• Title/Summary/Keyword: Metallic fuel

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Fabrication and Characterization of Cr Alloy for Metallic Interconnect of Solid Oxide Fuel Cell (고체 산화물 연료전지용 Cr계 금속 연결재 제조 및 특성 연구)

  • Song, Rak-Hyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.1
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    • pp.58-65
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    • 2005
  • The $LaCrO_3$-dispersed Cr alloys for metallic interconnect of solid oxide fuel cell were prepared as a function of $LaCrO_3$ content in the range of 5 to 25 vol.% and were sintered at 1500$^{\circ}C$ under an Ar atmosphere with 5 vol.% $H_2$. The sintering and oxidation behaviors of these alloys were examined. The alloys indicated a good sinterability above 95% relative density at a given sintering condition, and their sintering densities is independent on $LaCrO_3$ content. The $LaCrO_3$ particles of the sintered alloys were concentrated on interfaces of Cr particles, and the size of the Cr particles increased with decreasing $LaCrO_3$ content, which is caused by inhibited grain growth of Cr particle by $LaCrO_3$ particle. The oxidation test showed all $LaCrO_3$-dispersed Cr alloys have good oxidation resistance as compared with pure Cr, which is attributed to presence of $LaCrO_3$ at the interface at which the oxidation reaction occurs rapidly. The Cr alloys with about 15 vol.% $LaCrO_3$ are very resistant to oxidation.

Ceramic Materials for Interconnects in Solid Oxide Fuel Cells - A Review (고체산화물 연료전지 연결재용 세라믹 소재)

  • Park, Beom-Kyeong;Song, Rak-Hyun;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Park, Chong-Ook;Lee, Jong-Won
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.231-242
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    • 2014
  • An interconnect in solid oxide fuel cells (SOFCs) electrically connects unit cells and separates fuel from oxidant in the adjoining cells. The interconnects can be divided broadly into two categories - ceramic and metallic interconnects. A thin and gastight ceramic layer is deposited onto a porous support, and metallic interconnects are coated with conductive ceramics to improve their surface stability. This paper provides a short review on ceramic materials for SOFC interconnects. After a brief discussion of the key requirements for interconnects, the article describes basic aspects of chromites and titanates with a perovskite structure for ceramic interconnects, followed by the introduction of dual-layer interconnects. Then, the paper presents protective coatings based on spinel-or perovskite-type oxides on metallic interconnects, which are capable of mitigating oxide scale growth and inhibiting Cr evaporation.

Safety Characteristics of Metal-Fueled Sodium-Cooled Fast Reactor (금속연료를 사용하는 소듐냉각 고속로의 안전특성)

  • Jeong, Hae-Yong
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.19-30
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    • 2014
  • The leading countries in nuclear technology development are concentrating their efforts on the development of Sodium-cooled Fast Reactor, which is one of the Generation-IV nuclear reactor systems characterized by a sustainability, an enhanced safety, proliferation resistance, and improved economics. Especially, the Republic of Korea is developing a Sodium-cooled Fast Reactor equipped with metallic-fuel. This type of fast reactor has superior inherent safety and passive safety characteristics. Further, sodium-cooled fast reactors enable the reuse of spent fuel and the closing of fuel cycle, thus, it increases the sustainability of nuclear energy. Many countries are planning the deployment of sodium-cooled fast reactors before 2050 in their energy mix.

Analysis of High Radioactive Materials in Irradiated DUPIC SIMFUEL Using EPMA (EPMA를 이용한 DUPIC 사용후 핵연료 핵분열 생성물의 특성 분석)

  • 정양홍;유병옥;주용선;이종원;정인하;김명한
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.2
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    • pp.125-133
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    • 2004
  • Fission products of DUPIC (Direct Use of Spent PWR Fuel in CANDU Reactors) fuel, irradiated in HANARO research reactor with 61 ㎾/m of maximum linear power and 1,770 ㎿d/tU of average burn-up, was characterized by EPMA(Electron Probe Micro Analyzer). In order to find accurate characterization, the analysis results by EPMA of fresh simulated DUPIC fuel containing fission products as chemicals were compared with that of wet chemical analysis. The metallic precipitates observed at the center of the fresh simulated DUPIC fuel were about 1 $\mu\textrm{m}$ in size and their major components by EPMA were Mo-53.89 at.%, Ru-37.40 at.%, and Pd+Rh-8.71 at.%. Established procedure through the fresh simulated DUPIC fuel was applied to the irradiated DUPIC fuel. Observed size of metallic precipitates were 2∼2.5 $\mu\textrm{m}$ and their compositions were Mo-47.34 at.%, Ru-46 at.%, and Pd+Rh-6.65 at.%. What are uncommon things for this experiment, special treatment for improving the conductivity was attempted to the specimen and the conditions of exact irradiation of electron beam to small metallic precipitate were suggested.

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