• Title/Summary/Keyword: Metal mixture

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Removal of Potassium from Molasses by Solvent Extraction and Ion Exchange

  • Wang, Lingyun;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2711-2716
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    • 2014
  • The high content of potassium in molasses limits its usage as a raw material for stock feed. Moreover, its high viscosity makes it difficult to develop an efficient removal process. In this study, ion exchange and solvent extraction experiments have been performed to investigate the removal of potassium from a mixture of molasses with water. Cationic exchange resins (AG50W-X8 and Diphonix) showed a high loading percentage of potassium but the occurrence of breakthrough in few bed volumes was a drawback to the industrial application. Among the cationic extractants (D2EHPA, PC 88A, Cyanex 272) tested in this study, saponified PC 88A was found to be the best extractant for the removal of potassium. Batch simulation studies on a three stage counter current extraction confirmed that 85% of potassium was removed from 50 wt % molasses solution in water by using saponifed PC 88A.

Numerical investigation of gaseous detonation observed in the elasto-plastic metal tubes (탄소성 금속관 내 가스 폭굉의 수치적 연구)

  • Gwak, Min-cheol;Do, Yeong-dea;Park, Jeong-su;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.85-87
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    • 2012
  • We present a numerical investigation on gaseous (ethylene-air mixture) detonation in the elastoplastical metal tubes to understand the wall effects associated with the developing detonation instability. The acoustic disturbances originating from the rapidly expanding tube walls reach the detonating flame surface, thereby causing flame distortions and total energy losses. The compressible Navier-Stokes equations with equation of state for gas and elasto-plastic deformation field equations for inert tubes are solved simultaneously to understand the complex multi-material interaction in the rapidly expanding gas pipe. In order to track governing variables across the material interface, we use the hybrid particle level-set and ghost fluid methods to precisely estimate the interfacial quantities. Features observed from the deforming (thin) tube show substantially different behavior when a detonation propagates in the rigid (thick) tube with no acoustically responding wall conditions.

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Adsorption of Heavy Metals by the Mixture of Macbansuk and Clay (맥반석과 점토로 성형한 흡착제에 의한 수중의 중금속 흡착)

  • 연익준;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.150-157
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    • 1999
  • According to the fact that Macbansuk and clay are very porous, we produced combined adsorbent and we investigated the removing capacity of adsorbent to toxic heavy metal (Pb, Cu) in the single and mixed solution.Then the experimental parametars were pH, reaction time and amount of adsorbent. And we studied possibility of adsorbent by applying to the Freundlich isotherm. As raising the pH of single and mixed solution in range 2~5, the maximum adsorption capability was investigated in range 3~4. When Cu and Pb were applied to Freundlich isotherm, l/n were 0.291 and 0.513 respectively. In the case of mixed solution with both, l/n value was 0.614. In this study, we concluded that the combined adsorbent treated toxic heavy metal is possible under 100 ppm of its concentration.

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Development of Transparent Conductive Patterned Film with Hybrid Ag Ink

  • Choe, Ju-Hwan;Baek, Su-Jin;Lee, Beom-Ju;Sin, Jin-Guk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.2.3-2.3
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    • 2011
  • With increased interest in printed devices, various metal nano inks have been investigated as candidates materials for printed electrodes and wiring as well as conductive film substituting photo-lithography process. Recent advances in organic conductive polymer allow us to fabricate high performance printed device. Meanwhile, there was several attempts to fabricate conductive films by mixing conductive polymer with metal nano-particle or nano-wires. The presence of Ag nanowires in conductive polymer mixture have shown good potential in organic photovoltaic devices.

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Growth of carbon nanotubes on metal substrates using microwave plasma-enhanced chemical vapor deposition (금속 기판 위에 성장한 탄소나노튜브 특성에 관한 연구)

  • 김현숙;박성렬;양지훈;문상현;박종윤;박래준
    • Journal of the Korean Vacuum Society
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    • v.11 no.4
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    • pp.256-260
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    • 2002
  • Carbon nanotubes on metal(SUS304) substrates were synthesized by using micro-wave plasma-enhanced chemical vapor deposition at $650^{\circ}C$ with gas mixture CH$_4$(11%) and H$_2$(89%). Their structure was investigated by scanning electron microscopy and transmission electron microscopy. Raman spectroscopy was also used to justify the structure and crystallinity of graphite sheets. High-resolution transmission electron microscopy images clearly showed carbon nanotubes to be multwalled. The measured turn-on field and current density obtained from I-V measurement were 4.4 V/$\mu \textrm{m}$ and $8.4\times10^1\mu\textrm{A}/\textrm{cm}^2$, respectively.

