using default value in 2006 IPCC GL show excessive output.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.6B
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• pp.399-406
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• 2012

The objective of this research is to develop greenhouse gas generation models and estimation method of their parameters for solid waste landfills. Two models obtained by differentiating the Modified Gompertz and Logistic models were employed to evaluate two parameters of a first-order decay model, methane generation potential ($L_0$) and methane generation rate constant (k). The parameters were determined by the statistical comparison of predicted gas generation rate data using the two models and actual landfill gas collection data. The values of r-square obtained from regression analysis between two data showed that one model by differentiating the Modified Gompetz was 0.92 and the other model by differentiating the Logistic was 0.94. From this result, the estimation methods showed that $L_0$ and k values can be determined by regression analysis if landfill gas collection data are available. Also, new models based on two models obtained by differentiating the Modified Gompertz and Logistic models were developed to predict greenhouse gas generation from solid waste landfills that actual landfill generation data could not be available. They showed better prediction than LandGEM model. Frequency distribution of the ratio of Qcs (LFG collection system) to Q (prediction value) was used to evaluate the accuracy of the models. The new models showed higher accuracy than LandGEM model. Thus, it is concluded that the models developed in this research are suitable for the prediction of greenhouse gas generation from solid waste landfills.

• Environmental Engineering Research
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• v.25 no.3
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• pp.374-383
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• 2020

Landfill gas (LFG) emissions from a given amount of landfill waste depend on the carbon flows in the waste. The objective of this study was to more accurately estimate the first-order decay parameters through methane (CH₄) and carbon flow balances based on the analysis of a full-scale landfill with long-term data and detailed field records on LFG and leachate. The carbon storage factor for the case-study landfill was 0.055 g-degradable organic carbon (DOC) stored per g-wet waste and the amounts of DOC lost with the leachate were less than 1.3%. The appropriate CH₄ generation rate constant (k) for bulk waste was 0.24 y-1. The the CH₄ generation potential (L0) values ranged 33.7-46.7 m3-CH₄ Mg-1, based on the fraction of DOC that can decompose (DOCf) value of 0.40. Results show that CH4 and carbon flow balance methods can be used to estimate model parameters appropriately and to predict long-term carbon emissions from landfills.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.1
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• pp.54-61
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• 2007

The influences of pH were investigated for anaerobic hydrogen gas production under the constant pH condition ranged from pH 3 to 10. Carbon dioxide and hydrogen gas were main components of the gas but methane was not detected in the produced gas when sucrose was added in enrichment medium. When the modified Gompartz equation was applied for the statistical analysis of experimental data, a hydrogen production potential and maximum gas production rate at pH 5 were 1,182 mL and 112.46 mL/g dry wt biomass/hr. The hydrogen conversion ratio was 22.56%. The butyrate/acetate ratios at pH 5 and pH 6 are 1.63 and 0.38. Higher butyrate/acetate ratio produced more hydrogen gas generation. The Haldane equation model was used to find the optimum pH and fitted well with the experimental data$(r^2=0.98)$. The optimum pH and specific hydrogen production were 5.5 and 119.61 mL/g VSS/h.