• Composites Research
• /
• v.36 no.5
• /
• pp.377-382
• /
• 2023

To enhance the performance of graphene-based devices, it is of great importance to better understand the interfacial interaction of graphene with its underlying substrates. In this study, the adhesion energy of monolayer graphene placed on dielectric substrates was characterized using mode I fracture tests. Large-area monolayer graphene was synthesized on copper foil using chemical vapor deposition (CVD) with methane and hydrogen. The synthesized graphene was placed on target dielectric substrates using polymer-assisted wet transfer technique. The monolayer graphene placed on a substrate was mechanically delaminated from the dielectric substrate by mode I fracture tests using double cantilever beam configuration. The obtained force-displacement curves were analyzed to estimate the adhesion energies, showing 1.13 ± 0.12 J/m² for silicon dioxide and 2.90 ± 0.08 J/m² for silicon nitride. This work provides the quantitative measurement of the interfacial interactions of CVD-grown graphene with dielectric substrates.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.30 no.4 s.247
• /
• pp.320-327
• /
• 2006

The computations of chemically reacting laminar and turbulent flows are performed using the preconditioned Navier-Stokes solver coupled with turbulent transport and multi-species equations. A low-Reynolds number $k-\varepsilon$ turbulence model proposed by Chien is used. The presence of the turbulent kinetic energy tenn in the momentum equation can materially affect the overall stability of the fluids-turbulence system. Because of this coupling effect, a fully coupled formulation is desirable and this approach is taken in the present study. Choi and Merkle's preconditioning technique is used to overcome the convergence difficulties occurred at low speed flows. The numerical scheme used for the present study is based on the implicit upwind ADI algorithm and is validated through the comparisons of computational and experimental results for laminar methane-air diffusion flame and $ H_2/O_2$ reacting turbulent shear flow. Preconditioning formulation shows better convergence characteristics than that of non-preconditioned system by approximately five times as much.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.293-293
• /
• 2010

Carbon nanotubes (CNTs) have attracted considerable attention as possible routes to device miniaturization due to their excellent mechanical, thermal, and electronic properties. These properties show great potential for devices such as field emission displays, CNT based transistors, and bio-sensors. The metals such as nickel, cobalt, gold, iron, platinum, and palladium are used as the catalysts for the CNT growth. In this study, diamond-like carbon (DLC) was used for CNT growth as a nonmetallic catalyst layer. DLC films were deposited by a radio frequency (RF) plasma-enhanced chemical vapor deposition (RF-PECVD) method with a mixture of methane and hydrogen gases. CNTs were synthesized by a hot filament plasma-enhanced chemical vapor deposition (HF-PECVD) method with ammonia (NH3) as a pretreatment gas and acetylene (C2H2) as a carbon source gas. The grown CNTs and the pretreated DLC filmswere observed using field emission scanning electron microscopy (FE-SEM) measurement, and the structure of the grown CNTs was analyzed by high resolution transmission scanning electron microscopy (HR-TEM). Also, using energy dispersive spectroscopy (EDS) measurement, we confirmed that only the carbon component remained on the substrate.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.157-157
• /
• 2011

Graphene has generated significant interest in the recent years as a functional material for electronics, sensing, and energy applications due to its unique electrical, optical, and mechanical properties. Much of the considerable interest in graphene stems from results obtained for samples mechanically exfoliated from graphite. Practical applications, however, require reliable and well-controlled methods for fabrication of large area graphene films. Recently high quality graphene layers were fabricated using chemical vapor deposition (CVD) on nickel and copper with methane as the source of the carbon atoms. Here, we report a simple and efficient method to synthesize graphene layers using solid carbon source. Few-layer graphene films are grown using filtered vacuum arc source (FVAS) technique by evaporation of carbon atom on Ni catalytic metal and subsequent annealing of the samples at 800$^{\circ}$C. In our system, carbon atoms diffuse into the Ni metal layer at elevated temperatures followed by their segregation as graphene on the free surface during the cooling down step as the solubility of carbon in the metal decrease. For a given annealing condition and cooling rate, the number of graphene layers is easily controlled by changing the thickness of the initially evaporated amorphous carbon film. Based on the Raman analysis, the quality of graphene is comparable to other synthesis methods found in the literature, such as CVD and chemical methods.

• Membrane Journal
• /
• v.33 no.6
• /
• pp.352-361
• /
• 2023

Steam methane reforming is currently the most widely used technology for producing hydrogen, a clean fuel. Hydrogen produced by steam methane reforming contains impurities such as carbon monoxide, and it is essential to undergo an appropriate post-purification step for commercial usage, such as fuel cells. Recently, membrane separation technology has been gaining great attention as an effective purification method; in this study, we evaluated the feasibility of using commercial polysulfone membranes for biogas upgrading to separate and recover hydrogen from a hydrogen/carbon monoxide gas mixture. Initially, we examined the physicochemical properties of the commercial membrane used. We then conducted performance evaluations of the commercial membrane module under various conditions using mixed gas, considering factors such as stage-cut and operating pressure. Finally, based on the evaluation results, we carried out simulations for process design. The maximum H₂ permeability and H₂/CO separation factor for the commercial membrane process were recorded at 361 GPU and 20.6, respectively. Additionally, the CO removal efficiency reached up to 94%, and the produced hydrogen concentration achieved a maximum of 99.1%.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.208-208
• /
• 2009

