• Title/Summary/Keyword: Metal substrate

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Collision Behavior of Molten Metal Droplet by Laser Beam (레이저 빔에 의해 생성된 금속액적의 충돌거동)

  • 김용욱;양영수
    • Laser Solutions
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    • v.6 no.1
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    • pp.1-8
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    • 2003
  • A molten metal droplets are deposited onto solid substrate for solid freeform fabrication, Collision dynamic and substrate heat transfer associated with solidification determine the final shape of molten metal droplets. In this study, the experimental model, based on the variational condition with substrate temperature and falling height, was produced reliable optimal data of droplet pattern.

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Effects of Catalyst Metal and Substrate Temperature on a Flame Synthesis of Carbon Nanomaterials (화염을 이용한 탄소나노튜브와 나노섬유의 합성에 미치는 촉매금속 및 기판온도의 영향)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.8 no.2
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    • pp.27-33
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    • 2003
  • Synthesis of carbon nanomaterials on a metal substrate by an ethylene fueled inverse diffusion flame was illustrated. Stainless steel plates were used for the catalytic metal substrate. The effects of catalyst metal particles were investigated through $Fe(NO_3){_3}$ (ferric nitrate, nonahydrate) and $Ni(NO_3){_2}$ (nickel nitrate, hexahydrate). Carbon nanotubes and nanofibers with diameters of $30{\sim}70nm$ were found on the substrate for the case of using SUS304 substrates only and using them with metal nitrates. In case of using metal nitrates, due to the easy activation of the metal particles, the formation and growth of carbon nanomaterials were occurred in the lower temperature region than that of using SUS304 substrates only.

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Production of Ultra-fine Metal Powder with Gas Atomization Processes

  • Wang, M. R.
    • Journal of ILASS-Korea
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    • v.11 no.2
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    • pp.59-68
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    • 2006
  • Experimental results of the metal powder production with internal mixing, internal impinging and the atomizer coupled with substrate design are presented in this paper. In a test with internal mixing atomizer, mean powder size was decreased from $37{\mu}m\;to\;23{\mu}m$ for Pb65Sn35 alloy as the gas-to-melt mass ratio was increased from 0.04 to 0.17. The particle size further reduces to $16.01{\mu}m$ as the orifice area is increased to $24mm^2$. The micrograph of the metal powder indicates that very fine and spherical metal powder has been produced by this process. In a test program using the internal impinging atomizers, the mean particle size of the metal powder was decreased from $22{\mu}m\;to\;12{\mu}m$ as the gas-to-melt-mass ratio increased from 0.05 to 0.22. The test results of an atomizer coupled with a substrate indicates that the deposition rate of the molten spray on the substrate is controlled by the diameter of the substrate, the height of the substrate ring and the distance of the substrate from the outlet of the atomizer. This in rum determines the powder production rate of the spraying processes. Experimental results indicate that the deposition rate of the spray forming material decreases as the distance between the substrate and the atomizer increases. For example, the deposition rate decreases from 48% to 19% as the substrate is placed at a distance from 20cm to 40cm. On the other hand, the metal powder production rate and its particle size increases as the subsrate is placed far away from the atomizer. The production of metal powder with mean particle size as low as $3.13{\mu}m$ has been achieved, a level which is not achievable by the conventional gas atomization processes.

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Synthesis of Carbon Nanotubes and Nanofibers on a Substrate Coated with Metal Nitrates using an C2H4 Inverse Diffusion Flame (메탈나이트레이트가 도포된 기판과 C2H4 역확산화염을 이용한 탄소나노튜브 및 탄소나노섬유의 합성)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.10
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    • pp.1480-1488
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    • 2003
  • Synthesis of carbon nanomaterials on a substrate coated with metal nitrates using an ethylene fueled inverse diffusion flame was illustrated. The effects of radial distance, residence time of the substrate, and hydrocarbon composition on the synthesis of carbon nanomaterials were investigated. The effects of catalyst metal particles were also studied using SUS304 substrates coated with Fe(NO$_3$)$_3$ (ferric nitrate, nonahydrate) and Ni(NO$_3$)$_2$(nickel nitrate, hexahydrate), and Cu substrate. Carbon nanomaterials, with diameters ranging from 30 - 70 nm, were observed on the substrate for both cases of using substrates only and using them with metal nitrates. In case of using the substrate with metal nitrates, the formation and growth of carbon nanomaterials were occurred in the lower temperature region than that of using the substrates only due to the easy activation of the metal particles coated on the surface of the substrates.

Synthesis of Carbon Nanotubes and Nanofibers on a Catalytic Metal Substrate by an Inverse Diffusion Flame (역확산화염과 촉매금속 기판을 이용한 탄소 나노튜브와 나노섬유의 연소합성)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.7 no.4
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    • pp.21-28
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    • 2002
  • Synthesis of carbon nanotubes and nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was illustrated. Stainless steel plates were used for the catalytic metal substrate. Multi-walled carbon nanotubes and nanofibers with a diameter range of 30-80nm were found on the substrate. The temperature of the substrate played an important role in the formation of carbon nanotubes and nanofibers. The pathway to the nanotubes and nanofibers could be determined by the temperature history of the substrate.

