• 제목/요약/키워드: Metals pollutants

검색결과 360건 처리시간 0.022초

식수품질 저해요인 중 관리 우선순위 도출에 관한 연구 (Managerial Priority Derivation for Pollutants in Drinking Water)

  • 오희균;이희찬
    • 한국물환경학회지
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    • 제32권1호
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    • pp.80-88
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    • 2016
  • The main purpose of this study was to derive managerial priority for pollutants in drinking water using the Delphi technique and analytic hierarchy process (AHP) method. We collected fundamental existing items based on a literature review for water pollutants, and deduced a total of 36 sub-items from nine core sectors, as follows: organic matter; inorganic substances; pathogenic organisms; chemicals; heavy metals; radioactive substances; sediment deposits; heat; and oil, and then conducted the first round of an expert study to ensure that objective indicators properly evaluate major issues for management of for drinking water quality. In the following round, the necessity and importance assessments of adjusted items were implemented using a content validity ratio index. Finally, items modified by Delphi surveys were applied to AHP. We computed weighted values by pair-wise comparison of sub-items and each of five sectors modified by the second round. According to the results of AHP, the managerial priority for pollutants in drinking water was as follows; while heavy metal placed first in importance, pathogenic organisms came second, followed by inorganic substances, organic matter and chemical substances from the sector perspective.

자주달개비 생물검정 기법을 이용한 환경오염 평가 (Assessment of Environmental Pollution with Tradescantia Bioassays)

  • 김진규;신해식
    • 한국환경생물학회:학술대회논문집
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    • 한국환경생물학회 2004년도 학술대회
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    • pp.1-15
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    • 2004
  • Higher plants can be valuable genetic assay systems for monitoring environmental pollutants and evaluating their biological toxicity. Two assays are considered ideal for in situ monitoring and testing of soil, airborne and aqueous mutagenic agents; the Tradescantia stamen hair assay for somatic cell mutations and the Tradescantia micronucleus assay for chromosome aberrations. Both assays can be used for in vivo and in vitro testing of mutagens. Since higher plant systems are now recognized as excellent indicators and have unique advantages over in situ monitoring and screening, higher plant systems could be accepted by regulatory authorities as an alternative first-tier assay system for the detection of possible genetic damages resulting from the pollutants or chemicals used and produced by industrial sectors. It has been concluded that potential mutagen and carcinogen such as the heavy metals among indoor air particulates, volatile compounds in the working places, soil, and water pollutants contribute to the overall health risk. This contribution can be considerable under certain circumstances. It is therefore important to identify the level of genotoxic activity in the environment and to relate it to the biomarkers of a health risk in humans. The results from the higher plant bioassays could make a significant contribution to assessing the risks of pollutants and protecting the public firom agents that can cause mutation anuor cancer. The plant bioassays, which are relatively inexpensive and easy to handle, are recommended for the scientists who are interested in monitoring pollutants and evaluating their environmental toxicity to living organisms.

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제일인산칼륨과 벤토나이트 처리를 통한 토양 내 TNT와 중금속 이동성 및 인체위해도 저감 기술 (Risk Evaluation of Monopotassium Phosphate (MKP) and Bentonite Application via the Mobility Reduction of Soil TNT and Heavy Metals)

  • 정재웅;유기현;남경필
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권6호
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    • pp.28-36
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    • 2015
  • Simultaneous mobility reduction of explosives and heavy metals in an operational range by monopotassium phosphate (MKP) and bentonite spreading technology was investigated. Potassium ion and phosphate ion in MKP act as explosives sorption enhancer and insoluble heavy metal phosphate formation, respectively, while bentonite acts as the explosives adsorbent. Then, the decrease in surface water concentration of the pollutants and resulting risk reduction for local residents of the operational range, by MKP/bentonite application was estimated. Under untreated scenario, the noncancer hazard index (HI) exceeded unity on February, July and August, mainly due to 2,4,6-trinitrotoluene (TNT); however, MKP/bentonite treatment was expected to lower the noncancer hazard index by decreasing the surface water concentration of explosives and heavy metals (especially TNT). For example, on July, estimated surface water concentration and HI of TNT were 0.01 mg/L and 1.1, respectively, meanwhile the sorption coefficient of TNT was 3.9 mg1−nkg−1Ln. However, by MKP/bentonite treatment, the TNT sorption coefficient increased to 113.8 mg1−nkg−1Ln and the surface water concentration and HI decreased to about 0.002 mg/L and 0.2, respectively. Based on the result, it can be concluded that MKP/bentonite spreading is a benign technology that can mitigate the risk posed by the pollutants migration from operational ranges.

