• 대한전기학회:학술대회논문집
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• 대한전기학회 1993년도 하계학술대회 논문집 B
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• pp.645-647
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• 1993

Surface breakdown characteristics are investigated under metallic-particle contaminated conditions in $SF_6$ gas. The main results show that a rib increases breakdown voltage by a corona stabilization effect and the elongation of discharge path. The breakdown voltage at higher pressures than 4 atm may be estimated on the basis of mean breakdown field strength($E_{BD}$) and discharge length(L) which depend on gas pressure and surface shape.

• 한국환경과학회지
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• 제22권1호
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• pp.7-15
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• 2013

Aerosol characterization study for individual particle in Busan metropolitan industrial complex was carried out from December 2010 to August 2011. SEM(scanning electron microscope)-EDX(energy dispersive x-ray) analysis was used for the analysis of 600 single particles during the sampling periods to identify non-metallic aerosol particle sources. Average $PM_{10}$ concentration was 65.5 ${\mu}g/m^3$ in summer, 104.1 ${\mu}g/m^3$ in winter during the sample periods. And Average $PM_{2.5}$ concentration was 24.5 ${\mu}g/m^3$ in summer, 64.5 ${\mu}g/m^3$ in winter individually. Particle density, enrichment factor, correlation analysis, principle component analysis were performed based on chemical composition data. Particle density distribution was measured to 2~4 $g/cm^3$, and the density of $PM_{2.5}$ was measured above 3 $g/cm^3$. In general, the elements Si, Ca, Fe and Al concentrations were higher in all samples of individual particles. The non-ferrous elements Zn, Br, Pb, Cu concentrations were higher in summer than in winter. The concentrations were not changed with the seasons because of non-ferrous industry emission pattern.

• 천문학회보
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• 제40권1호
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• pp.62.1-62.1
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• 2015

Polarization of the light reflected off the Moon provides information on the size and composition of the particles in the lunar regolith. The mean particle size of the regolith can be estimated from the combination of the albedo and degree of polarization, while the color ratio of the parallel-component polarization (CP) has been suggested to be related to the amount of nanophase metallic iron (npFe^0) inside the regolith particles. Both the mean size and npFe^0 abundance of the particles have been used as maturity indicators of the regolith since sustained impacts of high energy particles and micro-meteoroids cause comminution of particles and production of npFe^0. Based on our multispectral polarimetric observations of the whole near side of the Moon in the U, B, V, R, and I bands, we compare the maps of the mean particle size, CP, and the optical maturity (OM). We find that the mean particle size map is sensitive to the most immature (~0.1 Gyr) soil, the OP map to the intermediate immaturity (a few 0.1 Gyr) soil, and the CP map to the least immature (~1 Gyr) soil.

• 한국재료학회지
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• 제12권10호
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• pp.784-790
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• 2002

For mass product of nanocrystalline ZnO ultrafine powders, self-sustaining combustion process(SCP) and ultrasonic spray combustion method(USCM) were applied at the same time. Ultrasonic spray gun was attached on top of the vertical type furnace. The droplet was sprayed into reaction zone of the furnace to form SCP which produces spherical shape with soft agglomerate crystalline ZnO particles. To characterize formed particles, fuel and oxidizing agent for SCP were used glycine and zinc nitrate or zinc hydroxide. Respectively, with changing combustion temperature and mixture ratio of oxidizing agent and fuel, the best ultrasonic spray conditions were obtained. To observe ultrasonic spray effect, two types of powder synthesis processes were compared. One was directly sprayed into furnace from the precursor solution (Type A), the other directly was heated on the hot plate without using spray gun (Type B). Powder obtained by type A was porous sponge shape with heavy agglomeration, but powder obtained using type B was finer primary particle size, spherical shape with weak agglomeration and bigger value of specific surface area. 9/ This can be due to much lower reaction temperature of type B at ignition time than type A. Synthesized nanocrystalline ZnO powders at the best ultrasonic spray conditions have primary particle size in range 20~30nm and specific surface area is about 20m$^2$/g.

• 한국환경과학회지
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• 제12권6호
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• pp.627-633
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• 2003

