• Title/Summary/Keyword: Metal surface decontamination

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Laser decontamination for radioactive contaminated metal surface: A review

  • Qian Wang;Feisen Wang;Chuang Cai;Hui Chen;Fei Ji;Chen Yong;Dasong Liao
    • Nuclear Engineering and Technology
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    • v.55 no.1
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    • pp.12-24
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    • 2023
  • With the improvement of laser technology, the strategic needs of efficient and precise decontamination of various components in nuclear application units can be fulfilled by laser decontamination. The surface contaminants of nuclear facilities mainly exist both as loose contaminated layer and fixed oxide layer. The types of radionuclides and contamination layer thickness are closely related to the operation status of nuclear facilities, which have an important influence on the laser decontamination process. This study reviewed the mechanism of laser surface treatment and the influence of laser process parameters on the decontamination thickness, decontamination factor, decontamination efficiency and the distribution of aerosol particle. Although multiple studies have been performed on the mechanism of laser processing and laser decontamination process, there are few studies on the microscopic process mechanism of laser decontamination and the influence of laser decontamination on surface properties. In particular, the interaction between laser and radioactive contaminants needs more research in the future.

Surface removal of stainless steel using a single-mode continuous wave fiber laser to decontaminate primary circuits

  • Song, Ki-Hee;Shin, Jae Sung
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3293-3298
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    • 2022
  • Removing radioactive contaminated metal materials is a vital task during the decommissioning of nuclear power plants to reduce the cost of the post-dismantling process. The laser decontamination technique has been recognized as a key tool for a successful dismantling process as it enables a remote operation in radioactive facilities. It also minimizes exposure of workers to hazardous materials and reduces secondary waste, increasing the environmental friendless of the post-dismantling processing. In this work, we present a thorough and efficient laser decontamination approach using a single-mode continuous-wave (CW) laser. We subjected stainless steels to a surface-removal process that repetitively exposes the laser to a confined region of ~75 ㎛ at a high scanning rate of 10 m/s. We evaluate the decontamination performance by measuring the removal depth with a 3D scanning microscope and further investigate optimal removal conditions given practical parameters such as the laser power and scan properties. We successfully removed the metal surface to a depth of more than 40 ㎛ with laser power of 300 W and ten scans, showing the potential to achieve an extremely high DF more than 1000 by simply increasing the number of scans and the laser power for the decontamination of primary circuits.

Decontamination of Metal Surface by Reactive Cold Plasma

  • YUN Sang-pil;JEON Sang-hwan;KIM Yang-saa
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.300-315
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    • 2005
  • Recently plasma surface-cleaning or surface-etching techniques have been focused in the respect of decontamination of spent or used nuclear parts and equipment. In this study decontamination rate of metallic cobalt surface was experimentally investigated via its surface etching rate with a $CF_4-O_2$ mixed gas plasma and metallic surface wastes of cobalt oxides were simulated and decontaminated with $NF_3$ - Ar mixed gas plasma. Experimental results revealed that a mixed etchant gas with about $80{\%}\;CF_4-20{\%}\;O_2$ gives the highest reaction rate of cobalt disk and the rate reaches with a negative 300 DC bias voltage up to $0.43\;{\mu}m$/min at $380^{\circ}C$ and $20{\%}\;NF_3-80\%$ Ar mixed gas gives $0.2\;{\mu}m$/min of reaction rate of cobalt oxide film.

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The effects of physical decontamination methods on zirconia implant surfaces: a systematic review

  • Tan, Nathan Chiang Ping;Khan, Ahsen;Antunes, Elsa;Miller, Catherine M;Sharma, Dileep
    • Journal of Periodontal and Implant Science
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    • v.51 no.5
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    • pp.298-315
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    • 2021
  • Purpose: Peri-implantitis therapy and implant maintenance are fundamental practices to enhance the longevity of zirconia implants. However, the use of physical decontamination methods, including hand instruments, polishing devices, ultrasonic scalers, and laser systems, might damage the implant surfaces. The aim of this systematic review was to evaluate the effects of physical decontamination methods on zirconia implant surfaces. Methods: A systematic search was conducted using 5 electronic databases: Ovid MEDLINE, PubMed, Scopus, Web of Science, and Cochrane. Hand searching of the OpenGrey database, reference lists, and 6 selected dental journals was also performed to identify relevant studies satisfying the eligibility criteria. Results: Overall, 1049 unique studies were identified, of which 11 studies were deemed suitable for final review. Air-abrasive devices with glycine powder, prophylaxis cups, and ultrasonic scalers with non-metal tips were found to cause minimal to no damage to implantgrade zirconia surfaces. However, hand instruments and ultrasonic scalers with metal tips have the potential to cause major damage to zirconia surfaces. In terms of laser systems, diode lasers appear to be the most promising, as no surface alterations were reported following their use. Conclusion: Air-abrasive devices and prophylaxis cups are safe for zirconia implant decontamination due to preservation of the implant surface integrity. In contrast, hand instruments and ultrasonic scalers with metal tips should be used with caution. Recommendations for the use of laser systems could not be fully established due to significant heterogeneity among included studies, but diode lasers may be the best-suited system. Further research-specifically, randomised controlled trials-would further confirm the effects of physical decontamination methods in a clinical setting.

