• 제목/요약/키워드: Metal oxide addition

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Effects of Indium and Tin on Interfacial Property of Porcelain Fused to Low Gold Alloys (도재소부용 금합금에서 인듐, 주석 첨가가 금속-도재계면 특성에 미치는 영향)

  • Nam, Sang-Yong;Kwak, Dong-Ju;Chung, Suk-Min
    • Journal of Technologic Dentistry
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    • v.23 no.1
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    • pp.31-43
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    • 2001
  • This study was performed to observe the micro-structure change of surface, behavior of oxide change of element, the component transformation of the alloy and the bonding strength between the porcelain interface in order to investigate effects of indium, tin on interfacial properties of porcelain fused to low gold alloy. Hardness of castings was measured with a micro-Vicker's hardness tester. The compositional change of the surface of heat-treated specimen was analyzed with an EDS and an EPMA. The interfacial shear bonding strength between alloy specimen and fused porcelain was measured with a mechanical testing system(MTS 858.20). The results were as follows: 1) The hardness value of alloy increased as increasing amount of indium addition. 2) The formation of oxidation increased as increasing indium and tin contents after heat treatment. 3) Diffusion of indium and tin elements increased as increasing indium and tin contents in metal-porcelain surface after porcelain fused to metal firing. 4) The most interfacial shear bonding strength was increased as increasing a composition of adding elements, and a heat-treatment time, and an oxygen partial pressure. From the results of this study it was found that the addition of alloying elements such as indium and tin increase hardness of as-cast alloy, produce surface oxide layer of adding elements by heat-treatment which may improve interfacial bonding strength between alloy and porcelain.

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An ASIC implementation of a Dual Channel Acoustic Beamforming for MEMS microphone in 0.18㎛ CMOS technology (0.18㎛ CMOS 공정을 이용한 MEMS 마이크로폰용 이중 채널 음성 빔포밍 ASIC 설계)

  • Jang, Young-Jong;Lee, Jea-Hack;Kim, Dong-Sun;Hwang, Tae-ho
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.5
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    • pp.949-958
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    • 2018
  • A voice recognition control system is a system for controlling a peripheral device by recognizing a voice. Recently, a voice recognition control system have been applied not only to smart devices but also to various environments ranging from IoT(: Internet of Things), robots, and vehicles. In such a voice recognition control system, the recognition rate is lowered due to the ambient noise in addition to the voice of the user. In this paper, we propose a dual channel acoustic beamforming hardware architecture for MEMS(: Microelectromechanical Systems) microphones to eliminate ambient noise in addition to user's voice. And the proposed hardware architecture is designed as ASIC(: Application-Specific Integrated Circuit) using TowerJazz $0.18{\mu}m$ CMOS(: Complementary Metal-Oxide Semiconductor) technology. The designed dual channel acoustic beamforming ASIC has a die size of $48mm^2$, and the directivity index of the user's voice were measured to be 4.233㏈.

Enhancement on the Charge-discharge Property of Carbon Anode by the Addition of Metal Oxides in Li-ion Secondary Batteries (금속산화물 첨가방법에 의한 리튬이차전지 부극재료의 충방전 특성 개선)

  • 김정식
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1085-1089
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    • 2003
  • In the present study effects of SnO$_2$-impregnation on the cell performance of Mesocarbon Microbeads (MCMB) electrode in the Li-ion battery have been investigated. Sn element was impreganted into MCMB powders by the chemical titration, and then post annealed at 250$^{\circ}C$ for 1 h in ambient atmosphere to be transformed as tin-oxide. From the measurement for the cell performance with the half cell in which the SnO$_2$-impregnated MCMB was used as an anode, the SnO$_2$-impregnated MCMB showed higher charge/discharge capacities, higher reversible specific charge capacity and better cycleability than a raw MCMB. As the amount of impregnated SnO$_2$ increased, both reversible and irreversible capacities increased.

Effect of Red Pepper Seed on Kimchi Antioxidant Activity During Fermentation

  • Sim, Ki-Hyeon;Han, Young-Sil
    • Food Science and Biotechnology
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    • v.17 no.2
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    • pp.295-301
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    • 2008
  • In this study, the antioxidant activities of red pepper seed kimchi extracts were examined. The extracts were evaluated by various antioxidant assays that included determinations of total phenolic and flavonoid contents, DPPH radical scavenging, superoxide anion radical scavenging, nitric oxide scavenging, superoxide dismutase (SOD) activity, metal chelating activity, and reducing power. All the kimchi extracts showed strong antioxidant activities by the tested methods. The 7% red pepper seed kimchi that was fermented for 6 days possessed the highest activity according to the performed tests. Yet, the highest scavenging activity was exhibited against nitrite, by extracts from kimchi for 0 day of fermentation rather than 6 days. All the activities for the kimchi fermented for 0 day with the addition of 7% red pepper seed increased markedly with an increase in concentration. With the exception of metal chelating and SOD activities, for the antioxidant properties assayed, the red pepper seed kimchi extracts were found to be highly effective.

