• Journal of the Korean Chemical Society
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• v.67 no.4
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• pp.222-225
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• 2023

Metallic salts of C10-18 aliphatic carboxylic acids were prepared and their scanning electron microscopic images were analyzed for the morphology dependency with the metal and the carboxylic acid. Regardless of metal ion, metal salts of dicarboxylic acids showed a high crystallinity with a fiber image (SuA-Na). The aromatic dicarboxylates also represented a morphology of a rectangular-rod or board shapes (IA-Li, IA-Ba). With Na ion, most aliphatic carboxylate (MA, PA, SA) showed a fiber-like crystallinity. However, other monovalent Li, K and multivalent Mg, especially Al ion resulted a glassy-amorphous in the metallic salts of acids (MA, PA, SA). With divalent Ba and Ca ions, the metal salt of aliphatic acids expressed a branched round cluster shape as in SA-Ca, SA-Ba. Both Li and Mg ions with a similar size showed a strong morphological similarity in the metallic salts of aliphatic acids MA, PA, SA. In the case of Na and Ca ions with a similar size (98, 106 pm), both ionic salts of stearic acid gave a branching effect for a fiber or round granular image. In the case of hydroxyl-aliphatic acids (HLA, HPA, HSA), the fiber images in HLA-Na and HSA-Na was appeared about 100 nm thicker than those of nonhydroxycarboxylates (LA-Na, SA-Na). The metallic salts of unsaturated C-18 carboxylic acids (OlA, LeA and LnA) showed an amorphous glassy image due to a kinked carbon chain.

• Journal of the Korean Chemical Society
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• v.15 no.6
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• pp.330-347
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• 1971

Catalytic effects of metallic salts on the combustion of diesel fuel oil have been studied. In the case of organometallic salt, the active species are the metallic oxides resulted from combustion of the salts. The oxides act only on the residual solid carbon produced from the fuel oil combustion. The catalytic activity can be explained with the semiconductor theory just as in the case of the gas phase reaction. The chemical rate constant of the combustion of carbon, the soot from diesel fuel oil, is found to be $k_c=1.1{\times}10^4\;exp$ (-16,600/T) below $800^{\circ}K$. By addition of metallic oxides, the rate constant increases remarkably. This work has substantiated the belief that the effect of the metallic salts on the fuel oil combustion can conveniently be studied by checking directly the effect of the corresponding metallic oxide on the soot carbon.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.3
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• pp.73-80
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• 2014

In this study, in order to investigate the influence of insolubilizer on the double coating structure, we carried out basic research related to the double coating formulation with four insolubilizers having various chemical types such as amino aldehyde, glyoxal and two metallic salts. It was found that although the four insolubilizers showed similar results on optical and surface properties of the coated papers, they gave different results in the printabilities of the coated papers since coating structure was significantly influenced by different reacting mechanism of the insolubilizers. Three of the insolubilizers (glyoxal, two metallic salts) showed better results than amino aldehyde type one when they were applied to top coating formulation. Metallic salts type insolubilizers showed good results in the print gloss when it was applied to top coating formulation. It was believed that amino aldehyde type insolubilizer applied top coating formulation showed good both of dry-pick and wet-pick strength.

• Carbon letters
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• v.7 no.1
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• pp.34-41
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• 2006

The objective of this paper is to compare the variation of surface properties by hydrochloric acid pre-treatment and of metallic potassium and their salts loading effect for activated carbon after surfaces transformation by acid. From the results of nitrogen adsorption, each isotherm shows a distinct knee band, which is closely related to the characteristic of microporous carbons with capillary condensation in micropores. In order to present the causes of the differences in surface properties and $S_{BET}$ after the samples were treated with hydrochloric acid, pore structure and surface morphology are investigated by adsorption analysis. X-ray diffraction (XRD) patterns indicate that activated carbons show better performance for metallic potassium and potassium salts by pre-treatment with hydrochloric acid. Scanning electron microscopy (SEM) pictures of potassium/activated carbon particles provide information about the homogeneous distribution of metal or metal complex on the surface. For the chemical composition microanalysis for potassium treatment of the activated carbon pre-treated with hydrochloric acid, samples were analyzed by energy disperse X-ray (EDX). Finally, the type and quality of oxygen groups are determined from the method proposed by Boehm. A positive influence of the acidic groups on the carbon surface by acid treatment is also demonstrated by an increase in the contents of potassium salts with increasing of acidic groups calculated from Boehm titration.

