• 한국연소학회지
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• 제13권2호
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• pp.14-22
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• 2008

The CH* chemiluminescence of premixed flames and their dependency on fuel types has been experimentally investigated on laminar methane and propane premixed flames. The measured chemiluminescence intensities are observed linearly proportional to the fuel flow rate, which could be interpreted as the CH* chemiluminescence signal is linearly proportional to the heat release rate under fuel lean conditions. The effect of equivalence ratio could be expressed by an exponential function as ${I_{CH*}}^{\propto}\;a_1\;{\exp}(b_1{\Phi})$, where $a_1\;=\;0.00054$ and $b_1\;=\;4.60$ for methane and $a_1\;=\;0.0056$ and $b_1\;=\;5.02$ for propane. Oscillating flames showed the temporal fluctuation of chemiluminescence intensity: however, the time averaged values are virtually identical to those of quiescent flames under the same fuel flow rate and equivalence ratio conditions. This observation suggests that there is no significant flame stretch effect on chemiluminescence intensity, in average values.

• 한국연소학회지
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• 제10권2호
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• pp.35-41
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• 2005

Behaviors of lean premixed flame of propane/air and methane/air flame anchored by a pilot flame in a tube were investigated experimentally varying the mean velocity from 10 to 140 cm/s and the equivalence ratio from 0.45 to 0.8. Behaviors of both flames are divided into five regions of stable, flash-back, tail-out, flickering and vibrating. General characteristics of each region and Le number effect are investigated. Two main instabilities, flickering and vibration, are both unstable but the instability mechanism, the frequency and the amplitude of pressure fluctuation are different. In the edge of the vibrating region, pressure fluctuation repeats generation and extinction. Repeated growth and decrease of the amplitude of pressure fluctuation are explained by Rayleigh#s index.

• 한국연소학회지
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• 제13권1호
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• pp.10-16
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• 2008

Numerical simulations of freely propagating premixed flames burning mixtures of methane and chlorinated hydrocarbons in fuel are performed at atmospheric pressure in order to understand the effect of chlorinated hydrocarbons on the formation of nitrogen oxide. A detailed chemical reaction mechanism is used, the adopted scheme involving 89 gas-phase species and 1017 elementary forward reaction steps. Chlorine atoms available from chlorinated hydrocarbons inhibit the formation of nitrogen oxides by lowering the concentration of radical species. The reduction of NO emission index calculated with thermal or prompt NO mechanism is not linear and is probably related to the saturation effect as $CH_3Cl$ addition is increased, In the formation or consumption of nitrogen oxide, the $NO_2$ and NOCl reactions play an important role in lean flames while the HNO reactions do in rich flames. The molar ratio of Cl to H in fuel has an effect on the magnitude of NO emission index.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.335-338
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• 2001

With the use of the electron microscopy and X-ray phase analysis the regularities of carbon deposit formation in process of methane and propane pyrolysis on the zeolites, Kazakhstan natural clays, chrome and bauxite sludge containing metal oxides of iron subgroup, have been studied. In process of over-carbonization the trivalent iron was reduced to metal form. In addition, the carbon tubes of divers morphology had been impregnated with ultra-dispersed metal particles. The kinetic parameters of carbon formation in process of methane decomposition on the zeolite CoO mixture surface were investigated by method of thermo-gravimetric analysis. The morphology and structure of formed carbon fibrils, with the metal particles fixed at their ends, have been investigated, the formation of branched carbon fibrils pattern, so called octopus, being found.

• 대한기계학회논문집B
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• 제31권5호
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• pp.491-498
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• 2007

Flame characteristics of a methane-air premixed flame stabilized in a heat-regenerative small combustor were investigated experimentally. A small combustor having two counter-current shallow channels and a combustion space at one side was developed. In which the channel-gap was less the ordinary quenching distance of a stoichiometric methane-air premixed flame. Two design parameters of channel gap and thickness of the middle wall, which is located between two channels for unburned and burned gases, were varied. Flame stabilization conditions and characteristic flame behaviors were experimentally examined. Conclusively, Blowout conditions were governed mostly by the scale of the combustion space, and flashback conditions into the channel are dominated by the channel gap. Surface temperatures of the combustor were between 100 to 500$^{\circ}C$. Additionally, two distinctive flame stabilization modes of radiation and well-stirred?reaction were observed and their applicability was discussed.

