• Title/Summary/Keyword: Methane emission

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Greenhouse gases emission from aerobic methanotrophic denitrification (AeOM-D) in sequencing batch reactor

  • Lee, Kwanhyoung;Choi, Oh Kyung;Lee, Jae Woo
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.171-184
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    • 2017
  • This study presents the effect of hydraulic retention time (HRT) on the characteristics of emission of three major greenhouse gases (GHGs) including $CH_4$, $CO_2$ and $N_2O$ during operation of a sequencing batch reactor for aerobic oxidation of methane with denitrification (AeOM-D SBR). Dissolved $N_2O$ concentration increased, leveled-off and slightly decreased as the HRT increased from 0.25 to 1d. Concentration of the dissolved $N_2O$ was higher at the shorter HRT, which was highly associated with the lowered C/N ratio. A longer HRT resulted in a higher C/N ratio with a sufficient carbon source produced by methanotrophs via methane oxidation, which provided a favorable condition for reducing $N_2O$ formation. With a less formation of the dissolved $N_2O$, $N_2O$ emission rate was lower at a longer HRT condition due to the lower C/N ratio. Opposite to the $N_2O$ emission, emission rates of $CH_4$ and $CO_2$ were higher at a longer HRT. Longer HRT resulted in the greater total GHGs emission as $CO_2$ equivalent which was doubled when the HRT increased from 0.5d to 1.0 d. Contribution of $CH_4$ onto the total GHGs emission was most dominant accounting for 98 - 99% compared to that of $N_2O$ (< 2%).

The Effects of Nitrogen Fertilizers and Cultural Patterns on Methane Emission From Rice Paddy Fields (논토양에서 질소비종 및 벼 재배양식이 메탄가스 발생에 미치는 영향)

  • Ko, Jee-Yeon;Kang, Hang-Won;Kang, Ui-Gum;Park, Hang-Mee;Lim, Dong-Kuy;Park, Kyeng-Bae
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.227-233
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    • 1998
  • To mitigate the methane emission from rice paddy fields, effects of nitrogen fertilizers source and cultural patterns were evaluated on silty loam soils. And a pot experiment was carried out to find out the effects of nitrogen fertilizers on soil pH, Eh, sulfate concentration of soil water in flooded soil. In transplanting cultivation, the total methane emission depending on fertilizers was $32.9gm^{-2}$ for urea ; $30.3gm^{-2}$ for ammonium sulfate ; $26.4gm^{-2}$ for coated urea. Methane emitted in direct seeding on dry soil was $24.7gm^{-2}$ for urea ; $16.7gm^{-2}$ for ammonium sulfate : and $22.8gm^{-2}$ for coated urea. Thus, the methane emission rate of direct seeding on dry soil was 29.7% lower than transplanting. According to the nitrogen fertilizers, the methane emission rate by ammonium sulfate and coated urea were reduced 18.4 and 15.9% in comparison with urea, respectively. In pot experiments, pH in flooded soils depending on nitrogen fertilizers dereased in order of urea > coated $urea{\fallingdotseq}no$ fertilizer > ammonium sulfate and the order was coincided with that of total $CH_4$ emission from flooded soil. Soil Eh was highest in ammonium sulfate application followed by coated urea, no fertilizer, urea. And sulfate concentrations of soil water were in order of ammonium sulfate > coated urea > urea > no fertilizer.

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Analysis of surface emission and oxidation rate of landfill gas by major discharge path of landfill (매립장 주요 배출경로별 매립가스 표면발산량 및 산화율 분석)

