• Journal of Welding and Joining
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• 제12권4호
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• pp.76-84
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• 1994

Droplet transfer modes due to welding conditions and the effect of Ca in welding wire on droplet transfer were investigated. Droplet transfer mode in CO$_{2}$ welding was classified into 2 modes, that is, short circuit and globular transfer, with increasing welding current and voltage. With increasing Ca content in wire, repulsive pressure due to vaporization of Ca was considerably increased. In short circuit transfer region, arcing time was increased and droplet transfer cycle was decreased, with increasing Ca content. In globular transfer region, welding condition for globular transfer was lower current region, with increasing Ca content.

• Journal of Welding and Joining
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• 제17권6호
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• pp.46-52
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• 1999

The auxiliary gas-shielded MAG (AMAG) process, which was devised to provide an argon-rich shielding environment using small amount of argon gas, was investigated experimentally to figure out its effects on metal transfer and weld quality. Proper conditions for the AMAG process including the argon gas ratio, position and direction of the auxiliary nozzle were determined experimentally. Performance of the AMAG process was compared with that of the double gas-shielded MAG(DMAG) and MAG processes by monitoring the bead profile, current and voltage waveforms. The AMAG process was found to provide better bead profile, more stable arc and wider operating range of spray transfer mode compared with the DMAG process. In general, performance of the AMAG process using the argon ratio of 30% was comparable to that of the MAG process using 80% argon and 20% CO₂ gas.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 춘계학술발표대회 개요집
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• pp.65-67
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• 2002

The gas metal arc welding(GMAW) is regarded as one of the best candidate for welding automation in industrial joining application. It is important to monitor the weld quality for the high performance of weld automation. The measured analog signal is frequency analyzed by digital signal process method. In order to observe the welding phenomena and control welding condition, arc light, voltage, and current are measured at the same time. They are analyzed and compared with arc sound. for these experiments, a power source of constant voltage characteristics was used in the pure metal transfer mode.

• 한국분무공학회지
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• 제18권4호
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• pp.196-201
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• 2013

SCR(Selective Catalytic Reduction) is a major after-treatment solution to reduce NOx emission in recent diesel engines. In this study, a metal foam is applied as an alternative SCR substrate and tested in a commercial diesel engine to compared with a conventional ceramic SCR system. Basic engine test from ND-13 mode shows that a metal foam catalyst has lower NOx conversion efficiency than a ceramic catalyst especially over $350^{\circ}C$. A metal foam catalyst has characteristics of high exhaust gas pressure before a SCR catalyst and high heat transfer rate due to its material and structure. NOx conversion efficiency of a metal foam catalyst shows an increasing tendency along with the increase of exhaust gas temperature by $500^{\circ}C$. The effect of urea injection quantity variation is also remarkable only at high exhaust gas temperature.

• 한국정밀공학회지
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• 제16권12호
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• pp.152-160
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• 1999

The weld quality of $CO_2$ arc welding is closely related to the arc stability. As the characteristics of the arc are excessively complex and nonlinear, it is not easy to make the arc model as mathematical form and to control the arc state to be stabilized. This paper was aimed to estimate the arc stability and to control for stabilizing the arc state in short circuit metal transfer mode of $CO_2$ arc welding. For these purposes, the behaviors of arc stability was investigated at different welding conditions using Mita's arc stability index, and the fuzzy control algorithm which uses the arc stability index as control imput and the arc voltage as control output was developed. In the control of the arc stability, the experiments of two cases were performed; the case of setting an initial welding voltage arbitrarily, the case of the step change in workpiece shape. Obtained results were as follows; Mita's arc stability index was able to be estimated qualitatively in the case of using the inverter type welding power source and the control performance for stabilizing the arc status was excellent in the case of existing step change disturbance.