황복(Takifugu obscurus)에 대한 중금속, 유기주석화합물 및 다환방향족탄화수소(PAHs)의 급성 독성 (Acute Toxicity of Dissolved Inorganic Metals, Organotins and Polycyclic Aromatic Hydrocarbons to Puffer Fish, Takifugu obscurus)

  • 이정석;이규태;김동훈;김진형;한경남
    • Environmental Analysis Health and Toxicology
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    • 제19권2호
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    • pp.141-151
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    • 2004
  • We exposed juvenile puffer fish, Takifugu obscurus(30 days after hatching) to various aqueous pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), 2 organotin compound.; (tributyltin [TBT] and triphenyltin[TPhT]) and 5 polycyclic aromatic hydrocarbon (PAH) compounds (chrysene, fluoranthene, naphthalene, phenanthrene and pyrene) to estimate median lethal concentrations (LC50s) of each pollutant after the 96-hour acute exposure. Among the inorganic metals, Hg (52 $\mu\textrm{g}$/L; 96-h LC50) was most toxic to test animals and followed by Ag (164 $\mu\textrm{g}$/L), Cu (440 $\mu\textrm{g}$/L) and Cd (1180 $\mu\textrm{g}$/L). Aqueous TBT was more toxic between the two organotins; the 96-h LC50 for TBT (5.1 $\mu\textrm{g}$/L) was 3 times lower than that of TPhT (17.3 $\mu\textrm{g}$/L). The acute toxicity of PAH compounds was highest for chrysene (1.5 $\mu\textrm{g}$/L; 96-h LC50) and decreased in the order of pyrene (65 $\mu\textrm{g}$/L) > fluoranthene (158 $\mu\textrm{g}$/L) > phenanthrene (432 $\mu\textrm{g}$/L) > naphthalene (8690 $\mu\textrm{g}$/L). The toxicity of PAH compounds wat closely related to their physico-chemical characteristics such as $K_{ow}$ and water solubility, and well explained by simple QSAR relationship. The sensitivity of puffer fish to various inorganic and organic pollutants was generally comparable to various fish species widely used as standard test species in previous studies and further evaluation should be conducted to develop adequate testing procedure for T. obscurus when used in various toxicity tests.

교통량 과밀 도로주변의 토양과 가로수, 대기중 Pb, Cu, Zn 중금속 농도와 그 상관성에 관한 연구 (Pb, Cu, Zn Contaminants and Their Correlation of Soil, Leave and Bark of Ginkgo. B and Ambient Air Adjacent to a Heavy Traffic Road Side)

  • 박기학
    • 한국환경보건학회지
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    • 제18권2호
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    • pp.19-25
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    • 1992
  • The study was carried out to investigate the correlation between the heavy metals emitted by the motor vehicles with the heavy traffic road side environment (soil, leave, bark, ambient air). The Pb, Cu, Zn contents in road side soil sand leaves, barks from Ginkgo, biloba and ambient air adjacent to the heavy traffic road side from June to August, 1992 Suwon city were analyzed by Atomic absorption spectrometry and Inductively coupled plasma emission spectrophotometry. The results were as follows: 1) The high levels of heavy metals concentration were Pb, at city-terminal in soil (186 $\mu$g/g), Cu, at city-terminal in soil (221 $\mu$g/g), Zn, at city-terminal in ambient air (252 $\mu$g/m$^{3}$). 2) The low leves of heavy metals concentration were Pb, at North-gate in ambient air (1.65$\mu$g/m$^{3}$), Cu, at North-gate in ambient air (4 $\mu$g/m$^{3}$), Zn, at North-gate in ambient air (15.31$\mu$g/m$^{3}$). 3) The regional distribution of Pb, Cu, Zn in road side soils, leaves and barks from Ginkgo, biloba, ambient air show high levels in turn, city4erminal, Guan Sean Dong, South gate, North gate. 4) The concentration of heavy metals (Pb, Cu, Zn) in soils, leaves, barks, ambient air was highly correlated with the traffic volume of the sampling sites (r=0.64~0.96). To conclude that the high levels of Pb, Cu, Zn contaminations were positively related to motor vehicles-borne pollutants and road side soils, trees, ambient air adjacent to a high density building area with low road coverage and heavy traffic volume were reflected strongly by the hazardous pollutants emitted by motor vehicles.

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폐금속광산 하부 농경지 토양의 중금속오염과 그 복구방법으로서 반전객토의 효율성 (Pollution of Heavy Metals in Paddy Soils Around the Downstream Area of Abandoned Metal Mine and Efficiency of Reversed Soil Method as Its Remediation)

  • 나춘기;이무성;정재일
    • 자원환경지질
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    • 제30권2호
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    • pp.123-135
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    • 1997
  • In order to investigate the dispersion patterns and contamination level of heavy metals in the soil-ecosystem and to evaluate the efficiency of soil remediation by reversed soil method, soils and plants were collected from the Dongjin Au-Ag-Cu mine area and analysed for heavy metals. The dispersion patterns of heavy metals in soils and plants show that heavy metal pollutions caused by waste rump around Dongjin mine are mainly found in the vicinity of the waste rump and in the southward slanting of mine. Toxic metallic pollutants from the mine influence heavy metal contents in paddy soils in downstream area, and may be a potential sources of heavy metal pollution on crop plants. Soil samples collected from the remediated rice farming field by reversed method show similar levels of heavy metal content to those from the polluted rice farming field, but topsoil enrichment of heavy metals are not found. Heavy metal contents of the rice plants collected from remediated rice farming field are significantly lower than those from polluted rice farming field, and it suggests that the reversed soil method is effective for the reduction of bioavailability of heavy metals.

