• Journal of the Korean Solar Energy Society
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• v.36 no.1
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• pp.19-26
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• 2016

Biomass has been used for energy sources from the prehistoric age. Biomass are converted into solid, liquid or gaseous fuels and are used for heating, electricity generation or for transportation recently. Solid biofuels such as bio-chips or bio-pellet are used for heating or electricity generation. Liquid biofuels such as biodiesel and bioethanol from sugars or lignocellulosics are well known renewable transportation fuels. biogas produced from organic waste are also used for heating, generation and vehicles. Biomass resources for the production of above mentioned biofuels are classified under following 4 categories, such as forest biomass, agricultural residue biomass, livestock manure and municipal organic wastes. The energy potential of those biomass resources existing in Korea are estimated. The energy potential for dry biomass (forest, agricultural, municipal waste) were estimated from their heating value contained, whereas energy potential of wet biomass (livestock manure, food waste, waste sludge) is calculated from the biological methane potential of them on annual basis. Biomass resources potential of those 4 categories in Korea are estimated to be as follows. Forest biomass 355.602 million TOE, agricultural biomass 4.019 million TOE, livestock manure biomass 1.455 million TOE, and municipal organic waste 1.074 million TOE are available for biofuels production annually.

• Environmental Engineering Research
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• v.25 no.3
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• pp.374-383
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• 2020

Landfill gas (LFG) emissions from a given amount of landfill waste depend on the carbon flows in the waste. The objective of this study was to more accurately estimate the first-order decay parameters through methane (CH₄) and carbon flow balances based on the analysis of a full-scale landfill with long-term data and detailed field records on LFG and leachate. The carbon storage factor for the case-study landfill was 0.055 g-degradable organic carbon (DOC) stored per g-wet waste and the amounts of DOC lost with the leachate were less than 1.3%. The appropriate CH₄ generation rate constant (k) for bulk waste was 0.24 y-1. The the CH₄ generation potential (L0) values ranged 33.7-46.7 m3-CH₄ Mg-1, based on the fraction of DOC that can decompose (DOCf) value of 0.40. Results show that CH4 and carbon flow balance methods can be used to estimate model parameters appropriately and to predict long-term carbon emissions from landfills.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.6
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• pp.120-130
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• 2013

A study was conducted for the performance characteristics of methane taking recently the limelight in the world as a next-generation propellant, with the survey for state of the art in the development of methane/oxygen rocket engine being accompanied. Liquid methane as a rocket fuel has the favorable characteristics such as non-toxic, low cost, regenerative cooling capability, and potential for in-situ resource utilization (ISRU). The combination of liquid methane and liquid oxygen also provides the excellent performance including high specific impulse and low system mass. For these reasons, many researches have been actively carried out on the methane/oxygen engine, nevertheless, its technology readiness level is not that high enough just yet. Therefore, it is judged that it is the time to mitigate the technical gap with the space technology of advanced countries through a swift onset of the development of methane rocket engine.

• Proceedings of the Korean Society of Crop Science Conference
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• 2022.10a
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• pp.145-145
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• 2022

South Korea greenhouse gas emissions have increased year by year, resulting in a total emission of 727.6 million tons of CO₂ eq in 2018, a 2.5% increase compared to 2017. Among them, the agricultural sector emitted 21.2 million tons of CO₂ eq., accounting for 2.9% of the total. Among the greenhouse gases emitted from the agricultural sector, a particularly problematic is methane gas emitted from rice paddies. Methane is one of the important greenhouse gases with a global warming potential (GWP) that is about 21 times higher than that of carbon dioxide due to its high infrared absorption capacity despite its relatively short remaining atmospheric period. Since the pattern of methane generation varies depending on the rice variety and ecological type, research related to this is necessary for accurate emission calculation and development of reduction technology. Accordingly, a study was conducted to find out the changes in greenhouse gas emission according to rice varieties and ecology types. As for the rice eco-type cultivar, early maturing cultivar (Haedamssal) and medium-late rice cultivar (Saeilmi) were used. Haedamssal was transplanted on May 25 and June 25, and Saeilmi was transplanted on June 10 and June 25. The amount of methane generated according to the growing day showed a tendency to increase as the planting period was earlier. The difference between varieties was that Haedamssal showed higher methane production than Saeilmi. The total CH₄ flux in the saeilmi was 18.7 kg·h^-1(Jun 10 transplanting), 12.4 kg·h^-1(Jun 25 transplanting) during rice cultivation. Lower methane emission was observed in Saeilmi than in Haedam rice. In addition, the earlier the planting period, the higher the methane emission. This study is the result of the first year of research, and it is planned to investigate the amount of greenhouse gas emission between double cropping and single cropping using wheat cultivation after harvest for each ecological type.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.2
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• pp.156-161
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• 2012

