• Journal of Korean Society of Environmental Engineers
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• v.38 no.10
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• pp.535-542
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• 2016

As one of the most cost-effective methods for surface emission measurements, flux chamber method has been used worldwide. It can be classified into two types: SFC (with slope method) and DFC (with steady-state method). SFC (static flux chamber) type needs only simple equipment and is easy to handle. However, the value of flux might vary with SFC method, because it assumes that the change of concentration in chamber is linear with time. Although more specific equipments are required for DFC (dynamic flux chamber) method, it can lead to a constant result without any ambiguity. We made a self-designed DFC using a small and compact kit, which recorded good sample homogeneity (RSD < 5%) and recovery ( > 90%). Relative expanded measurement uncertainty of this improved DFC method was 7.37%, which mainly came from uncontrolled sweep air. The study shows that the improved DFC method can be used to collect highly reliable emission data from large landfill area.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.531-533
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• 2007

We report and discuss molecular and isotopic properties of hydrate-bound gases from 55 samples and void gases from 494 samples collected during Ocean Drilling Program (ODP) Leg 204 at Hydrate Ridge offshore Oregon. Gas hydrates appear to crystallize in sediments from two end-member gas sources (deep allochthonous and in situ) as mixtures of different proportions. In an area of high gas flux at the Southern Summit of the ridge (Sites 1248-1250), shallow (0-40 meters below the seafloor (mbsf)) gas hydrates are composed of mainly allochthonous mixed microbial and thermogenic methane and a small portion of thermogenic C2+ gases, which migrated vertically and laterally from as deep as 2-2.5 km depths. In contrast, deep (50-105 mbsf) gas hydrates at the Southern Summit (Sites 1248 and 1250) and on the flanks of the ridge (Sites 1244-1247) crystallize mainly from microbial methane and ethane generated dominantly in situ. A small contribution of allochthonous gas may also be present at sites where geologic and tectonic settings favor vertical gas migration from greater depth (e.g., Site 1244).

• Fire Science and Engineering
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• v.25 no.5
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• pp.128-133
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• 2011

The present study performs a series of 40 % reduced scale of ISO-9705 fire test to investigate the characteristics of heat flux on the floor level in terms of fire characteristics and location in the compartment. The heat flux was measured with Schmidt-Boelter type heat flux gauge at two locations on the floor level of inside and doorway side of the compartment. Different types of fuel - methane, heptane, toluene, ethanol, polystyrene - were burned in this test series. The measured heat flux inside of the compartment was relatively higher than that of front side as the heat release rate of fire and upper layer temperature increased. The difference of measured heat flux at inside and doorway side increased for high sooty fire. The present study shows that the heat flux distribution at lower layer greatly depend on the thermal radiation from fire and upper layer, not only the upper layer temperature but also various fire characteristics such as composition of combustion gases, soot concentration, ventilation condition and so on.

• Journal of Korean Society of Disaster and Security
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• v.16 no.4
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• pp.45-59
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• 2023

The global focus on mitigating climate change has traditionally centered on carbon dioxide, but recent attention has shifted towards methane as a crucial factor in climate change adaptation. Natural settings, particularly aquatic environments such as wetlands, reservoirs, and lakes, play a significant role as sources of greenhouse gases. The accumulation of organic contaminants on the lake and reservoir beds can lead to the microbial decomposition of sedimentary material, generating greenhouse gases, notably methane, under anaerobic conditions. The escalation of methane emissions in freshwater is attributed to the growing impact of non-point sources, alterations in water bodies for diverse purposes, and the introduction of structures such as river crossings that disrupt natural flow patterns. Furthermore, the effects of climate change, including rising water temperatures and ensuing hydrological and water quality challenges, contribute to an acceleration in methane emissions into the atmosphere. Methane emissions occur through various pathways, with ebullition fluxes-where methane bubbles are formed and released from bed sediments-recognized as a major mechanism. This study employs Biochemical Methane Potential (BMP) tests to analyze and quantify the factors influencing methane gas emissions. Methane production rates are measured under diverse conditions, including temperature, substrate type (glucose), shear velocity, and sediment properties. Additionally, numerical simulations are conducted to analyze the relationship between fluid shear stress on the sand bed and methane ebullition rates. The findings reveal that biochemical factors significantly influence methane production, whereas shear velocity primarily affects methane ebullition. Sediment properties are identified as influential factors impacting both methane production and ebullition. Overall, this study establishes empirical relationships between bubble dynamics, the Weber number, and methane emissions, presenting a formula to estimate methane ebullition flux. Future research, incorporating specific conditions such as water depth, effective shear stress beneath the sediment's tensile strength, and organic matter, is expected to contribute to the development of biogeochemical and hydro-environmental impact assessment methods suitable for in-situ applications.

