• Title/Summary/Keyword: Metal-Loading

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Preparation and Characterization of Mixed-matrix Membranes Containing MIL-100(Fe) for Gas Separation (MIL-100(Fe)를 함유한 혼합기질막(mixed-matrix membranes, MMMs)의 제조 및 기체 투과 특성 연구)

  • Song, Hye Rim;Nam, Seung Eun;Hwang, Young Kyu;Chang, Jong San;Lee, U Hwang;Park, You In
    • Membrane Journal
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    • v.23 no.6
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    • pp.432-438
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    • 2013
  • Mixed-matrix membranes (MMMs) containing MIL-100(Fe), a MOF type, were fabricated in this study. MMMs up to 30 wt% MOF loading were prepared, and their gas permeabilities were tested. $H_2$, $CO_2$, $O_2$, $N_2$, and $CH_4$ gas permeabilities increased with the MOF loading, while $SF_6$, the largest kinetic diameter in this study, exhibited reduction of gas permeability with the loading. Ideal gas selectivity of $N_2/SF_6$ improved by 40% as compared with pure polyimide membrane, suggesting the proposed MMMs were suitable for $N_2/SF_6$ separation.

Residual Strain Characteristics of Nickel-coated FBG Sensors (니켈이 코팅된 FBG 센서의 잔류 변형률 특성)

  • Cho, Won-Jae;Hwang, A-Reum;Kim, Sang-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.613-620
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    • 2017
  • A metal-coated FBG (fiber Bragg grating) sensor has a memory effect, which can recall the maximum strains experienced by the structure. In this study, a nickel-coated FBG sensor was fabricated through electroless (i.e., chemical plating) and electroplating. A thickness of approximately $43{\mu}m$ of a nickel layer was achieved. Then, we conducted cyclic loading tests for the fabricated nickel-coated FBG sensors to verify their capability to produce residual strains. The results revealed that the residual strain induced by the nickel coating linearly increased with an increase in the maximum strain experienced by the sensor. Therefore, we verified that a nickel-coated FBG sensor has a memory effect. The fabrication methods and the results of the cycle loading test will provide basic information and guidelines in the design of a nickel-coated FBG sensor when it is applied in the development of structural health monitoring techniques.

Assessment of Fatigue Damage of Adhesively Bonded Composite -Metal Joints by Acousto-Ultrasonics and Acoustic Emission (음향초음파와 음향방출에 의한 복합재료-금속 접착접합부의 피로손상 평가)

  • Kwon, Oh-Yang;Lee, Kyung-Joo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.4
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    • pp.425-433
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    • 2001
  • A correlation between fatigue damage and acousto-ultrasonic (AU) parameters has been obtained from signals acquired during fatigue loading of the single-lap joints of a carbon-fiber reinforced plastic (CFRP) laminates and A16061 plate. The correlation showed an analogy to those representing the stiffness reduction $(E/E_0)$ of polymer matrix composites by the accumulation of fatigue damage. This has been attributed to the transmission characteristics of acoustic wave energy through bonded joints with delamination-type defects and their influence on the change of spectral content of AU signals. Another correlation between fatigue cycles and the spectral magnitude of acoustic emission (AE) signals has also been found during the final stage of fatigue loading. Both AU and AE can be applied almost in real-time to monitor the evolution of damage during fatigue loading.

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Dynamic experimental study on single and double beam-column joints in steel traditional-style buildings

  • Xue, Jianyang;Qi, Liangjie;Yang, Kun;Wu, Zhanjing
    • Structural Engineering and Mechanics
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    • v.63 no.5
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    • pp.617-628
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    • 2017
  • In order to study the failure mode and seismic behavior of the interior-joint in steel traditional-style buildings, a single beam-column joint and a double beam-column joint were produced according to the relevant building criterion of ancient architectural buildings and the engineering instances, and the dynamic horizontal loading test was conducted by controlling the displacement of the column top and the peak acceleration of the actuator. The failure process of the specimens was observed, the bearing capacity, ductility, energy dissipation capacity, strength and stiffness degradation of the specimens were analyzed by the load-displacement hysteresis curve and backbone curve. The results show that the beam end plastic hinge area deformed obviously during the loading process, and tearing fracture of the base metal at top and bottom flange of beam occurred. The hysteresis curves of the specimens are both spindle-shaped and plump. The ultimate loads of the single beam-column joint and double beam-column joint are 48.65 kN and 70.60 kN respectively, and the equivalent viscous damping coefficients are more than 0.2 when destroyed, which shows the two specimens have great energy dissipation capacity. In addition, the stiffness, bearing capacity and energy dissipation capacity of the double beam-column joint are significantly better than that of the single beam-column joint. The ductility coefficients of the single beam-column joint and double beam-column joint are 1.81 and 1.92, respectively. The cracks grow fast when subjected to dynamic loading, and the strength and stiffness degradation is also degenerated quickly.

