• Title/Summary/Keyword: Metal level

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The Correlation of Heavy Metal Contents in Herbal Medicines and Their Soils at North Gyeongbuk Area (경북북부지역 한약재와 재배토양중의 중금속과의 상관관계)

  • Park Moon-Ki;Lee Hyeun-Jeung;Kim Kwang-Joong;Moon Young-Soo
    • Journal of Environmental Science International
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    • v.14 no.2
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    • pp.185-192
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    • 2005
  • The concentration of heavy metal were studied for the estimation of quality in herbal medicines which is Bupleuri Radix, Paeoniae Radix, Dioscoreae Rhizoma and Astragali Radix in products of north Gyeongbuk area Also, we collected soils from several area in Gyeongbuk, and determined heavy metal concentration of soils by ICP. We compared with herbal medicines in products of Gyeongbuk and their soils. The average levels of heavy metal of herbal medicines in Gyeongbuk area are as follows: Mercury is 0.037mg/kg, Chromium is 0.093 mg/kg, Nickel is 0.108mg/kg, Copper is 0.475mg/kg, Zinc is 3.14mg/kg, Manganese is 1.52mg/kg, Iron is 7,83mg/kg, and Cadmium, Lead and Arsenic is not detected. It was very lower in concentrations than those of average Korea area. For the heavy metals contents of Gyeongbuk area, in Gong Jung Ri, represented the higher level, it may be due to a near the road. The Cd contents in soil was not a wide difference. For the As and Pb contents in soil, Song Sa Ri (Bupleuri Radix) represented the higher level(0.68mg/kg, 1523mg/kg). Correlation coefficients of heavy metal contents in cultured herbal medicines and their soils did not give reproducible results. But the degree of correlation between a few heavy metal contents of Dioscoreae Rhizoma and their soil showed the good transfer from the soil.

Abrasion Wear Behavior of Recycled Tungsten Carbide Reinforced Metal Matrix Composite (재생 초경합금 분말을 활용한 금속기지 복합재료의 Abrasion 마모거동)

  • Kang, Nam-Hyun;Chae, Hyun-Byung;Kim, Jun-Ki;Choi, Jong-Ha;Kim, Jeong-Han
    • Korean Journal of Materials Research
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    • v.13 no.12
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    • pp.850-854
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    • 2003
  • The abrasion wear behavior on the hardfacing weld was investigated by performing abrasion wear, hardness, and microstructural tests. The gas metal arc(GMA) weld was produced by using the cored wire which was filled with the hard metal, i.e., the recycled tungsten carbide (WC) reinforced metal matrix composite. For 30% addition of the hard metal, the abrasion wear resistance was significantly improved comparing with that for 20% addition of the hard metal. Above 30% addition of the hard metal, however, there was no significant improvement of the wear resistance. The improvement of the wear resistance was due to the increased amount of eutectic carbides(W$_{6}$C) which was formed during GMA welding. For the weld in which the hard metal was added to 30-40%, an optimum level of abrasion wear resistance was performed.

Planarization of Multi-level metal Structure by Chemical Mechanical Polishing (CMP 공정을 이용한 Multilevel Metal 구조의 평탄화 연구)

  • 김상용;서용진;김태형;이우선;김창일
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.456-460
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    • 1997
  • As device sizes are scaled to submicron dimensions, planarization technology becomes increasing1y important, both during device fabrication and during formation of multilevel interconnects and wiring. Chemical Mechanical Polishing (CMP) has emerged recently as a new processing technique for achieving a high degree of planarization for submicron VLSI applications. This paper is presented the results of CMP process window characterization studies for 0.35 micron process with 6 metal layers.

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Effect of Zinc on Vascular Smooth Muscle Cell Death Mediated by PDTC

  • Moon Sung-Kwon;Ha Sang-Do
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.1
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    • pp.40-43
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    • 2000
  • Pyrrolidinedithiocarbamate (PDTC) and N-Acetylcysteine (NAC) are metal and nonmetal-chelating antioxidant which can induce rat and human smooth muscle cell death. When the smooth muscle cells from mouse aorta (MASMC) that we successfully cultured recently was exposed to PDTC and NAC in a normal serum state, the cells were induced to death by these compounds. However, PDTC did not induce the cell death in a serum depleted medium. This data suggests that certain factors in the serum may mediate the cytotoxic effect of PDTC. The metal chelator, Ca-EDTA blocked PDTC-induced cell death, but Cu-, Fe-, and Zn-EDTA did not block the PDTC-induced cell death. This data indicated that copper, iron, and zinc in the serum may lead to the cytotoxic effect of PDTC. Investigation of the intracellular zinc level in PDTC-induced smooth muscle cell death using the zinc probe dye N-(6-methoxy-8-quinolyl)-p-toluenesulfonamide shows that only the muscle-containing layers of the arteries have higher level of zinc. As expected, PDTC increased the intracellular fluorescence level of the zinc. In agreement with these results, the addition of an exogenous metal, zinc, induced the vascular aortic smooth muscle cell death which led to an increased intracellular zinc level. We concluded that PDTC induced mouse aortic smooth muscle cell death required not only zinc level but also intracellular copper and iron level. The mechanism of this antioxidant to induce vascular smooth muscle cell death may provide a new strategy to prevent their proliferation in arteriosclerotic lesions.