• Korean Journal of Agricultural and Forest Meteorology
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• v.20 no.1
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• pp.88-100
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• 2018

Methane emissions from rice paddies are the largest source of greenhouse gases in the agricultural sector, but there are significant regional differences depending on the surrounding conditions and cultivation practices. To visualize these differences and to analyze their causes and characteristics, the methane emissions from each administrative district in South Korea were calculated according to the IPCC guidelines using the data from the 2010 Agriculture, Forestry and Fisheries Census, and then the results were mapped by using the ArcGIS. The nationwide average of methane emissions per unit area was $380{\pm}74kg\;CH_4\;ha^{-1}\;yr^{-1}$. The western region showed a trend toward higher values than the eastern region. One of the major causes resulting in such regional differences was the $SF_o$ (scaling factor associated with the application of organic matter), where the number of cultivation days played an important role to either offset or deepen the differences. Comparison of our results against the actual methane emissions data observed by eddy covariance flux measurement in the three KoFlux rice paddy sites in Gimje, Haenam and Cheorwon showed some differences but encouraging results with a difference of 10 % or less depending on the sites and years. Using the updated GWP (global warming potential) value of 28, the national total methane emission in 2010 was estimated to be $8,742,000tons\;CO_2eq$ - 13% lower than that of the National Greenhouse Gas Inventory Report (i.e., $10,048,000tons\;CO_2eq$). The administrative districts-based map of methane emissions developed in this study can help identify the regional differences, and the analysis of their key controlling factors will provide important scientific basis for the practical policy makings for methane mitigation.

• Korean Journal of Environmental Agriculture
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• v.32 no.4
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• pp.252-259
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• 2013

BACKGROUND: Salt accumulation in coastal reclaimed soil can decrease plant growth and productivity, which could lead to considerable variation of methane($CH_4$) emission in a rice paddy. The objective of this study was to evaluate the effect of salt concentration on $CH_4$ emission in a coastal reclaimed soil. METHODS AND RESULTS: The effect of salt concentration on $CH_4$ emission and rice growth characteristics was studied by pot test, which packed by reclaimed paddy soils collected from Galsa, Hadong, Gyeongnam province. Electrical conductivity(EC) of each treatment was controlled by 0.98, 2.25, 5.05 and 9.48 dS/m and $CH_4$ emission was characterized a week interval by closed chamber method during rice cultivation. The $CH_4$ emission rate was significantly decreased with increase of salt accumulation, but total $CH_4$ flux in EC 5.50 dS/m treatment was lower than those of EC 9.48 dS/m treatment. It seems because of higher content of water soluble $SO{_4}^{2-}$ in EC 5.50 dS/m treatment than those of EC 9.48 dS/m treatment. Rice growth and grain yield were significantly decreased with increase of salt accumulation. Soil properties, especially EC and pH were negatively correlated with $CH_4$ flux, while rice growth characteristics like plant height and tiller number show significantly positive correlation with $CH_4$ flux. CONCLUSION(S): Conclusively, salt accumulation significantly decreased $CH_4$ flux in a rice paddy, which could be useful information for evaluating $CH_4$ flux in reclaimed area in Korea.