High-Rate Biological Nitrogen Removal from Plating Wastewater using Submerged MBR Packed with Granular Sulfur (황 충진 MBR을 이용한 도금폐수의 고효율 생물학적 질소 제거)

  • Kim, Dae-young;Moon, Jin-young;Baek, Jin-uk;Hwang, Yong-woo
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.2
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    • pp.200-208
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    • 2005
  • In this study, a new submerged membrane bioreactor process packed with granular sulfur (MBR-GS) was operated to identify the biological nitrogen removal behaviors with plating wastewater containing high-strength $NO_3{^-}$ concentration. The continuous denitrification was carried out at $20^{\circ}C$ with various nitrogen loading rates using synthetic wastewater, which composed of $NO_3{^-}$ and $HCO_3{^-}$, but also actual plating wastewater, which was collected from the effluent of the H metal plating company. As a result, high-rate denitrification in the range of $0.8kg\;NO_3{^-}-N/m^3\;day$ was accomplished at nitrogen loading rate of $0.9kg\;NO_3{^-}-N/m^3\;day$ using synthetic wastewater. Also, higher-rate denitrification with actual plating wastewater was achieved up to $0.91kg\;NO_3{^-}-N/m^3\;day$ at the loading rate of $1.11kg\;NO_3{^-}-N/m^3\;day$. Additionally, continuous filtration was possible during up to 30 days without chemical cleaning in the range of 20 cmHg of transmembrane pressure. On the basis of the proposed stoichiometry, ${SO_4}^{2-}$ production could be estimated efficiently, while observed alkalinity consumption was somewhat lower than theoretical value. Consequently, a new process, MBR-GS is capable of high-rate autotrophic denitrification by compulsive flux and expected to be utilized as an alternative of renovation techniques for nitrogen removal from not only plating wastewater but also municipal wastewater with low C/N ratio.

Comparison of Pollutant Removal Efficiency in Road Sediment with Media Using Filter Separator (필터 분리기를 이용한 여재별 도로퇴적물의 오염물질 제거효율 비교)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Chang-Su;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.332-340
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    • 2007
  • Storm runoff from road contains significant loads of particulate and dissolved solids, organic constituents and metal elements. Micro particle is important when considering pollution mitigation because pollutant metal and organics have similar behavior with particles. The objective of this research is to evaluate the hydrodynamic filter separator performance for road storm runoff treatment. A various types of media such as perlite, granular activated carbon, zeolite were used for column test packing media and filter separator, and to determine the removal efficiency with various surface loading rate. As the results of column test, the highest SS removal efficiency was using mixed media(granular activated carbon, zeolite and perlite), and granular activated carbon mixed with zeolite has higher heavy metal removal efficiency than perlite. In laboratory scale hydrodynamic filter separator study, the operation ranges of surface loading rates were from 192 to 1,469 $m^3/m^2/day$. The estimated overall removal efficiencies of hydrodynamic filter separator for typical storm runoff were SS 48.1%, BOD 31.9%, COD 32.6%, TN 15.5%, and TP 17.3%, respectively. For the case of heavy metals, overall removal efficiencies were Fe 26.0%, Cu 19.4%, Cr 25.7, Zn 16.6%, and Pb 15.0%, respectively. The most appropriate medium for hydrodynamic filter separator was perlite mixed with granular activated carbon to treatment of road storm runoff.

