• Title/Summary/Keyword: Metallic Ions

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The PM2.5 Concentration and Components Characteristics in Miryang (밀양지역의 PM2.5 농도 및 성분특성)

  • Suh, Jeong-Min;Kim, Young-Sik;Jeon, Bo-Kyung;Choi, Kum-Chan;Ryu, Jae-Yong;Park, Jeong-Ho
    • Journal of Environmental Science International
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    • v.16 no.12
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    • pp.1355-1367
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    • 2007
  • This study summarizes the relations among $PM_{2.5}$ concentration, water-soluble ions concentration, metallic element Components characteristics and SPSS in negative ion and metallic element of $PM_{2.5}$ particle in Miryang.(By the urban area, the industrial complex area and the suburban area according to the season) $PM_{2.5}$ concentration of total 72 samples collected from 3 sites turned out to range from 3.47 to 34.7 ${\mu}g/m^3$, and the average concentration was the suburban area-the kin nup(16.00 ${\mu}g/m^3$) > the urban area-the roof of the old Miryang university(10.32 ${\mu}g/m^3$) > the industrial complex-Sapo industrial complex(10.29 ${\mu}g/m^3$). In particular, the suburban area had $PM_{2.5}$ concentration 1.5 times those of urban area, industrial complex. It was thought although the site was suburban and farm-side without pollutants around, it had a higher concentration value influenced by external factors including the brickyard, small-scale incinerator, driving range construction, construction on the Daegu-Busan express and the widening of the four-lane road between Miryang-Anyang nearby. As for water-soluble ions among $PM_{2.5}$ particle collected in Miryang area, $SO4_{2^-}$ accounted for 60% and $NO_{3^-}$, was 30% in spring and summer. And $NO_{3^-}$ accounted for 50% and $SO4_{2^-}$ was 35% in fall and winter. The AI value of metallic Components among $PM_{2.5}$ particle collected in Miryang area had a high value influenced by the apartment complex construction and the extension work of road. The industrial complex area had Zn concentration 3 times, and Fe concentration 2 times those of urban area and suburb area. When it comes to the relation with metallic elements in urban area, the highest coefficient of correlation was between Cr-Fe with 0.85, and Pb-Cd turned out in the reverse correlation. Among metallic elements, the coefficients of correlation between Zn and Cr, Mn, Fe, NI were high in industrial complex area. The highest coefficient of correlation was between Mn-Zn with 0.88, meanwhile Ni and Cu, Cd turned out in the reverse correlation in the suburb area. These coefficients of correlation are attributed to the difference in pollutant sources, rather than difference in pollutant and non-pollutant.

Effects of Ion Nuclei in the Metallic Nanoparticle Generation Using a Supersonic Nozzle (초음속 노즐을 이용한 금속 나노 입자의 생성에서 이온 핵의 영향)

  • Jung, Jae-Hee;Kim, Sang-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.12 s.243
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    • pp.1329-1334
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    • 2005
  • Synthesis of silver nanoparticles by the supersonic nozzle expansion method with corona discharge ions was investigated. Corona discharge ions functioned as seeds for heterogeneous nucleation in the silver nanoparticles formation process and provided silver nanoparticles with electronic repulsive force that prevents aggregation of the particles. For ion ejecting, we used sonic-jet corona discharger. Upon application of the corona discharge ions, the mean diameter of the produced particles was decreased from 12.54 to 6.22nm and the standard deviation was decreased from 5.02 to 3.34nm. In addition, the agglomeration of silver nanoparticles was reduced.