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Preparation of LaGaO3 Based Oxide Thin Film on Porous Ni-Fe Metal Substrate and its SOFC Application

  • Ju, Young-Wan;Matsumoto, Hiroshige;Ishihara, Tatsumi;Inagaki, Toru;Eto, Hiroyuki
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.796-801
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    • 2008
  • $LaGaO_3$ thin film was prepared on Ni-Fe metal porous substrate by Pulsed Laser Deposition method. By the thermal reduction, the dense $NiO-{Fe_3}{O_4}$ substrate is changed to a porous Ni-Fe metal substrate. The volumetric shrinkage and porosity of the substrate are controlled by the reduction temperature. It was found that a thermal expansion property of the Ni-Fe porous metal substrate is almost the same with that of $LaGaO_3$ based oxide. $LaGaO_3$ based electrolyte films are prepared by the pulsed laser deposition (PLD) method. The film composition is sensitively affected by the deposition temperature. The obtained film is amorphous state after deposition. After post annealing at 1073K in air, the single phase of $LaGaO_3$ perovskite was obtained. Since the thermal expansion coefficient of the film is almost the same with that of LSGM film, the obtained metal support LSGM film cell shows the high tolerance against a thermal shock and after 6 min startup from room temperature, the cell shows the almost theoretical open circuit potential.

Analysis and Conservation of Metal Thread Made of Proteinaceous Substrate - Golden Decorative Rank Badge of an Official Uniform Excavated from Baekryeong Im's Tomb in the 16th Century of Korea - (단백질계 배지로 이루어진 금속사의 분석과 보존처리 - 16세기 임백령 묘 출토 단령의 직금 흉배를 중심으로 -)

  • Noh, Soo-Jung;Oh, Joon-Suk
    • Journal of the Korean Society of Costume
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    • v.58 no.9
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    • pp.129-141
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    • 2008
  • Jikgeum(woven with supplementary golden wefts) hyungbae(rank badge) of danryung(official uniform) excavated from Im Backryung'tomb($1498{\sim}1546$) of the Joseon dynasty($1392{\sim}1910$) at Goyang, Gyunggi-Do in 2007, was in a critical condition because of serious collapse of substrate in metal thread. For conservation of hyungbae, metal thread was examined by different scientific methods(Light Microscope, Scanning Electron Microscope and Energy Dispersive X-Rray Spectrometry(SEM-EDS), Fourier Transform Infrared Spectroscopy(FT-IR)). Analytical data showed that metal thread was gilt membrane strip composed of gold leaves and proteinaceous substrate which was probably parchment. To protect collapse of substrate, 1% solution of Paraloid B-72 was infilterated into substrate for consolidation of substrate and it was adhered to warp of fabric in hyungbae, before wet cleaning. After wet cleaning, the most of the gold leaves were restored, which was confirmed by both the examination with the naked eye and the microscopic examination.

New Method of Gas Barrier Coating on Plastic Substrate for Flexible Display

  • Hwang, Hee-Nam;Choi, Jae-Moon;Kim, In-Sun;Park, Jong-Rak
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.985-987
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    • 2004
  • A plastic substrate for flexible display is developed. The gas barrier property in the substrate is improved through depositing metal and metal oxide multi layer on plastic film by PVD process. The metal/metal-oxide multiplayer on plastic film shows excellent gas barrier property and optical property.

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Flame Synthesis of Carbon Nanofibers using SUS304 Substrates (촉매금속 기판을 사용한 탄소나노섬유의 화염합성)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.8 no.2
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    • pp.50-55
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    • 2003
  • Synthesis of carbon nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was observed. Stainless steel plates were used for the catalytic metal substrate. The effects of radial distance and residence time of the substrate were investigated. The role of hydrocarbon composition in the fuel was also viewed. Nanofibers with a diameter range of 30-70nm were found on the substrate. The carbon nanofibers were formed and grown in the region from 4 to 5.5mm from the central axis of a flame outside of the visible flame front in the radial direction. The minimum residence time required for the formation of carbon nanofibers were about 20 seconds, and over 60 seconds were required for the full-scale growth. The characteristic time of the formation of carbon nanofibers was much shorter than that of the substrate temperature growth. In this study, the variation in hydrocarbon composition had no significant effect on the formation and growth of the carbon nanofibers.

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Silicidation and Thermal Stability of the So/refreactory Metal Bilayer on the Doped Polycrystalline Si Substrate (Co/내열금속/다결정 Si 구조의 실리사이드화와 열적안정성)

  • 권영재;이종무
    • Journal of the Korean Ceramic Society
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    • v.36 no.6
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    • pp.604-610
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    • 1999
  • Silicide layer structures and morphology degradation of the surface and interface of the silicide layers for he Co/refractory metal bilayer sputter-deposited on the P-doped polycrystalline Si substrate and subjected to rapid thermal annealing were investigated and compared with those on the single Si substrate. The CoSi-CoSi2 phase transition temperature is lower an morphology degradation of the silcide layer occurs more severely for the Co/refractorymetal bilayer on the P-doped polycrystalline Si substrate than on the single Si substrate. Also the final layer structure and the morphology of the films after silicidation annealing was found to depend strongly upon the interlayer metal. The layer structure after silicidation annealing of Co/Hf/doped-poly Si is Co-Hf alloy/polycrystalline CoSi2/poly Si substrate while that of Co/Nb is polycrystalline CoSi2/NbSi2/polycrystalline CoSi2/poly Si.

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