Conversion Efficiency of Catalyst for Lean-bum Natural Gas Vehicles with Steady and Unsteady State Temperature Change (정상 및 비정상 온도변화에 따른 린번 천연가스 자동차용 촉매의 정화성능)

  • Cho Byung-Chul;Juhng Woo-Nam;Piao Fengai;Lee Choon-Hee;Lee Jang-Hee;Yun Jeong-Eui
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.3
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    • pp.123-130
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    • 2005
  • In this study, we evaluated the CH4 and CO conversion efficiencies over the oxidation catalysts for natural gas vehicle with lean-burn system. On the fresh catalyst, the conversion efficiency was increased when the loading of precious metal was increased. On the aged catalyst, the conversion efficiency was decreased as increasing the excess air ratio. We could confirm the measuring conversion efficiency of the unsteady state with the FTIR and that of steady state with the GC The temperature increasing ratio of unsteady state is acceptable from 3$^{\circ}C$/min. to 15$^{\circ}C$/min. for the evaluation of catalyst conversion performance , which has within the 4$\%$ of the difference of conversion efficiency. We observed a physical behavior of the thermal aged catalyst's surface using TEM and BET device. It was found that the precious metal was grown to the micro-scopic size by thermal aging process.

Solution-Processed Metal Oxide Thin Film Nanostructures for Water Splitting Photoelectrodes: A Review

  • Lee, Mi Gyoung;Park, Jong Seong;Jang, Ho Won
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.185-202
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    • 2018
  • Photoelectrochemical (PEC) cells can convert solar energy, the largest potential source of renewable energy, into hydrogen fuel which can be stored, transported, and used on demand. In terms of cost competitiveness compared with fossil fuels, however, both photocatalytic efficiency and cost-effectiveness must be achieved simultaneously. Improvement of cost-effective, scalable, versatile, and eco-friendly fabrication methods has emerged as an urgent mission for PEC cells, and solution-based fabrication methods could be capable of meeting these demands. Herein, we review recent challenges for various nanostructured oxide photoelectrodes fabricated by solution-based processes. Hematite, tungsten oxide, bismuth vanadate, titanium oxide, and copper oxides are the main oxides focused on, and various strategies have been attempted with respect to these photocatalyst materials. The effects of nanostructuring, heterojunctions, and co-catalyst loading on the surface are discussed. Our review introduces notable solution-based processes for water splitting photoelectrodes and gives an outlook on eco-friendly and cost-effective approaches to solar fuel generation and innovative artificial photosynthesis technologies.

Fatigue Characteristics and FEM Analysis of 18Ni(200) Maraging Steel (18Ni 마르에이징강의 피로특성 및 유한요소해석)

  • 장경천;국중민;최병희;정재강;최병기
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.04a
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    • pp.136-142
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    • 2004
  • Effects of Nb(Niobium) contents and solution annealing on the strength and fatigue lift of 18%Ni maraging steel commonly using in aircraft, space field, nuclear energy, and vehicle etc. were investigated. Also the fatigue life stress intensity factor were compared experiment result and FEA(finite element analysis) result. The more Nb content, the higher or the lower fatigue lift on base metal specimens or solution annealed specimens showing that the fatigue life was almost the same. The maximum stresses of X, Y, and Z axis direction showed about 2.12${\times}$10$^2$MPa, 4.40${\times}$10$^2$MPa and 1.32${\times}$10$^2$MPa respectively. The Y direction stress showed the highest because of the same direction as the loading direction. The fatigue lives showed about 7% lower FEA result than experiment result showing almost invariable error every analyzed cycle. Stress intensity factor of the FEA result was lower about 3.5∼10% than that of the experiment result showing that the longer fatigue crack length, the higher error. It considered that the cause for the difference was the modeled crack tip having always the same shape and condition regardless of the crack growth.

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Effects of $K_{II}$ on fatigue crack propagation behavior of wedzone in generally rolled steel for marine structure (박용 구조물용 일반압연강 용접부의 피로균열 전파거동에 미치는 $K_{II}$의 영향)

  • 한문식;김상철
    • Journal of Welding and Joining
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    • v.6 no.3
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    • pp.43-55
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    • 1988
  • An experimental study was carried out to identify the fatigue fractue behavior of weld zone in generally rolled steel for marine structure. The bending an shear loads were applied simultaneously on the specimens to simulate real load condition for marine structure. The effect of the stress intensity factor under mode I with II loading condition on the initiation and the propagation of a crack were investigated, with particular emphaiss on mode II. When the $K_{II}$ stress intensiy factor in mode II was applied under mode I load condition, the growth behavior of a crack seems to be affected mainly by the anisotropic characteristic of materials. Especially, when the crack was located in and near the weld zone and parallel to th weld line, the propagation behaviour was turned out to be quite different from that of the base metal along the direction transverse to the weld line. In general, the propagation veiocity of the cracks in and near the weld zone was found to be slower that the velocity in base metal.

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