  • Seung-Kyu Chun;Jong-Keun Park;Myoung-Gwan Kim
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.3
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    • pp.425-434
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    • 2023
  • An analysis was conducted on landfill gas generation and surface emission by major routes for three landfill sites of S Landfill in the metropolitan area. LS1, which had a total landfill gas generation ratio of 10.9%, accounted for 49.4% of the total surface emissions. The total surface emission of methane alone was 13.6 Nm3/min in the three landfill sites. Among them, the surface emission of methane at LS1, LS2, and LS3 was 8.4(61.7%), 4.0(29.4%), and 1.2 Nm3/min(8.9%), respectively. By emission path in the upper, slope, and dike, it was 7.3(53.2%), 6.4(46.7%), and 0.02 Nm3/min(0.1%). The dike section of the major surface emission areas showed the largest oxidation rate at 87.5%, followed by the upper at 72.3%, and the slope at 71.8%. Based on methane generation, LS1 had the largest surface emission contribution rate, with 61.7% of the total by S Landfill. By major emission path, the slope section of LS1 accounted for 41.7% of the total, the upper section of LS2 24.4%, and the upper section of LS1 20.0%, which accounted for 86.1% of the total methane surface emission of S Landfill. Therefore, it is concluded that intensive management will be necessary.

Effects of Application of Nitrogen Fertilizers on Methane Emission in a Paddy Soil (논 토양에서 질소비종이 CH4 배출에 미치는 영향)

  • Lee, Kyeong-Bo;Lee, Deog-Bae;Kim, Jong-Gu;Lee, Sang-Bok;Kim, Jae-Duk;Han, Sang-Su
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.3
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    • pp.212-219
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    • 2000
  • This study was conducted to investigate methane emission among nitrogen fertilizers in paddy soil(Jeonbug series, occurring on fluvio-alluvial plain). The application rates of rice straw was $5,000kg\;ha^{-1}$ with $110kg\;N\;ha^{-1}$ as chemical fertilizer. It was found that the methane flux tended to be lower in ammonium sulfate than in urea and latex coated urea(LCU). The seasonal variations of the methane emission flux was high during the heading stage of the rice plant. Methane concentration in the soil solution was the highest at 5cm depth, but decreased with upper and lower depth. Methane emission under rice straw application was $0.265g\;m^{-2}\;day^{-1}$ by urea application. $0.207g\;m^{-2}\;day^{-1}$ by ammonium sulfate application, $0.318g\;m^{-2}\;day^{-1}$ by latex coated urea(LCU) application while methane emission under non rice straw application was $0.192g\;m^{-2}\;day^{-1}$ by urea application, $0.165g\;m^{-2}\;day^{-1}$ by ammonium sulfate application, $0.179g\;m^{-2}\;day^{-1}$ by latex coated urea(LCU) application.

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The Influence of a Vortex on a Freely Propagating Laminar Methane-Air Flame

  • Lee, Ki-Yong
    • Journal of Mechanical Science and Technology
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    • v.18 no.5
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    • pp.857-864
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    • 2004
  • The change in the NO emission indices (EINO) in a two-dimensional plane has been investigated, which is due to the interaction between a vortex and methane-air flames established at different equivalence ratios, by solving the field equation. After solving the field equation, the spatial distribution of G-values is obtained. The NO emission index is calculated after applying the appropriate relation between the G-values and the NO production rate or the mass fraction of methane obtained from the library of freely propagating flames created from detailed simulations. When a vortex exists in a reacting flow field, in general EINO slightly increases, whereas ElNO is lowered in the vicinity of the vortex regardless of flow direction. A change in vortex size has negligible impact on EINO$\_$T/ but increasing the vortex strength slightly increases EINO$\_$T/ in the domain of this study.

Measurement Uncertainty of Methane Concentrations from a Rice Paddy Measured by a Closed Automated Chamber System (벼논에서 폐쇄형 자동 챔버 시스템으로 측정한 메탄 농도에 대한 요인별 측정 불확도 비교)