Marine biomass is considered an important substrate for anaerobic digestion to recovery energy i.e. methane. Nevertheless, marine biomass has attracted little attention by researchers compared to terrestrial feedstock for anaerobic digestion. In this study, biochemical methane potential (BMP) test was used to evaluate generation of renewable energy from starfish. A cumulative biogas yield of $748{\pm}67mL\;g^{-1}VS^{-1}$ was obtained after 60 days of digestion. The cumulative methane yield of $486{\pm}28mL\;CH_4\;g^{-1}VS^{-1}$ was obtained after 60 days of digestion. The methane content of the biogas was approximately 70%. The calculated data applying the modified Gompertz equation for the cumulative $CH_4$ production showed good correlation with the experimental result obtained from this batch study. Since the result obtained from this study is comparable to results with other substrates, marine biomass can be co-digested with food waste or swine wastewater to produce $CH_4$ gas that will help to reduce the gap in global energy demand.

• Environmental Engineering Research
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• v.22 no.4
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• pp.339-346
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• 2017

The objective of this study is the evaluation of the performance of a large-scale respirometer (LSR) of 17.7 L in the determination of the methane generation rate constant (k) values. To achieve this objective, a comparison between anaerobic (GB21) and LSR tests was conducted. The data were modeled using a linear function, and the resulting correlation coefficient ($R^2$) of the linear regression is 0.91. This result shows that despite the aerobic conditions, the biodegradability values that were obtained from the LSR test produced results that are similar to those from the GB21 test. In this respect, the LSR test can be an indicator of the anaerobic biodegradability for landfill waste. In addition, the results show the high repeatability of the tests with an average coefficient of variance (CV) that is lower than 10%; furthermore, the CV for the LSR is lower than that of the GB21, which indicates that the LSR-test method could provide a better representation of waste samples. Therefore, the LSR method allows for both the prediction of the long-term biodegradation potential in a shorter length of time and the reduction of the sampling errors that are caused by the heterogeneity of waste samples. The k values are $0.156y^{-1}$ and $0.127y^{-1}$ for the cumulative biogas production (GB21) and the cumulative oxygen uptake for the LSR, respectively.

• Asian-Australasian Journal of Animal Sciences
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• v.28 no.2
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• pp.188-199
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• 2015

Nineteen tanniferous browse plants were collected from South Africa to investigate their digestibility, gas production (GP) characteristics and methane production. Fresh samples were collected, dried in forced oven, and ground and analyzed for nutrient composition. In vitro GP and in vitro organic matter digestibility (IVOMD) were determined using rumen fluid collected, strained and anaerobically prepared. A semi-automated system was used to measure GP by incubating the sample in a shaking incubator at $39^{\circ}C$. There was significant (p<0.05) variation in chemical composition of studied browses. Crude protein (CP) content of the species ranged from 86.9 to 305.0 g/kg dry matter (DM). The neutral detergent fiber (NDF) ranged from 292.8 to 517.5 g/kg DM while acid detergent fiber (ADF) ranged from 273.3 to 495.1 g/kg DM. The ash, ether extract, non-fibrous carbohydrate, neutral detergent insoluble nitrogen, and acid detergent insoluble nitrogen and CP were negatively correlated with methane production. Methane production was positively correlated with NDF, ADF, cellulose and hemi-cellulose. Tannin decreased GP, IVOMD, total volatile fatty acid and methane production. The observed low methanogenic potential and substantial ammonia generation of some of the browses might be potentially useful as rumen manipulating agents. However, a systematic evaluation is needed to determine optimum levels of supplementation in a mixed diet in order to attain a maximal depressing effect on enteric $CH_4$ production with a minimal detrimental effect on rumen fermentation of poor quality roughage based diet.