• Transactions on Electrical and Electronic Materials
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• 제2권2호
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• pp.5-15
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• 2001

The experiment established optimal conditions for over-carbonization. With the use of the electron microscopy and X-ray phase analysis the regularities of carbon deposit formation in process of methane and propane pyrolysis on the zeolites, Kazakhstan natural clays, chrome and bauxite sludge containing metal oxides of iron subgroup, have been studied. In process of over-carbonization the trivalent iron was reduced to metal form. In addition, the carbon tubes of divers morphology had been impregnated with ultra-dispersed metal particles. The kinetic parameters of carbon formation in process of methane decomposition on the zeolite - CoO mixture surface were investigated by method of thermo-gravimetric analysis. The morphology and structure of formed carbon fibrils, with the metal particles fixed at their ends, have been investigated, the formation of branched carbon fibrils pattern, so called octopus, being found. Also, the walnut shells and grape kernel carbonization, their immobilization by the cells of selective absorption of heavy metal and sulfur dioxide ions have been studied. The example of metal-carbon composites used as adsorbents for wastewater purification, C$_3$- C$_4$ hydrocarbon cracking catalysts and refractory materials with improved properties have been considered.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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• pp.1-14
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• 2004

Experiments were performed in order to examine the stability of hydrocarbon-fueled flames in cavity flameholders in supersonic airflows. Methane and ethylene were burned in two different cavity configurations having aft walls ramped at 22.5 and 90$^{\circ}$. Air stagnation temperatures were 590 K at Mach 2 and 640 K at Mach 3. Lean blowout limits showed dependence on the air mass flowrates. Visual observations, planar laser induced fluorescence (PLIF) of nitric oxide (NO), and Schlieren imaging were used to investigate these phenomena. Large differences were noted between cavity floor and cavity ramp injection schemes. Cavity ramp injection provided better performance in most cases. Ethylene pilots have a wider range of stable operation than methane. Fuel flowrates at ignition showed similar trends as lean blowout limits, but higher flowrates were required.

• 한국추진공학회지
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• 제21권1호
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• pp.63-71
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• 2017

메탄($CH_4$)/산소($O_2$) 액체이원추진제는 친환경성, 무독성, 경제성, 우수한 성능 등의 장점으로 최근 들어 차세대 친환경 이원추진제로서 관심을 받고 있다. 본 연구에서는 연소실 내 압력 변화에 따른 기체 메탄/산소 비예혼합 동축 화염의 연소안정한계를 측정하고, 화염 및 유동의 가시화를 통해 분사 조건 및 압력 변화에 따른 화염의 구조와 특성을 파악하였다. 연구 결과 연료과농 조건에서 연소실 내 압력이 증가할 경우 연소안정한계가 확장되고 반응 영역이 증가하는 것을 확인할 수 있었다.

• 한국환경과학회지
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• 제27권5호
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• pp.309-317
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• 2018

In this study, a laser sheet technique and PLIF (Planar laser-induced fluorescence) are applied to a laboratory-scale pulverized coal burner of the open type, and the spatial relationship of the pulverized coal particle zone and the combustion reaction zone is examined by simultaneous measurement of Mie scattering and OH-LIF images. It is found that this technique can be used to investigate the spatial relationship of the combustion reaction zone and pulverized-coal particles in turbulent pulverized-coal flames without disturbing the combustion reaction field. In the upstream region, the combustion reaction occurs only in the periphery of the clusters where high-temperature burned gas of the methane pilot flame is entrained and oxygen supply is sufficient. In the downstream region, however, combustion reaction can be seen also within clusters of pulverized-coal particles, since the temperature of pulverized-coal particles rises, and the mixing with emitted volatile matter and ambient air is promoted.

• 한국연소학회지
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• 제5권2호
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• pp.9-17
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• 2000

A brief introduction is given on the conditional moment closure model for turbulent nonpremixed combustion. It is based on the transport equations derived through a rigorous mathematical procedure for the conditionally averaged quantities and appropriate modeling forms for conditional scalar dissipation rate, conditional mean velocity and reaction rate. Examples are given for prediction of NO and OR in bluffbody flames, soot distribution in jet flames and autoignition of a methane/ethane jet to predict the ignition delay with respect to initial temperature, pressure and fuel composition. Conditional averaging may also be a powerful modeling concept in other approaches involved in turbulent combustion problems in various different regimes.