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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2013.23.6.432

Preparation and Characterization of Mixed-matrix Membranes Containing MIL-100(Fe) for Gas Separation  

Song, Hye Rim (Green Chemistry and Environmental Biotechnology, University of Science and Technology)
Nam, Seung Eun (Resources Separation and Recovery Research Group, Korea Research Institute of Chemical Technology)
Hwang, Young Kyu (Bio-refinery Research Group, Korea Research Institute of Chemical Technology)
Chang, Jong San (Bio-refinery Research Group, Korea Research Institute of Chemical Technology)
Lee, U Hwang (Bio-refinery Research Group, Korea Research Institute of Chemical Technology)
Park, You In (Resources Separation and Recovery Research Group, Korea Research Institute of Chemical Technology)
Publication Information
Membrane Journal / v.23, no.6, 2013 , pp. 432-438 More about this Journal
Abstract
Mixed-matrix membranes (MMMs) containing MIL-100(Fe), a MOF type, were fabricated in this study. MMMs up to 30 wt% MOF loading were prepared, and their gas permeabilities were tested. $H_2$, $CO_2$, $O_2$, $N_2$, and $CH_4$ gas permeabilities increased with the MOF loading, while $SF_6$, the largest kinetic diameter in this study, exhibited reduction of gas permeability with the loading. Ideal gas selectivity of $N_2/SF_6$ improved by 40% as compared with pure polyimide membrane, suggesting the proposed MMMs were suitable for $N_2/SF_6$ separation.
Keywords
MOF; MIL-100(Fe); MMMs; mixed matrix membrane; gas separation membrane;
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