2001년 3월부터 2002년 2월까지 부산의 신라대학교 옥상에서 측정한 PM$_{10}$의 질량농도와 화학적 성분을 조사한 결과 다음과 같은 결론을 얻었다. 1) PM$_{10}$의 질량농도는 평균 98.21 $\mu\textrm{g}$/㎥로 나타났으며, 최고농도는 330.56 $\mu\textrm{g}$/㎥로서 연간 기준치인 80 $\mu\textrm{g}$/㎥를 초과하였다. 또한 K(1.23 $\mu\textrm{g}$/㎥)>Ca (1.12 $\mu\textrm{g}$/㎥)>Na(0.79 $\mu\textrm{g}$/㎥))>Al(0.76 $\mu\textrm{g}$/㎥)>Fe (0.75 $\mu\textrm{g}$/㎥) 순으로서 높은 조성을 보였고, Cd (2.72 ng/㎥)이 가장 낮은 질량 농도를 보였다. 2) Cd, Ni, Pb 및 Zn은 평균 지각농축계수가 10이상의 인위적인 기원으로 봄철과 여름철에 비하여 서풍계열의 바람이 우세한 겨울철에 매우 높은 값을 보였으며, 연구 지역의 서쪽에 인접한 사상공단과 서남쪽에 위치한 신평 .장림공단으로부터 서풍계열의 바람을 타고 이동되었음을 알 수 있었다. 또한 이들 중금속은 미세입자의 조성에 많은 영향을 미치는 것으로 나타났으며, 평균 토양입자의 기여율은 9.5%로 나타났다. 3) PM$_{10}$의 조성에 관여하는 금속 원소들은 토양, 해양 및 인위적인 오염물질에 의한 기원을 동시에 포함하고 있으나 해양기원보다는 토양 및 인위적인 기원들 간의 상관성이 우세하게 나타났다.

• 조명전기설비학회논문지
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• 제16권2호
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• pp.59-64
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• 2002

본 논문에서는 전계해석을 통하여 금속성 파티클이 GIS 스페이서의 여러 위치에 부차되었을 경우 립이 파괴전압특성에 미치는 영향을 분석하였다. 또한, 립-스페이서의 여러 위치에 금속성 파티클을 부착하고 립의 모양, 길이, 두께 등의 변화에 따라 얻은 파괴진압특성 실험결과를 전계해석의 결과와 비교·검토하였다. 전계해석의 결과 립의 연면에서의 전계집중이 다른 부분에 비하며 완화되어 절연파괴시 발생된 스트리머의 진전이 억제될 수 있다는 것을 알 수 있었으며, 실험을 통하여 파괴전압이 상승된다는 것을 확인할 수 있었다. 또한 립의 길이와 두께 등에 따라서도 파괴전압 특성이 달라짐을 알 수 있었다. 또한 립의 끝단을 라운드 처리함으로써 파괴전압 특성을 더욱 향상시킬 수 있음을 전계해석과 실험을 통하여 알 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.306.1-306.1
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• 2014

정보화 시대의 발전에 따라 점점 더 많은 정보를 더욱 빠르게 처리할 수 있는 기기들이 요구되고 있다. 메모리는 그 중에서 핵심적인 부품으로써 소자의 고집적화와 고속화가 계속 진행되면서 기존의 메모리 소자들은 집적화에서 그 한계에 도달하고 있다. 기존 소자들의 집적화의 한계를 극복하기 위하여 새로운 비휘발성 메모리 소자들이 제안되었다. 그 중 resistive switching random access memory(ReRAM)은 저항의 변화특성을 사용하는 메모리로 간단한 구조를 가지고 있기 때문에 집적화에 유리하다는 장점을 가지고 있다. 그 외에도 빠른 동작 속도와 낮은 전압에서의 동작이 가능하여 차세대 메모리로써 각광받고 있는 추세이다. 본 연구실에서는 이미 nitride 물질을 기반으로 한 여러 ReRAM 소자들을 제안해 왔다. 그 중 AlN-based ReRAM 소자는 빠른 동작 속도와 좋은 내구성을 보인 바 있다. 하지만 상업화를 위해서 해결해야 할 문제점들이 아직 존재하고 있다. 대표적으로 소자의 배열에서 각 소자의 균일한 동작이 보증되어야 하기 때문에 소자의 셋/리셋 전압의 산포를 줄이고 동작 전류 레벨을 낮추어야 할 필요성이 존재한다. 이러한 ReRAM의 이슈를 해결하기 위해, 본 실험에서는 기존의 AlN-based ReRAM 소자에 Ti를 도핑 방법을 이용하여 소자의 동작 전압 및 전류의 산포를 줄이기 위한 연구를 진행 하였다. 본 실험은 co-sputtering 방법을 이용하여 Ti가 도핑된 AlN을 저항변화 물질로 사용하여 그 특성을 살펴보았다. Ti의 도핑 효과로 소자의 신뢰성 향상 및 동작 전압의 감소 등의 효과를 얻을 수 있었다. 이는 nitride 기반 물질에서 Ti dopant에 의해 형성된 TiN의 효과로 설명된다. TiN는 metallic한 특성을 지니고 있기에 저항변화물질 내에서 일종의 metallic particle의 역할을 수행할 수 있다. 따라서 conducting path의 형성과정에서 이러한 particle 들이 전계를 유도하여 좀 더 균일한 set/reset 특성을 나타내게 된다.