PFC Ultrasonic Decontamination Efficiency on the Various Types of Metal Specimens (금속 시편 형태에 따른 PEC 초음파 제염 성능)

  • Won Hui-Jun;Kim Gye-Nam;Jung Chung-Hun;Park Jin-Ho;Oh Won-Zin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.293-300
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    • 2005
  • Ultrasonic decontamination of the type 304 stainless steel specimen loosely contaminated with $Eu_2O_3$ powders was investigated. Decontamination factors (DFs) by the three kinds of ultrasonic media such as water, pure PFC (Pefluorocarbon, $C_7F_{16}$) and a mixed solution of $99.9\;vol\%\;PFC\;and\;0.1\;vol\%$ anionic surfactant were determined. The determined DF values were 20, 50 and 200, respectively. This significant difference in the decontamination factors for the different decontamination solution was well explained by the surface tension of the media as well as the interaction between the positively charged surface of $Eu_2O_3$ powders and the anionic surfactant. Ultrasonic decontamination behavior of the loosely contaminated metal specimens such as plate, pipe, welding specimen and crevice specimen in the mixed solution of PFC and anionic surfactant was also investigated. The contaminants were completely removed for the tested specimens except for the longest specimen. For 6-cm long pipe specimen, however, $98.5\%$ of the contaminants were removed.

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Chemical Decontamination Design for NPP Decommissioning and Considerations on its Methodology (원전해체를 위한 화학제염 설계 및 그 방법론에 대한 고려사항)

  • Park, Geun Young;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.3
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    • pp.187-199
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    • 2015
  • Decontamination is one of the crucial technologies that are applied during the decommissioning process of nuclear facilities to secure the safety of workers and to minimize the quantity of radioactive waste. Decontamination removes radionuclides on the surface of contaminated metal. Compared with decontamination for operational nuclear facilities, decontamination for nuclear power plants that are being decommissioned needs to remove the more and thicker surface using more aggressive agents or specially developed equipment. This paper analyzed the factors to be considered before planning the decontamination, representative decontamination technologies, and their application procedure,etc. ORCID

Electrochemical corrosion study on base metals used in nuclear power plants in the HyBRID process for chemical decontamination

  • Kim, Sung-Wook;Park, Sang-Yoon;Roh, Chang-Hyun;Shim, Ji-Hyung;Kim, Sun-Byeong
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2329-2333
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    • 2022
  • Base metal corrosion forms a significant issue during the chemical decontamination of the primary coolant loop in nuclear power plants as it is directly related to the economic and safety viability of decommissioning. In this technical note, potentiodynamic evaluations of several base metals (304 stainless steel, SA106 Grade B carbon steel, and alloy 600) were performed to determine their corrosion behavior during the hydrazine (N2H4)-based reductive ion decontamination (HyBRID) process. The results suggested that N2H4 protected the surface of the base metals in the HyBRID solution, which is primarily composed of H2SO4. The corrosion resistance of the carbon steel was further improved through the addition of CuSO4 to the solution. The corrosion rate of carbon steel in the H2SO4-N2H4-CuSO4 solution was lower than that exhibited in an oxalic acid solution, a commonly used reaction medium during commercial decontamination processes. These results indicate the superiority of the HyBRID process with respect to the base metal stability.

Development of Cesium-selective Paramagnetic Core Inorganic Composite Agent for Water Decontamination (수질오염 제염을 위한 세슘 선택성 상자성 코어 무기복합제염제 개발)

  • Seong Pyo Hong;Bo-Sun Kang
    • Journal of Radiation Industry
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    • v.18 no.2
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    • pp.127-132
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    • 2024
  • Large amounts of liquid radioactive waste or radioactive contaminated water could be produced during the treatment of radiation accidents or during the dismantling and decontamination process of nuclear power plants. Since most of the decontamination agents to date are difficult to recover after adsorption of radioactive isotopes, their use in open environments such as rivers, reservoirs, or oceans is limited. In this study, as a radioactive decontamination agent that can overcome the current limitations when used in an open environment, a paramagnetic core inorganic composite (PMCIC) decomposite agent with high selectivity to cesium ions was developed. PMCore was prepared by synthesizing paramagnetic iron oxide nanoparticles, and inorganic crystals such as metal-ferrocyanide were conjugated to the surface so that PMCore could be selective to cesium ions. The developed PMCIC could be easily recovered from the water by magnetism and could adsorb up to 94 μM of Cs atoms per 1 g of PMCIC.