  • Ju, Ok Jung;Kang, Namgoo;Lim, Gap June
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.228-236
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    • 2020
  • BACKGROUND: The closed chamber method is the most commonly used for measuring greenhouse gas emissions from rice fields. This method has the advantages of being simple, easily available and economical. However, a measurement result using the chamber method is an estimated value and is complete when the uncertainty is estimated. The methane emissions from a rice paddy account for the largest portion of the greenhouse gas emissions in the agriculture sectors. Although assessment of uncertainty components affecting methane emission from a rice paddy is necessary to take account of dispersion characteristics, research on these uncertainty components is very rare to date. The goal of this study was to elucidate influencing factors on measurement uncertainty of methane concentrations measured by a closed automated chamber system from a rice paddy. METHODS AND RESULTS: The methane sampling system is located in the rice paddy in Gyeonggi-do Agricultural Research and Extension Services (37°13'15"N, 127°02'22"E). The primary measurement uncertainty components influencing methane concentrations (influencing factors) investigated in this research were repeatability, reproducibility and calibration in the aspects of methane sampling and analytical instrumentation. The magnitudes of the relative standard uncertainty of each influencing factor were quantified and compared. CONCLUSION: Results of this study showed what influencing factors were more important in determination of methane concentrations measured using the chamber system and analytical instrumentation located in the monitoring site. Quantifying the measurement uncertainty of the methane concentrations in this study would contribute to improving measurement quality of methane fluxes.

Estimation of National Greenhouse Gas Emissions in Agricultural Sector from 1990 to 2013 - Focusing on the Crop Cultivation - (1990년부터 2013년까지 농업 분야 국가 온실가스 배출량 평가 - 경종부문 중심으로 -)

  • Choi, Eun Jung;Jeong, Hyun Cheol;Kim, Gun Yeob;Lee, Sun-il;Lee, Jong Sik
    • Journal of Climate Change Research
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    • v.7 no.4
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    • pp.443-450
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    • 2016
  • The major greenhouse gases (GHGs) in agricultural sector are methane ($CH_4$), nitrous oxide ($N_2O$), carbon dioxide ($CO_2$). GHGs emissions are estimated by pertinent source category in a guideline book from Intergovernmental Panel on Climate Change (IPCC) such as methane from rice paddy, nitrous oxide from agricultural soil and crop residue burning. The methods for estimation GHGs emissions in agricultural sector are based on 1996 and 2006 IPCC guideline, 2000 and 2003 Good Practice Guidance. In general, GHG emissions were calculated by multiplying the activity data by emission factor. The total GHGs emission is $10,863Gg\;CO_2-eq$. from crop cultivation in agricultural sector in 2013. The emission is divided by the ratio of greenhouse gases that methane and nitrous oxide are 64% and 34%, respectively. Each gas emission according to the source categories is $7,000Gg\;CO_2-eq$. from rice paddy field, $3,897Gg\;CO_2-eq$. from agricultural soil, and $21Gg\;CO_2-eq$. from field burning, respectively. The GHGs emission in agricultural sector had been gradually decreased from 1990 to 2013 because of the reduction of cultivation. In order to compare with indirect emissions from agricultural soil, each emission was calculated using IPCC default factors (D) and country specific emission factors (CS). Nitrous oxide emission by CS applied in indirect emission, as nitrogen leaching and run off, was lower about 50% than that by D.

Effects of Flavonoid-rich Plant Extracts on In vitro Ruminal Methanogenesis, Microbial Populations and Fermentation Characteristics