• Clean Technology
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• v.19 no.3
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• pp.249-256
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• 2013

The experiments have been performed to obtain zinc complex compound with smaller particle sizes, which is used as a charge control agent in manufacturing toner. Metallic salts and polyhydric alcohols have been studied to investigate their effects on the formation and the triboelectric charge of zinc complex-compound particle with different sizes. Reactants such as zinc chloride and 3,5-di-tert.-butyl salicylic acid have been used to form the complex compound. Polyethylene glycol (PEG-300), glycerin and ethylene glycol have been added into the zinc chloride solution beforehand to lower the reaction rate in the formation of zinc complex-compound. Aluminium(III) chloride has been mixed in the zinc chloride solution beforehand to restrain the particle size from growing. When PEG-300 and aluminium(III) chloride are used to lower the reaction rate and to restrain the particle size from growing, the average particle size of zinc complex compound decreases from $5.28{\mu}m$ to $2.33{\mu}m$, which was 44.1% of $5.28{\mu}m$.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.8-13
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• 2012

The experiments have been performed to obtain zinc complex compound with smaller particle size, which is used as a charge control agent in manufacturing toner. Metallic salts and polyhydric alcohols have been studied to investigate their effects on the formation of different sizes of zinc complex-compound particle. Reactants such as zinc chloride and 3,5-di-tert-butyl salicylic acid have been used to form the complex compound. Polyethylene glycol (PEG-300), glycerin and ethylene glycol have been added into the zinc chloride solution beforehand to lower the reaction rate in the formation of zinc complex-compound. Zirconium (IV) oxychloride octahydrate has been mixed in the zinc chloride solution beforehand to restrain crystals from growing. When PEG-300 and zirconium (IV) oxychloride octahydrate are used to lower the reaction rate and to restrain the particle size from growing, the average particle size of zinc complex compound decreases from 5.28 to 1.84 ${\mu}m$, which is 34.9% of 5.28 ${\mu}m$.

• Korean Journal of Materials Research
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• v.25 no.12
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• pp.694-702
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• 2015

Nd-Fe-B permanent magnets have been used in a wide variety of applications because of their high magnetic flux density. So, demand for neodymium has been increasing in worldwide. In this study, an electrowinning process was performed in $LiF-NdF_3-Nd_2O_3$ high temperature molten salts. However, a corrosion resistant material for use in the molten salt must be found for stable operation because of the harsh corrosion environment of the electrowinning process. Therefore, for this paper, boron nitride(BN), aluminum nitride(AlN), and silicon nitride($Si_3N_4$) were selected as protective and structural materials in the high temperature electrolyte. To investigate the characteristics of BN, AlN, and $Si_3N_4$, in molten salts, materials were immersed in the molten salts for 24, 72, 120, and 192 hours. Also, surface condition and stability were investigated by SEM and EDS and corrosion products were calculated by HSC chemistry. As a result, among BN, AlN, and $Si_3N_4$, AlN was found to show the best protective material properties.

• Proceedings of the Materials Research Society of Korea Conference
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• 2002.05a
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• pp.20-20
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• 2002

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.2
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• pp.191-198
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• 1995

In order to evaluate the distribution and behaviour of atmospheric particulate metals in high-altitude area, we collected 22 aerosol samples using a high volume air sampler at Soback Mt. Meteorological Observation Station from Jan. to Nov. 1993 and analysed for metals (Al, Fe, Mg, Na, Ca, Mn, Co, Ni, Cu, Zn, Cd, and Pb) with ICP/AES and ICP/MS. Although sampling site is located in high-altitude and far from local sources of atmospheric pollutants, enrichments of metals are 2 times higher than those of western coastal reural area. This fact may imply that of metallic pollutants in the coastal rural site were came from further western side (e.g. China), atmospheric metals in this study area contain the signal of metropolitan cities located in the main wind direction (NNW). Sea salts are negligible in the aerosol particle population because reference elements of sea salts (Na, Mg) are all originated from soil particles. The contents of soil particles in aerosols are highest in spring and lowest in winter. Atmospheric enriched elements (Ni, Cu, Zn, Cd and Pb) are diluted with soil particles, especially during the yellow sand period. The results of factor analysis suggest possibility of interpreting their chemical significance in terms of sources (soil, pollutants) and gas-particle conversion processes (formation of ammonium sulfates, ammonium nitrates and/or their mixtures).

• Bulletin of the Korean Chemical Society
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• v.28 no.2
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• pp.241-245
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• 2007

The electronic structures of the new organic conducting salts, the β'- and β''-phases of (BEDT-TTF)2[(IBr2)0.2(BrICl)0.1(ICl2)0.7], were examined by calculating their electronic band structures, Fermi surfaces and HOMO-HOMO interaction energies using the extended Huckel tight binding method. On the basis of these calculations, we probed why the β'-phase is semiconducting while the β ''-phase is metallic.