• 대한금속재료학회지
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• 제49권3호
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• pp.221-230
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• 2011

The cold spray process is an emerging technology that utilizes high velocity metallic particles for surface coating. Metallic powder particles are injected into a converging-diverging de Laval nozzle and accelerated to a high velocity by a supersonic gas flow. The cold spray process normally uses a circular nozzle that has a rather narrow spraying range. To overcome this fault, a slit nozzle was considered in this study. The slit nozzle is anticipated to reduce the coating process time because it has a wider coating width than the circular nozzle. However, the slit nozzle can reduce the coating efficiency because it does not allow as much gas and particle velocity as the circular nozzle. To improve the coating efficiency of a slit nozzle, the shape of the slit nozzle was modified. And the results of gas flow and particle behaviour according to the nozzlers shape were compared by the a numerical analysis. As a results, as Expansion Ratio(ER) of 7.5 was found to be the most optimal condition for enhancing the spraying efficiency when the ER was changed by the variation of nozzle neck and exit size.

• 환경위생공학
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• 제18권4호
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• pp.24-35
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• 2003

Recent epidemiologic studies revealed that the concentration of air pollutants and fine particulated matter have some effects on health status and are associated with increased mortality and morbidity. The purpose of this study was to characterize background mass concentration of fine particle (PM2.5) and metallic composition from September 2001 to August 2002 in comparison with a medium city, Asan and metropolitan city, Seoul. Conclusively, proper management for fine particles was required in a medium city, Asan, considering the concentrations of metallic elements in fine particles in Asan were relatively higher than those in Seoul. The results were as followed. 1. Average mass concentrations of fine particles in Asan and Seoul were 37.70(${\pm}18.41{\;}{\mu}g/\textrm{m}^3$) and 5.83(${\pm}38.50$) ${\mu}g/\textrm{m}^3$, respectively. When the weather conditions were classified as normal and yellow-sand, measured average mass concentrations of fine particles in yellow-sand weather condition was significantly higher than those of normal weather condition in both cities (p<0.05). 2. Depending on seasons, measured average mass concentrations of fine particles in Asan and Seoul in spring were 47.76(${\pm}19.07$) ${\mu}g/\textrm{m}^3$m and 61.53 (${\pm}4.37$) ${\mu}g/\textrm{m}^3$, respectively. In summer, the average mass concentrations of fine particles in Asan and Seoul were 29.44(${\pm}9.85$) ${\mu}g/\textrm{m}^3$ and 25.42(${\pm}8.10$) ${\mu}g/\textrm{m}^3$, respectively. Especially, the concentration was the highest in spring and the lowest in summer among four seasons. 3. Average concentrations of manganese(Mn), iron(Fe), chromium(Cr), cadmium(Cd), lead(Pb) and silicon(Si) in fine particles in Asan were significantly higher in Seoul (p<0.05). Average concentration of Si in fine particle in Asan was statistically higher than that of Seoul during yellow -sand condition (p<0.05). 4. Considering the characterization of four seasons, average Pb concentration of fine particle in Asan is significantly higher than that of Seoul in spring(p<0.01). In summer, average Mn and Cr concentrations of fine particle in Asan is higher than those of Seoul (p<0.05). Average Mn, Fe. Cr and Si concentrations in fall (p<0.05), and average Mn, Fe, Cr, Pb, and Si concentrations in winter (p<0.05) in Asan were higher than those of Seoul, respectively. 5. Mass concentrations of each Mn, Fe, Cd and Si in fine particles were significantly correlated with both cities. In normal weather condition, Mn, Cu and Si concentrations are statistically significant in Asan, while Mn, Fe, Cu and Si concentrations are statistically significant in Seoul. Mn, Fe and Si concentrations in both cities were statistically significant during yellow-sand weather.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2002년도 연료전지심포지움 2002논문집
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• pp.211-218
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• 2002

In this study, Pt/Pd (1.1), PtPd (2:1) and PtPd (3:1) binary catalysts and Pt/Ru/Pd (5:4:1) ternary catalyst were designed. The catalysts were synthesized by impregnation method using $NaBH_4$ as a reducing agent. A good catalyst for methanol oxidation requires low on-set potential, stable durability and low activation energy. In order to investigate the catalytic activity for the methanol oxidation, electrochemical measurements such as cyclic voltammetry and chronoamperometry were peformed in sulfuric acid with/without methanol solution. In order to calculate the activation energy of the reaction, electrochemical measurements were also tested at different temperatures. For investigation of the structural analysis such as particle size and alloying, X-ray diffraction and transmission electron microscopy analysis were used. In order to identify the role of the Pd and to determine the composition of the surface of the Pt/Pd nanoparticles, X-ray photoelectron spectroscopy (XPS) analysis was investigated. The XPS spectra of Pd showed that Pd appears only as a metallic state in the binary catalysts. The chemical states of Pt in PtPd catalysts are both metallic and oxidative. Polarization curves and power density data were obtained by testing the DMFC unit cell performance of PtPd and PtRuPd catalysts. These data showed that Pt/Pd (2:1) and Pt/Ru/Pd (5:4:1) have better performance than Pt and Pt/Ru, respectively.