Equivalent Beam and Equivalent Bimorph Beam Models for ionic Polymer-Metal Composite Actuators (등가 보 및 등가 바이모프 보를 이용한 IPMC 작동기 모델링)

  • 이상기;김광진;윤광준;박훈철
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.11
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    • pp.1012-1016
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    • 2004
  • In the present paper, equivalent beam and equivalent bimorph beam models for IPMC(ionic Polymer-Metal Composite) actuators are described. Physical properties of an IPMC, such as Young's modulus and electro-mechanical coupling coefficient. are determined from the rule of mixture, bimorph beam equations, and measured force-displacement data of a cantilevered IPMC actuator. By using a beam equation with estimated physical properties, actuation displacements of a cantilevered IPMC actuator was calculated and a good agreement between the computed tip displacements and the measured data was observed. Finite element analysis(FEA) combined with the estimated physical properties was used to reproduce the force-displacement relationship of an IPMC actuator. Results from the FEA agreed well with the measure data. The proposed models might be used for modeling of IPMC actuators with complicated shapes and boundary conditions.

Adsorption of Heavy Metals on Organobentonite (유기 벤토나이트에 의한 중금속 흡착특성)

  • 유지영;최재영;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.168-171
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    • 2001
  • Organobentonite modified with hexadecyltrimethylammonium (HDTMA) was used to quantify an adsorption of heavy metals. Based on preliminary experiments, optimal soil/solution ratio, a range of pH, and electrolyte were selected. Adsorption experiments of cadmium and lead were conducted to quantify an adsorption selectivity to bentonite and organobentonite. Adsorption of cadmium and lead to bentonite was increased with increasing a soil/solution ratio. Adsorption of cadmium and lead to bentonite was increased with increasing a soil/solution ratio. Adsorptions of heavy metal to organobentonite were slightly reduced relative to bentonite. This study used the principle of hard-soft-acid-base (HBAB) to interpretate an adsorption mechanism. Because of competition between cadmium and lead. adsorption of cadmium and lead was reduced in mixture of heavy metals. Adsorption selectivity.

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The consolidation of CNT/Cu mixture powder using equal channel angular pressing (Equal Channel Angular Pressing 공정을 이용한 CNT/Cu 복합분말의 고형화)

  • Yoon, S.C.;Quang, P.;Kim, H.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.119-122
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    • 2006
  • In this study, bottom-up type powder processing and top-down type SPD (severe plastic deformation) approaches were combined in order to achieve full density of 1 vol.% carbon nanotube (CNT)-metal matrix composites with superior mechanical properties by improved particle bonding and least grain growth, which were considered as a bottle neck of the bottom-up method using the conventional powder metallurgy of compaction and sintering. ECAP (equal channel angular pressing), the most promising method in SPD, was used for the CNT-Cu powder consolidation. The powder ECAP processing with 1, 2, 4 and 8 route C passes was conducted at room temperature. It was found by mechanical testing of the consolidated 1 vol.% CNT-Cu that high mechanical strength could be achieved effectively as a result of the Cu matrix strengthening and improved particle bonding during ECAP. The ECAP processing of powders is a viable method to achieve fully density CNT-Cu nanocomposites.

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New Glass Ceramics for Hard Disk Substrates with Improved Surface Flatness

  • Utsuno, Futoshi;Yamada, Yusuke;Takeya, Huminori;Yasui, Itaru
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.363-367
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    • 1999
  • New glass ceramics were investigated for the application as substrates to be used in hard disk devices. The glass system to precipitate lithium di-silicate was studied so as to optimize the composition to realize very high surface flatness. The addition of small amount of several metal oxides with high valences had very drastic effects on the microstructure, because they played a role of crystallization agents, and consequently it determined surface flatness even after the polishing process. The possible mechanism changes of crystal growth due to the addition of metal oxides were discussed in relation to the final micro-texture development. The glass ceramics with very high surface flatness(Ra=7.1 $\AA$) was obtained by the addition of the mixture of $P-2O_5 \;and \;MoO_3$ as crystallization agents.

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The Separation and Analysis of Babbitt Metal by the Cation Exchange Chromatographic Method (양이온 교환 크로마토그라피에 의한 Babbitt 금속의 분리 및 정량)

  • Sun Tae Kim;Kee Won Cha;Kee Chae Park
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.366-369
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    • 1971
  • The cation exchange chromatographic method for the analysis of Babbitt metal has been studied. The quantitative separation of the mixture of Sb, Cu, Pb, and Sn ions has been obtained by elution, through 5cm column of resin, Rexyn 101 (Na form, 100~200 mesh), using 0.1 M NaCl solution for Sb, pH 4.5 and pH 7 solution of 0.01 M Na-Citrate + 0.1 M $NaNO_3$ for Cu and Pb, and 2NHCl solution for Sn as eluent.

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