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도상자갈 표면 유류 오염물질의 물리적 제거방안 연구 (Physical remediation of ballast gravels contaminated by oil pollutants)

  • 조영민;이재영;정우성;박덕신;강해숙;김희만;임종일
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2007년도 추계학술대회 논문집
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    • pp.1386-1391
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    • 2007
  • The ballast gravels are often contaminated by various pollutants, like diesel fuel, lubricants, and heavy metals. Especially, the gravels near the switching are apt to be polluted by the lubricant. Because this lubricant can pollute the soil of track, the contaminated ballast gravels should be cleaned immediately. In this study, a physical desorption method was used to remove the oil contaminants from the surface of the ballast gravels. Thermosetting resin was used as a media for physical remediation of ballast gravels. The total petroleum hydrocarbon of the gravels was monitored over time. In addition, scanning electron microscopic images were obtained to observe the removal of the oily pollutants from the surface of the gravels.

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환경유래 식품오염물질의 우선순위 선정 기법 (Food-CRS-Korea)의 개발과 적용 (Development of Korean Food-Chemical Ranking and Scoring System (Food-CRS-Korea) and Its Application to Prioritizing Food Toxic Chemicals Associated with Environmental Pollutants)

  • 양지연;장지영;김수환;김윤관;이효민;신동천;임영욱
    • Environmental Analysis Health and Toxicology
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    • 제25권1호
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    • pp.41-55
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    • 2010
  • The aims of this study were to develop the suitable "system software" in chemical ranking and scoring (CRS) for the food hazardous chemicals associated with environmental emission and to suggest the priority lists of food contamination by environmental-origined pollutants. Study materials were selected with reference to the priority pollutants list for environment and food management from domestic and foreign research and the number of study materials is 103 pollutants (18 heavy metals, 10 PBTs, 10 EDs, and 65 organic compounds). The Food-CRS-Korea system consisted of the environmental fate model via multimedia, transfer environment to food model, and health risk assessment by contaminated food intake. We have established that health risks of excess cancer risks, hazard quotients (HQs) by chronic toxicity and HQs by reproductive toxicity convert to score, respectively. The creditable scoring system was designed to consider uncertainty of quantitative risk assessment based on VOI (Value-Of-Information). The predictability of the Food-CRS-Korea model was evaluated by comparing the presumable values and the measured ones of the environmental media and foodstuffs. The priority lists based on emissions with background-level-correction are 15 pollutants such as arsenic, cadmium, and etc. The priority lists based on environmental monitoring date are 17 pollutants including DEHP, TCDD, and so on. Consequently, we suggested the priority lists of 13 pollutants by considering the several emission and exposure scenarios. According to the Food-CRS-Korea system, arsenics, cadmium, chromes, DEHP, leads, and nickels have high health risk rates and reliable grades.

전기비저항과 투수계수 측정을 통한 celite가 가미된 필터의 투과 성능 모니터링 (Monitoring the performance of a celite-based filter by using electrical resistivity and permeability measurements)

  • 김규원;권태혁;조계춘
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 춘계 학술발표회
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    • pp.673-676
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    • 2009
  • Non-point pollutants, which mainly originate from high traffic roads and rural areas, contaminate the environment by flowing into various rivers and lakes and thus are of interest as an environmental issue. Accordingly, efforts have been made to design and maintain efficient filter systems for the control of the non-point pollutants. Meanwhile, clay-type materials are widely used for the absorption of chemicals included in pollutants and the absorption performances of various clays have been reported in the literature. Thus, the present study proposes a non-destructive monitoring method for the performance of a clay-type filter using electrical resistivity measurement. A series of experimental tests is performed on celite-based particulate filters with infiltrating non-point source pollutants having the same characteristics as pollutants on high traffic roads. Each test measures permeability, resistivity of the filter materials and resistivity of the filtrated water. As the particulate filter materials filtrate pollutants and absorb heavy chemicals (e.g., $Cr^{6+}$, lead, nickel, among others), ionic concentration increases resulting as the electrical resistivity decrease. When the filter systems approach the end of their lifetime, the electrical resistivity of the filter material converges to a very low value due to lowered filter absorption efficiency. Hence, the electrical resistivity of the filtrated water also converges to a low value due to high concentrations of heavy metals. The permeability converges to a very low value because of significantly reduced porosity due to clogging and absorption of pollutants on the filter material. The experimental results show that electrical resistivity monitoring of filter materials is a promising approach to estimation of filter performance and its life expectancy.

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