Detection of Streptavidin-Biotin Complexes Using a Highly Sensitive AlGaN/GaN-Based Extended-Gate MISHEMT-Type Biosensor

  • Lee, Hee Ho;Bae, Myunghan;Choi, Byoung-Soo;Shin, Jang-Kyoo
    • Journal of Sensor Science and Technology
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    • v.25 no.5
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    • pp.320-325
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    • 2016
  • In this paper, we propose an AlGaN/GaN-based extended-gate metal-insulator-semiconductor high electron mobility transistor (MISHEMT)-type biosensor for detecting streptavidin-biotin complexes. We measure the drain current of the fabricated sensor, which varies depending on the antibody-antigen reaction of streptavidin with biotin molecules. To confirm the immobilization of biotin polyethylene glycol (PEG) thiol, we analyze the Au surface of a GaN sample using X-ray photoelectron spectroscopy (XPS). The proposed biosensor shows higher sensitivity than Si-based extended-gate metal oxide semiconductor field effect transistor (MOSFET)-type biosensor. In addition, the proposed AlGaN/GaN-based extended-gate MISHEMT-type biosensor exhibits better long-term stability, compared to the conventional AlGaN/GaN-based MISHEMT-type biosensor.

Removal of Volatile Organic Compounds (VOCs) of Deodorant by Adding a Metal Oxide to the Essential Oils (식물정유물질에 금속산화물을 첨가한 탈취제의 휘발성유기화합물질의 제거에 관한 연구)

  • Lim, You-Young;Lee, Min-Ho;Jeon, Soo-Bin;Yang, Kyeong-Soon;Jeong, Hae-Eun;Oh, Kwang-Joong
    • Clean Technology
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    • v.22 no.2
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    • pp.96-105
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    • 2016
  • VOCs emissions from industries cause the air pollution and odor. In the industrial facilities, the existing odor treatment techniques have limits and problems. In this study, the optimum essential oil and metal oxide selected by screening test. lavender oil, cypress oil and TiO2 were determined by deodorant materials and those were blended by 5%, 45%, 10%, respectively. In addition, the result of batch type experiments depending on the dilution rate, injection, rate, temperature showed that the optimum condition of deodorant is 6 mL of injection rate, and 200 times of dilution rate and the removal efficiency increased in proportion with temperature. In addition, the activation energy was calculated from the rate equation, which appeared in the 3-4 times lower than conventional deodorants.

Development of Copper and Copper Oxide Removal Technology Using Supercritical CO2 and Hexane for Silicon Solar Cell Recycling (실리콘 태양전지 재자원화를 위한 초임계 CO2 및 헥산을 이용한 구리 및 산화구리 제거기술 개발)

  • Lee, Hyo Seok;Cho, Jae Yu;Heo, Jaeyeong
    • Current Photovoltaic Research
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    • v.7 no.1
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    • pp.21-27
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    • 2019
  • Lifetime of Si photovoltaics modules are about 25 years and a large amount of waste modules are expected to be discharged in the near future. Therefore, the extraction and collection of valuable metals out of discharged Si modules will be one of the important technologies. In this study, we demonstrated that supercritical $CO_2$ extraction method can be effectively used to remove Cu, one of the abundant elements in the module, as well as its oxide form, $Cu_2O$. Especially, we proved that the addition of hexane as co-solvent is effective for the removal of both materials. The optimal ratio of $CO_2$ and hexane was 4:1 at a fixed temperature and pressure of $250^{\circ}C$ and 250 bar, respectively. In addition, it was proven that the removal of $Cu_2O$ was preceded via reduction of $Cu_2O$ to Cu.