• Journal of Welding and Joining
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• 제16권4호
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• pp.39-46
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• 1998

$CO_2$ gas shielded arc welding has been characterized with its harsh arc compared to Ar-based shielding gases and with its high level of spattere specially in welding current range of 250~300 amperes. In this range of welding current, the metal transfer mode showed to be changed from short circuit to globular with the increase of welding voltage resulting in so-called the transitional mode in which both modes of transfer appeared together. To characterize the transitional mode, the short circuit events were divided into two groups, i.e. normal short circuit (N.S.C) which has short circuit time $(t_s)$ over 2msec and instantaneous short circuit (I.S.C) of $t_s$$\leq$2msec. The experimental results showed that the number of N.S.C decreased almost linearly with the increase of welding voltage and appeared to be not related with spatter generation rate. However I.S.C became to be pronounced in the transitional condition and its number reached the maximum value at around 29.0 volts. Considering the relation with the spatter generation rate, it was found that the number of I.S.C had a very strong correlation with the spatter generation rate of the transitional condition. It was further demonstrated that spatter generation rate decreased quite linearly with the decrease of I.S.C frequency. It implies that I.S.C is the most important waveform factor controlling the spatter generation of the transitional mode, i.e. in the middle range of welding current. Based on these results, It was discussed that in the transitional mode the basic concept of waveform control for suppressing spatter generation would be different from the one applied for typical short circuit transfer mode of low welding current.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2009년 추계학술발표대회
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• pp.202-204
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• 2009

Erosion is a common failure mode of materials frequently encountered in plant and power industry. Although the erosion resistance of Fe-base alloy has been inferior to the other expensive materials, it is expected that the strain-induced martensitic transformation can impart high erosion resistance to Fe-base alloy. The key technology to develop Fe-base metal cored welding wire for erosion resistant overlay welding may include the strain-induced metallurgy for hardening rate control and the welding flux metallurgy for dilution control. Sophisticated studies showed that the strain-induced martensitic transformation behavior was related to the critical strain energy which was dependent on the alloy composition. Dilution and bead shape of overlay weld were proved to be affected by metal transfer mode during gas tungsten arc welding and elements in welding fluxes. It was considered that the highly erosion resistant Fe-base overlay weld could be achieved by precise control of alloy composition to have proper level of critical strain energy for energy absorption and welding flux formulation to have small amount of deoxidizing metallic elements for dilution.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.454-457
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• 1997

The purpose of this study is to develop an optimal model, using existing models, that is able to estimate the amount of spatter utilizing artificial neural network in the short circuit transfer mode of gas metal arc (GMA) welding. The amount of spatter generated during welding can become a barometer which represents the process stability of metal transfer in GMA welding, and it depends on some factors which constitute a periodic waveforms of welding current and arc voltage in short circuit GMA welding. So, the 12 factors, which could express the characteristics for the waveforms, and the amount of spatter are used as input and output variables of the neural network, respectively. Two neural network models to estimate the amount of spatter are proposed: A neural network model, where arc extinction is not considered, and a combined neural network model where it is considered. In order to reduce the calculation time it take to produce an output, the input vector and hidden layers for each model are optimized using the correlation coefficients between each factor and the amount of spattcr. The est~mation performance of each optimized model to the amount of spatter IS assessed and compared to the est~mation performance of the model proposed by Kang. Also, through the evaluation for the estimation performance of each optimized model, it is shown that the combined neural network model can almost perfectly predict the amount of spatter.

• 약학회지
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• 제36권6호
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• pp.577-581
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• 1992

Norfloxacin complexes of $Fe^{2+}$, $Cu^{2+}$ and $Al^{3+}$ have been prepared as solids. The stoichiometry of the complexes has been established. IR investigation indicates the metal-ligating sites in norfloxacin. The bioactivities of complexes all lower than that of norfloxacin. The solubilities and partition coefficients have been measured as a function of temperature. The data are used to evaluate the thermodynamic parameters ${\Delta}G$, ${\Delta}H$, ${\Delta}S$ for the solute transfer process and compared with the parent quinolone, norfloxacin. The existence of such complexes is discussed in the light of quinolone mode-of-action theories.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2153-2161
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• 2007

The transition metal-induced in situ generation of carbene complexes from alkynes having a carbonyl or imino group as a nucleophilic functionality has been investigated. These reactive carbenoid species are generated with high atom efficiency through a 6-endo-dig cyclization mode based on the electrocyclization of vinylidene complexes or a 5-exo-dig cyclization mode in π-alkyne complexes, and have been found to serve as versatile intermediates in catalytic carbene transfer reactions. Highlighted and reviewed in this account are the generation and preparation of pyranylidene, furylcarbene, pyrrolylcarbene, and vinylcarbene complexes and their application to [3,3]sigmatropic rearrangement of acylcyclopropylvinylidenes, catalytic cyclopropanation reactions, [2,3]sigmatropic rearrangement or condensation reactions via ylides, ring-opening and substitution reactions with heteroaromatic compounds, and catalytic isomerization of oligoynes.