• 제목/요약/키워드: Metallic Waste

검색결과 115건 처리시간 0.026초

Fabrication of nickel nanoparticles-embedded carbon particles by solution plasma in waste vegetable oil

  • Pansuwan, Gun;Phuksawattanachai, Surayouth;Kerdthip, Kraiphum;Sungworawongpana, Nathas;Nounjeen, Sarun;Anantachaisilp, Suranan;Kang, Jun;Panomsuwan, Gasidit;Ueno, Tomonaga;Saito, Nagahiro;Pootawang, Panuphong
    • Journal of Advanced Marine Engineering and Technology
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    • 제40권10호
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    • pp.894-898
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    • 2016
  • Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

De-link R를 이용한 폐고무 재활용(I) (Recycling of Waste Rubber by De-link System (I))

  • 황성혁;홍존희;유태욱;김진국
    • Elastomers and Composites
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    • 제36권2호
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    • pp.79-85
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    • 2001
  • 폐고무의 증가로 인하여 환경문제가 날로 심각해지고 있다. 그러므로 효율적인 재활용을 통하여 이러한 문제를 해결하는데 많은 연구가 진행되고 있다. 본 연구에서는 탈황시스템을 이용하여 폐고무 분말의 가황 결합을 분리함으로서 기본물성을 높이는데 목적을 두었다. 폐고무분말의 입자크기에 따른 물성의 변화와 De-link 함량 증가에 따른 물성을 조사하였고 De-link를 함유한 시료를 기존 배합물에 10phr 충전하여 유변학적, 기계적 및 가교도 등의 물성을 조사하였다. 또한 광학현미경을 사용하여 표면을 확인함으로서 제품특성을 연구하였다.

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U-2wt%Nb, Ti, Ni 합금의 공기중 산화거동 (Oxidation Behavior of U-2wt%Nb, Ti, and Ni Alloys in Air)

  • 주준식;유길성;조일제;국동학;서항석;이은표;방경식;김호동
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.395-400
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    • 2003
  • 사용후핵연료 금속전환체의 장기저장 안정성 확보를 위해 금속전환체의 주성분인 금속우라늄과 산화 안정화 후보물질인 Nb, Ti, Ni, Zr, Hf 등을 첨가한 모의금속전환체 합금을 제작하여 $200^{\circ}C~300^{\circ}C$ 온도구간에서 순수 산소분위기로 산화시험을 수행하였다. U-Nb, U-Zr, U-Ti 합금은 순수 금속우라늄보다 무게증가 측면에서의 산화저항성이 높았으나, U-Hf, U-Ni 합금의 경우에는 오히려 순수 금속우라늄보다 산화 저항성이 낮게 나타났다. 시편에 대한 미세성분 및 조직을 광학현미경, SEM, EPMA 등을 통해 분석하였다. 각 합금의 산화율 및 활성화에너지를 구한 결과 U-Nb 합금의 활성화에너지가 높고 산화 저항성이 가장 양호한 것으로 나타나 산화 저항성 후보물질로 선정하였다.

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Electrochemical Decontamination of Metallic Wastes Contaminated with Uranium Compounds in a Neutral Salt Electrolyte

  • Park, W. K.;Y. M. Yang;C. H. Jung;H. J. Won;W. Z. Oh;Park, J. H.
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.689-695
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    • 2003
  • Electrochemical decontamination process has been applied for recycle or self disposal with authorization of large amount of metallic wastes contaminated with uranium compounds such as $UO_2$, ammonium uranyl carbonate (AUC), ammonium di-uranate (ADU), and uranyl nitrate(UN) with tributylphosphate(TBP) and dodecane, which are generated by dismantling the contaminated system components and equipment of a retired uranium conversion plant in Korea Atomic Energy Research Institute (KAERI). Electrochemical decontamination for metallic wastes contaminated with uranium compounds was evaluated through the experiments on the electrolytic dissolution of stainless steel as the material of the system components in neutral salt electrolytes. The effects of type of neutral salt as the electrolyte, current density, and concentration of electrolyte on the dissolution of the materials were evaluated. Decontamination performance tests using the specimens taken from a uranium conversion plant were quite successful with the application electrochemical decontamination conditions obtained through the basic studies on the electrolytic dissolution of structural material of the system components.

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Development of Decontamination Methods using Liquid/Supercritical $CO_2$

  • Park, Kwangheon;Moonsung Koh;Chunghyun Yoon;Kim, Hongdoo;Kim, Hakwon
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 Proceedings of the 4th Korea-China Joint Workshop on Nuclear Waste Management
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    • pp.106-113
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    • 2004
  • A major problem of nuclear energy is the production of radioactive wastes. Needs for more environmentally favorable method to decontaminate radioactive contaminants make the use of liquid/Supercritical $CO_2$ as a solvent medium. In removing radioactive metallic contaminants under $CO_2$ solvent, two methods - use of chelating ligands and that of water in $CO_2$ emulsion - are possible. In the chelating ligand method, a combination of ligands that can make synergistic effects seems important. We discuss about the properties of microemulsion formed by F-AOT. By adding acid in water core, decontamination of metallic parts, soils were possible.

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