An Assessment of the Deterioration of Fabricated Metal Thread with Light, and Temperature and Humidity Factors: A Focused Study of Asian Textile Collections at the Metropolitan Museum of Art, New York

  • Park, Hae Jin;Hwang, Minsun;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.34 no.4
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    • pp.245-257
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    • 2018
  • To investigate the deterioration of textiles with metal thread, I surveyed 40 textile objects, dating from the 11th to the 19th century from Korea, China, Japan, and Central Asia at the Metropolitan Museum of Art, New York. This survey included various types, widths, and thicknesses of metal thread. In addition, deterioration was examined under the microscope and color information was collected using the spectrophotometer. While investigating metal thread in the collections, I fabricated 12 different types of metal samples with metal leaf(24K gold, silver, and copper leaf), adhesive (hide animal glue and a mixture of hide animal glue and iron oxide red), and paper substrate(Korean mulberry and Taiwanese kozo paper). The accelerated deterioration process of those fabricated samples was carried out using a light box(UV and daylight), and a humidity cabinet. In the light experiment with blue scales textile fading card(aka, blue wool standard), the metal leaf began to peel off during the deterioration process with 756,000 lux-hours UV and daylight. In the temperature and humidity experiment, I could observe the reddish tarnish on copper, and some part of it began to peel off. Color reading on the light exposed samples showed that the degree of color change on the surface follows the amount of exposure as it increased over time. On the other hand, color change on the samples after artificial deterioration using temperature and humidity factors showed random change of color with occasional spikes. Distortion of original shape worsened in the samples exposed to temperature and humidity.

Characterizations of Photo-Oxidative Abilities of Nanostructured TiO2 Powders Prepared with Additions of Various Metal-Chlorides during Homogeneous Precipitation (균일침전시 여러 가지 금속염화물들을 첨가하여 제조된 TiO2 나노 분말들의 광산화 능력 평가)

  • Hwang D. S;Lee N. H;Lee H. G;Kim S. J
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.293-299
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    • 2004
  • Transition metal ions doped $TiO_2$ nanostructured powders were prepared with simply heating aqueous $TiOCl_2$ solutions, contained various metal ions (Ni, Al, Fe, Zr, and Nb) of 1.47 mol% added as metal-chlorides, at $100^{\circ}C$ for 4 hrs by homogeneous precipitation process under suppressing conditions of water vaporization. The characterizations for prepared $TiO_2$ powders were carried out to observe doping of metal ions, their concentrations and microstructures using XRD, UV-VIS (DRS), XPS, SEM, TEM and ICP. Also, photo-oxidative abilities were evaluated by decomposition of 4-chlorophenol (4CP) under ultraviolet light irradiations. No secondary oxide phases were formed in all the $VTiO_2$ powders, showing doping with various transition metal ions. When adding ions ($Ni^{2+}$ or$ Al^{3+ }$ and $Zr^{4+}$ ) having valance states or ionic radii greatly different from those of $Ti^{4+}$ , the $TiO_2$ powders of mixed anatase and rutile phases were formed, whereas in the case of additions of $^Fe{3+ }$ and $Nb^{ 5+}$ as well as no addition of metal ion the powders with pure rutile phase alone were formed. Among the prepared $TiO_2$ powders, Ni$^{2+}$ doped $TiO_2$ powders, containing a small amount of anatase phase, showed excellent photo-oxidative ability in 4CP decomposition because of relative decreases in electron-hole recombination and poisoning of $TiO_2$ surface during the photoreaction.n.

Effect of the Slag Former on the Metal Melting and Radionuclides Distribution in an Electric Arc Furnace

  • Song Song-Pyung;Min Byung-Youn;Choi Wang-Kyu;Chung Chong-Hun;Oh Won-zin
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.32-37
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    • 2005
  • The characteristics of the metal melting and radionuclide distribution of the radioactive has been investigated in a lab-scale arc furnace. The slag former based on the constituents of silica, calcium oxide, aluminum oxide, borate and calcium fluoride additions was used for melting of the stainless and carbon steel. In the melting of the stainless steel, the amount of slag formation increased with an increase of the concentration of the slag former. But the effects of the slag basicity on the amount of stag formation showed a local maximum value of the slag formation with an increase of the basicity index in the melting of the stainless steel as well as in the melting of the carbon steel. With an increase of the amount of slag former addition, the trends of the cobalt distribution into the ingot and the stag depended on the kind of slag former used in the melting of the stainless steel while the effect of the slag basicity on the distribution of the cobalt was not clarified in the melting of carbon steel. Tn the melting of the carbon steel, the strontium was captured at up to $50\%$ into the slag phase. Cesium was completely eliminated from the melt of the stainless steel as well as the carbon steel and distributed to the dust phase.

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