• Journal of Wetlands Research
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• v.21 no.2
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• pp.95-101
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• 2019

In tidal flats that lack plants, methane ($CH_4$) fluxes are both positive (gas emission) and negative (gas "sinking") in nature. The levels of methanotroph populations significantly affect the extent of $CH_4$ sinking. This preliminary study examined $CH_4$ flux in tidal flats using a circular closed-chamber method to understand the effects of macroinvertebrate burrowing activity. The chamber was deployed over decapods (mud shrimp, Laomedia astacina and crab, Macrophthalmus japonicus) burrows for ~ 2 h, and the $CH_4$ and $CO_2$ concentrations were continuously monitored using a closed, diffuse $CH_4/CO_2$ flux meter. We found that Laomedia astacina burrow (which is relatively long) site afforded higher-level $CH_4$ production, likely due to diffusive emission of $CH_4$ in deep-layer sediments. In addition, the large methanotrophic bacteria population found in the burrow wall sediments has $CH_4$ oxidation (consumption) potential. Especially, nitrite-driven anaerobic oxidation of methane (AOM) may occur within burrows. The proposed $CH_4$-oxidation process was supported by the decrease in the ${\delta}^{13}C$ of headspace $CO_2$ during the chamber experiment. Therefore, macroinvertebrate burrows appear to be an important ecosystem environment for controlling atmospheric $CH_4$ over tidal flats.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.19-24
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• 2002

Recent studies of a triple flame suggested that the presence of triple point (triple line in this planar configuration) could explain the mechanisms of stable fuel-lean premixed flames with equivalence ratio lower than the flammability limit. In the present study, for better understanding of the stability mechanisms of fuel rich-lean premixed flames, the fuel-rich flames were replaced with hot coils that will provide heat flux into the fuel-lean flames. It is found that the fuel-lean premixed flames could be stabilized without any triple point (triple line): however, the equivalence ratio limit for stable fuel-lean flame in this case is higher than that of the present work with the presence of fuel-rich flames. These results demonstrate that heat flux coming from fuel-rich flames should be considered in order to properly understand the roll of a triple flame for stable fuel rich-lean flames.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.5.1-5.1
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• 2010

One of the most important environmental problems is global warming. Global warming is caused by increase in the amounts of water vapor, methane, carbon dioxide and other gases being released into the atmosphere as a result of the burning of fossil fuels. It has thus become important to reduce fossil fuel use. Environmentally friendly preparation of functional materials has, therefore, attracted much interest for environmental problems. Furthermore, nature mimetic processes are recently been of great interest as environmentally friendly one. There have been many studies on fabrication of various functional nanocrystals. Among various nanocrystal fabrication techniques, flux growth is an environmentally friendly, very convenient process and can produce functional nanocrystals at temperatures below the melting points of the solutes. Furthermore, this technique is suitable for the synthesis of crystals having an enhedral habit. In flux growth, the constituents of the materials to be crystallized are dissolved in a suitable flux (solvent) and crystal growth occurs as the solution becomes critically supersaturated. The supersaturation is attained by cooling the solution, by evaporation of the solvent or by a transport process in which the solute is made to flow from a hotter to a cooler region. Many kinds of oxide nanocrystals have been grown in our laboratory. For example, zero- (e.g., particle), one- (e.g., whisker and tube) and two-dimensional (e.g., sheet) nanocrystals were successfully grown by flux method. Our flux-growth technique has some industrial and ecological merits because the nanocrystal fabrication temperatures are far below their melting points and because the used reagents are less harmless to human being and the environment.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.28-35
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• 2018

In order to analyze the flammability limit and structure of the gaseous methane-gaseous oxygen diffusion flame formed through a shear coaxial injector, combustion experiments were carried out according to the condition of injector recess and propellant mass-flow rate. As a result, it was confirmed that stable anchored flame was observed even at the high oxygen Reynolds number as the propellant momentum flux ratio increased, and that the recess had no significant influence on the flame shape and flammability limit. The anchored flame visualized through a chemiluminescence showed the maximum OH radical emission intensity at a specific position, irrespective of the propellant injection condition, and the radical intensity was greatly reduced by the injector recess.