  • Kim, Eun T.;Guan, Le Luo;Lee, Shin J.;Lee, Sang M.;Lee, Sang S.;Lee, Il D.;Lee, Su K.;Lee, Sung S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.4
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    • pp.530-537
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    • 2015
  • The objective of this study was to evaluate the in vitro effects of flavonoid-rich plant extracts (PE) on ruminal fermentation characteristics and methane emission by studying their effectiveness for methanogenesis in the rumen. A fistulated Holstein cow was used as a donor of rumen fluid. The PE (Punica granatum, Betula schmidtii, Ginkgo biloba, Camellia japonica, and Cudrania tricuspidata) known to have high concentrations of flavonoid were added to an in vitro fermentation incubated with rumen fluid. Total gas production and microbial growth with all PE was higher than that of the control at 24 h incubation, while the methane emission was significantly lower (p<0.05) than that of the control. The decrease in methane accumulation relative to the control was 47.6%, 39.6%, 46.7%, 47.9%, and 48.8% for Punica, Betula, Ginkgo, Camellia, and Cudrania treatments, respectively. Ciliate populations were reduced by more than 60% in flavonoid-rich PE treatments. The Fibrobacter succinogenes diversity in all added flavonoid-rich PE was shown to increase, while the Ruminoccocus albus and R. flavefaciens populations in all PE decreased as compared with the control. In particular, the F. succinogenes community with the addition of Birch extract increased to a greater extent than that of others. In conclusion, the results of this study showed that flavonoid-rich PE decreased ruminal methane emission without adversely affecting ruminal fermentation characteristics in vitro in 24 h incubation time, suggesting that the flavonoid-rich PE have potential possibility as bio-active regulator for ruminants.

Estimation of Methane Generation Rate and Potential Methane Generation Capacity at Cheongju Megalo Landfill Site Based on LandGEM Model (LandGEM 모델을 이용한 청주권 생활폐기물 매립장의 매립지가스 발생상수 및 메탄 잠재발생량 산정)

  • Hong, Sang-Pyo
    • Journal of Environmental Health Sciences
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    • v.34 no.6
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    • pp.414-422
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    • 2008
  • Methane is a potent greenhouse gas and methane emissions from landfill sites have been linked to global warming. In this study, LandGEM (Landfill Gas Emission Model) was applied to predict landfill gas quantity over time, and then this result was compared with the data surveyed on the site, Cheongju Megalo Landfill. LandGEM allows the input of site-specific values for methane generation rate (k) and potential methane generation capacity $L_o$, but in this study, k value of 0.04/yr and $L_o$ value of $100\;m^3$/ton were considered to be most appropriate for reflecting non-arid temperate region conventional landfilling like Cheongju Megalo Landfill. Relatively high discrepancies between the surveyed data and the predicted data about landfill gas seems to be derived from insufficient compaction of daily soil-cover, inefficient recovery of landfill gas and banning of direct landfilling of food waste in 2005. This study can be used for dissemination of information and increasing awareness about the benefits of recovering and utilizing LFG (landfill gas) and mitigating greenhouse gas emissions.

Effects of tannin supplementation on growth performance and methane emissions of Hanwoo beef cows

  • Jeong, Sinyong;Lee, Mingyung;Jeon, Seoyoung;Kang, Yujin;Kang, Heejin;Seo, Seongwon
    • Korean Journal of Agricultural Science
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    • v.45 no.3
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    • pp.463-473
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    • 2018
  • The objective of this study was to investigate the effects of dietary hydrolysable tannin on growth performance and methane emissions of Hanwoo beef cows. Fifteen cows participated in a seven-week experiment. The cows were stratified by initial methane emissions and assigned to one of two treatments: Control and tannin supplementation. Commercial hydrolysable tannin was top-dressed to a concentrate mix at 3 g/kg based on the dry matter. Enteric methane production was measured for 4 consecutive days at 1 week before and 1, 3 and 7 weeks after the initiation of the experiment using a laser methane detector. The feed intake was measured daily during the methane measurement periods and an additional two days prior to each measurement. The body weight of the cows was measured every 4 weeks. Hydrolysable tannin had no effect (p > 0.05) on body weight, average daily gain, dry matter intake (DMI) and feed conversion ratio. After one week, the methane emission of the tannin supplementation group was 3.66 ppm-m / kg DMI, which was about 3.4% lower (p = 0.078) than that of the control group; however, this tendency disappeared at 3 weeks after the start of the experiment (p > 0.05). The results of this study show that hydrolysable tannin supplementation can reduce enteric methane emissions for a limited period in Hanwoo beef cows. More research, however, is needed to determine the optimal level of hydrolysable tannin supplementation to reduce enteric methane emissions for a longer period without adversely affecting the animal performance of Hanwoo beef cattle.