Adsorption of U(VI), Mn(II), Gd(III) lons on the Styrene - DVB Resin (스틸렌-DVB 수지 에 의한 U(VI), Mn(II), Gd(III) 이온들의 흡착)

  • 강영식;김준태
    • Journal of environmental and Sanitary engineering
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    • v.17 no.3
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    • pp.31-36
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    • 2002
  • The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metal ions by resin(cryptand resin) adsorbent were investigated. The metal ions were showed fast adsorption on the resins in over pH 3. The equilibrium time for adsorption of metallic ions was about two hours and the adsorption selectivity determined in methanol was in increasing order $UO^{2+}$ > $Mn^{2+}$ > $Gd^{3+}$ ion. The adsorption was in the order of 1%, 2% and 5% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

Enhanced Blue Emission in Er3+/Yb33+ Doped Glass-ceramics Containing Ag Nanoparticles and ZnO Nanocrystals

  • Bae, Chang-hyuck;Lim, Ki-Soo
    • Current Optics and Photonics
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    • v.3 no.2
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    • pp.135-142
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    • 2019
  • We report the precipitation of ZnO nanocrystals, Ag-clusters, and Ag nanoparticles in Ag/Er/Yb doped borate glasses by furnace annealing and $CO_2$ laser annealing. The XRD analysis revealed the precipitation of ZnO and Ag phases. The absorption spectra, the TEM and energy dispersive spectroscopy (EDS) revealed the incorporation of Er and Yb ions into ZnO nanocrystals formed by a laser technique and showed the surface plasmon band of Ag nanoparticles. The down-converted blue emission intensity of $Er^{3+}$ ions obtained under 365 nm excitation was enhanced by more than a hundred times in the glass treated by furnace annealing, mainly due to the energy transfer from Ag-clusters. Moreover, we discussed the contribution of Ag nanoparticles and defects to emission characteristics in the glasses treated by two annealing techniques. Up-conversion emissions of the $Er^{3+}$ ions under 980 nm excitation were enhanced due to the incorporation of $Er^{3+}$ and $Yb^{3+}$ ions into ZnO nanocrystals after thermal treatments.

Formation of Nano-oxides on Porous Metallic Glass Compacts using Hydrothermal Synthesis (수열합성 공정을 이용한 금속 다공체의 나노 산화물 형성)

  • Park, H.J.;Kim, Y.S.;Hong, S.H.;Kim, J.T.;Cho, J.Y.;Lee, W.H.;Kim, Ki Buem
    • Journal of Powder Materials
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    • v.22 no.4
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    • pp.229-233
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    • 2015
  • Porous metallic glass compact (PMGC) are developed by electro-discharge sintering (EDS) process of gas atomized $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ metallic glass powder under of 0.2 kJ generated by a $450{\mu}F$ capacitor being charged to 0.94 kV. Functional iron-oxides are formed and growth on the surface of PMGCs via hydrothermal synthesis. It is carried out at $150^{\circ}C$ for 48hr with distilled water of 100 mL containing Fe ions of 0.18 g/L. Consequently, two types of iron oxides with different morphology which are disc-shaped $Fe_2O_3$ and needle-shaped $Fe_3O_4$ are successfully formed on the surface of the PMGCs. This finding suggests that PMGC witih hydrothermal technique can be attractive for the practical technology as a new area of structural and functional materials. And they provide a promising road map for using the metallic glasses as a potential functional application.

Diffuse Large B-Cell Lymphoma Associated with a Chronic Inflammatory Condition Induced by Metallic Implants: A Case Report (금속성 임플란트로 인한 만성 염증 상태와 연관된 미만성 거대 B세포 림프종: 증례 보고)

  • Jin Hee Park;Sun Joo Lee;Hye Jung Choo
    • Journal of the Korean Society of Radiology
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    • v.83 no.4
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    • pp.931-937
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    • 2022
  • Chronic inflammatory condition associated with metallic implant insertion is a risk factor for diffuse large B-cell lymphoma (DLBCL). Metal ions play a role in the pathogenesis of lymphoma. We report a rare case of DLBCL in a patient who had a metallic implant in the proximal tibia for 15 months. Radiologic studies, including US and MRI, showed disproportionately large extraosseous soft-tissue mass and bone marrow involvement without prominent bone destruction. Multiple complications are associated with metallic implants, and misdiagnosis may lead to inappropriate treatment. Therefore, distinguishing lymphomas caused by a metallic implant-induced chronic inflammatory condition from other periprosthetic benign lesions and malignant soft tissue masses is challenging, but it is critical.