• New & Renewable Energy
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• v.4 no.3
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• pp.5-14
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• 2008

The target for the reduction of $CO_2$ emissions, as specified in the Kyoto Protocol, can only be achieved by an extended use of renewable fuels and the increasing of the energy efficiency. The energy generation from waste gases with a reasonable content of methane like biogas can significantly contribute to reach this target. A further reduction of greenhouse gas emissions is possible by increasing the electrical efficiency using progressive technologies. Fuel cells can be highly energy conversion devices. Utilizing biogas as the fuel for fuel cell systems offers an option that is technically feasible, potentially economically attractive and greenhouse gas neutral. High temperature fuel cells that are able to operate with carbon monoxide in the feed are well suited to these applications. Furthermore, because they do not require noble metal catalysts, the cost of high-temperature fuel cells has the greatest potential to become competitive in the near future compared to other types of fuel cells.

• Journal of Environmental Science International
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• v.8 no.3
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• pp.325-330
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• 1999

This study aims to observe the inhibition of methane generation, the decomposition of organic matter, and the trend of outflowing leachate, using the simulated column of the anaerobic sanitary landfill structure of sulfate addition type which is made by adding sulfate to a current anaerobic landfill structure, and the simulated column of semi-aerobic landfill structure in the laboratory which is used in the country like Japan in order to inhibit methane from a landfill site among the gases caused by a global warming these days, and at the same time to promote the decomposition of organic matter, the index of stabilization of landfill site. As a result of this study, it is thought that the ORP(Oxidation Reduction Potential) of the column of semi-aerobic landfill structure gradually represents a weak aerobic condition as time goes by, and that the inside of landfill site is likely to by in progress into anaerobic condition, unless air effectively comes into a semi-aerobic landfill structure in reality as time goes by. In addition, it can be seen that the decomposition of organic matter is promoted according to sulfate reduction in case of $R_1$, a sulfate-added anaerobic sanitary landfill structure, and that the stable decomposition of organic matter in $R_1$ makes a faster progess than $R_2$. Moreover it can be estimated that $R_1$, a sulfate-added anaerobic sanitary landfill structure has an inhibition efficiency of 55% or so, compared with $R_2$, a semi-aerobic landfill structure, in the efficiency of inhibiting methane.

• Journal of Korean Society on Water Environment
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• v.38 no.2
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• pp.95-102
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• 2022

Studies for improving the efficiency of the traditional anaerobic digestion process are being actively conducted. To improve anaerobic digestion efficiency, this study tried to derive the optimal pretreatment conditions and mixing conditions by integrating the heat solubilization pretreatment of sewage sludge, livestock manure, and food waste. The soluble chemical oxygen demand (SCOD) increase rate of sewage sludge before and after heat solubilization pretreatment showed an increased rate of 224.7% compared to the control group at 170℃ and 25 min and showed the most stable increase rate. As a result of the biomethane potential test of sewage sludge before and after heat solubilization pretreatment, the total chemical oxygen demand (TCOD) and SCOD removal rates increased as the heat solubilization temperature increased, but did not increase further at temperatures above 170℃. In the case of methane generation, there was no significant change in the cumulative methane generation from 0.134 to 0.203 Sm³-CH₄/kg-COD at 170℃ for 15 min. As a result of the integrated digestion of organic waste, the experimental condition in which 25% of the sewage sludge, 50% of the food waste, and 25% of the livestock manure were mixed showed the highest methane production of 0.3015 m³-CH₄/kg-COD, confirming that it was the optimal mixing ratio condition. In addition, under experimental conditions mixed with all three substrates, M4 conditions mixed with 25% sewage sludge, 50% food waste, and 25% livestock manure showed the highest methane generation at 0.2692 Sm³-CH₄/kg-COD.