메탄의 수증기-이산화탄소 복합개질반응에서 니켈 촉매의 탄소 침적 저항성에대한 Ce 증진 효과를 살펴보기 위해, Ni-Ce/${\alpha}-Al_2O_3$ 촉매를 제조하였다. Ce/Ni 비율 변화에 따른 촉매 비표면적, Ni 입자 분산도 및 촉매 활성 변화를 살펴보았고, Ce 첨가량을 최적화 할 수 있었다. Ce/Ni 비율 증가에 따라 NiO 결정크기가 감소하고 표면적과 Ni 분산도는 증가하였다. 특히, Ce/Ni=0.5 첨가 시, 촉매는 가장 넓은 비표면적과 Ni 분산도를 가졌으며, 우수한 촉매 활성 및 높은 탄소 침적 저항성을 보였다. 또한, 본 연구에서는 Ni과 Ce 담지 방법에 따른 Ni 분산도 향상과 Ni과 Ce간의 접촉 면적 극대화를 통한 활성산소 공급 향상에 대한 영향을 함께 살펴보았다. Ni과 Ce를 동시 함침법과 연속 함침법으로 담지하여 비교한 결과, 동시 함침법으로 제조한 Ni-Ce/${\alpha}-Al_2O_3$ (Ce/Ni=0.5) 촉매가 가장 우수한 촉매 성능 및 높은 탄소 침적 저항성을 보였다. 이는 동시 함침법으로 고분산된 Ni 입자와 담체간의 강한 상호작용 형성과 원활한 활성 산소 공급에 기인한 것이다.

• The Journal of Industrial Distribution & Business
• /
• v.14 no.4
• /
• pp.23-31
• /
• 2023

Purpose: Gas firms often fall victim to disregarding the importance of sensitivity, thus leading to many unprecedented repercussions. To ensure that gas firms fully contribute to sustainability and ethical standards, environmental Social Governance (ESG) has been identified as the ideal framework. This study aims to investigate the impact of ESG management for improving gas firm performance. Research design, data and methodology: The prior qualitative literature analysis was to figure out adequate past research for the topic based on the major portal web databased, such as 'Google Scholar' and 'Scopus' to make sure resources' credibility. Results: Gas firms are among the pertinent organizations vis-à-vis environmental destruction issues. Gas firms emit dangerous gases such as ethane, carbon dioxide and methane that are dangerous for the people and the environment. Thus, many pro-environmental conservation stakeholders have had rallying calls for such gas firms to mitigate environmental pollution intentionally. Conclusions: This study may be used to human resources in improving employee results elsewhere. Besides, it can be of the essence in improving the relationship between such firms and society. Therefore, the study findings are of greater significance and implications to multiple parties, users and stakeholders regarding the research topic and beyond the current scope of the study.

• Journal of Energy Engineering
• /
• v.23 no.3
• /
• pp.125-131
• /
• 2014

In order to increase landfill gas (LFG) production with food waste leachate, this study was confirmed to be acidogenetic conditions for landfill site injection. Thereby, it was conducted for acidogenetic treatments to determine the decrease in viscosity and VFA production. After acidogenesis treatments, solubility of food waste leachate increased approximately 15%, and as a result, UASB and CSTR were similar by reactor type using the change of retention time. Based on the result of the change in viscosity by reactor type, efficiency of UASB showed approximately 11.38% of higher decrease in viscosity as $76.95{\pm}3.27%$ vs. CSTR. Also, VFA production showed the higher increase of 2.01 times (UASB) and 1.76 times (CSTR) respectively at the point of increasing retention time from 3 to 5 days. From the above results, efficiency of UASB in a reactor was relatively higher because large molecular lead to longer retention time than small molecular due to having screen effect in the fixed media.

• Clean Technology
• /
• v.26 no.1
• /
• pp.55-64
• /
• 2020

According to the Korean Renewable Energy 3020 Implementation Plan, the installation capacity of renewable energy is expected to increase whereas technology for storing excess electricity and stabilizing the power supply of renewable energy sources is extremely required. Power-to-Gas is one of energy storage technologies where electricity is converted into gas fuel such as hydrogen and methane. Basically, Power-to-Gas system could be effectively utilized to store excess electricity generated by an imbalance between supply and demand. In this study, the economic feasibility analysis of Power-to-Gas reflecting the domestic situation was carried out. Total revenue requirement method was utilized to estimate the levelized cost of hydrogen. Validation on the economic analysis method in this study was conducted by comparison of the result, which is published by the International Energy Agency. The levelized cost of hydrogen of a 100-MW Power-to-Gas system reflecting the current economic status in Korea is 8,344 won kg^-1. The sensitivity analysis was carried out, applying the main analysis economic factors such as electricity cost, electrolyser cost, and operating year. Based on the sensitivity analysis, the conditions for economic feasibility were suggested by comparing the cost of producing hydrogen using renewable energy with the cost of producing natural gas reformed hydrogen with carbon capture and storage.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.3
• /
• pp.386-401
• /
• 2011

Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.