CMP Slurry Induction Properties of Silicate Oxides Deposited on Silicon Wafer (실리콘 웨이퍼위에 증착된 실리케이트 산화막의 CMP 슬러리 오염 특성)

  • 김상용;서용진;이우선;장의구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.2
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    • pp.131-136
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    • 2000
  • We have investigated the slurry induced metallic contaminations of undoped and doped silicate oxides surface on CMP cleaning process. The metallic contaminations by CMP slurry were evaluated in four different oxide films, such as plasma enhanced tetra-ethyl-orthyo-silicate glass(PE-TEOS), O3 boro-phos-pho-silicate glass(O3-BPSG), PE-BPSG, and phospho-silicate glass(PSG). All films were polished with KOH-based slurry prior to entering the post-CMP cleaner. The Total X-Ray fluorescence(TXRF) measurements showed that all oxide surfaces are heavily contaminated by potassium and calcium during polishing which is due to a CMP slurry. The polished O3-BPSG films presented higher potassium and calcium contaminations compared to PE-TEOS because of a mobile ions gettering ability of phosphorus. For PSG oxides, the slurry induced mobile ion contamination increased with an increase of phosphorus contents. In addition, the polishing removal rate of PSG oxides had a linear relationship as a function of phosphorus contents.

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A Study on Extraction of Non-metallic Ore Deposits from Remote Sensing Data of the Haenam Area (원격탐사자료에 의한 해남지역 비금속광상 및 관련 특성 추출을 위한 연구)

  • 박인석;박종남
    • Korean Journal of Remote Sensing
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    • v.8 no.2
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    • pp.105-123
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    • 1992
  • A study was made on the feature extraction for non-metallic one deposits and their related geology using the Remote Sensing and Airborne Radiometric data. The area chosen is around the Haenam area, where dickite and Quarzite mines are distributed in. The geology of the area consists mainly of Cretaceous volcanics and PreCambrian metamorphic. The methods applied are study on the reflectance characteristics of minerals and rocks sampled in the study area, and the feature extraction extraction of histogram normalized images for Landsat TM and Airborne Radiometric data, and finally evaluation of applicability of some useful pattern recognition techniques for regional lithological mapping. As a result, reflectances of non-metallic minerals are much higher than rock samples in the area. However, low grade dickites are slightly higher than rock samples, probably due to their greyish colour and also their textural features which may scatter the reflectance and may be capable of capturing much hychoryl ions. The reflectances of rock samples may depend on the degree of whiteness of samples. The outcrops or mine dumps in the study area were most effectively extracted on the histogram normalized image of TM Band 1, 2 and 3, due to their high reflectivity. The Masking technique using the above bands may be the most effective and the natural colour composite may provide some success as well. The colour composite image of PCA may also be effective in extracting geological features, and airborne radiometric data may be useful to some degree as an complementary tool.

Coating Durability of Metal Bipolar plate for Low Temperature PEMFC (저온 PEMFC용 금속분리판 코팅의 내구 특성 연구)

  • Kang, Sungjin;Jeon, Yootaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.82.2-82.2
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    • 2010
  • The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

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Acoustic waves in a high-frequency ultrasonic cleaner (고주파 초음파 세정기의 파동 해석)

  • 최성훈;김진오;김용훈
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1997.04a
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    • pp.656-661
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    • 1997
  • Ultrasonic cleaning at high frequency near 1MHz, called megasonic cleaning, is commonly used to remove particles less than 1.mu.m by generating accelerations on them. Ultrasonic waves generated from piezoelectric transducers are transmitted through a non-metallic inner container which is used to isolate a cleaning object from metallic ions. The transmission characteristics of a double-structured megasonic cleaner on the variations of parameters such as the thickness and oblique angle of a inner container, chemical ratio of a cleaning agent and temperature and transmittivity are investigated. The results are used to determine an optimum cleaning condition.

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