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Fabrication and Characterization of Carbon Nanotube/Cu Nanocomposites by Molecular Level Mixing Process (분자수준 혼합공정을 이용한 탄소나노튜브/Cu 나노복합재료의 제조 및 특성평가)

  • Kim, Kyung-Tae;Cha, Seung-Il;Hong, Soon-Hyung
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.261-264
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    • 2005
  • Since the first discovery of carbon nanotube (CNT) in 1991, a window to new technological areas has been opened. One of the emerging applications of CNTs is the reinforcement of composite materials to overcome the performance limits of conventional materials. However, because of the difficulties in distributing CNTs homogeneously in metal or ceramic matrix by means of traditional composite processes, it has been doubted whether CNTs can really reinforce metals or ceramics. In this study, CNT reinforced Cu matrix nanocomposite is fabricated by a novel fabrication process named molecular level mixing process. This process produces CNT/Cu composite powders whereby the CNTs are homogeneously implanted within Cu powders. The CNT/Cu nanocomposite, consolidated by spark plasma sintering of CNT/Cu composite powders, shows to be 3 times higher strength and 2 times higher Young’s modulus than Cu matrix. This extra-ordinary strengthening effect of carbon nanotubes in metal is higher than that of any other reinforcement ever used for metal matrix composites.

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Adsorption of Low-level CO2using Activated Carbon Pellet with Glycine Metal Salt Impregnation (글리신 금속염 함침 입자상 활성탄의 저농도 이산화탄소 흡착능 평가연구)

  • Lim, Yun Hui;Adelodun, A.A.;Jo, Young Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.1
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    • pp.68-76
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    • 2014
  • The present study has evaluated the $CO_2$ adsorption amount of activated carbon pellets (AC). Coconut shell based test AC were modified with surface impregnation of glycine, glycine metal salts and monoethanolamine for low level $CO_2$ (3000 ppm) adsorption. Physical and chemical properties of prepared adsorbents were analyzed and the adsorbed amount of $CO_2$ was investigated by using pure and 3,000 ppm $CO_2$ levels. The impregnation of nitrogen functionalities was verified by XPS analysis. The adsorption capacity for pure $CO_2$ gas was found to reach upto 3.08 mmol/g by AC-LiG (Activated carbon-Lithium glycinate), which has the largest specific surface area ($1026.9m^2/g$). As for low level $CO_2$ flow the primary amine impregnated adsorbent showed 0.26 mmol/g of adsorption amount, indicating the highest selectivity. An adsorbent with potassium-glycine salts (AC-KG, Activated carbon-Potassium glycinate) instead of amine presented with 0.12 mmol/g of adsorption capacity, which was higher than that of raw activated carbon granules (0.016 mmol/g).

Experimental study on fatigue crack propagation of fiber metal laminates

  • Xie, Zonghong;Peng, Fei;Zhao, Tianjiao
    • Steel and Composite Structures
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    • v.17 no.2
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    • pp.145-157
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    • 2014
  • This study aimed to investigate the fatigue crack growth behavior of a kind of fiber metal laminates (FML) under four different stress levels. The FML specimen consists of three 2024-T3 aluminum alloy sheets and two layers of glass/epoxy composite lamina. Tensile-tensile cyclic fatigue tests were conducted on centrally notched specimen at four stress levels with various maximum values. A digital camera system was used to take photos of the propagating cracks on both sides of the specimens. Image processing software was adopted to accurately measure the length of the cracks on each photo. The test results show that: (1) a-N and da/dN-a curves of FML specimens can be divided into transient crack growth segment, steady state crack growth segment and accelerated crack growth segment; (2) compared to 2024-T3 aluminum alloy, the fatigue properties of FML are much better; (3) da/dN-${\Delta}K$ curves of FML specimens can be divided into fatigue crack growth rate decrease segment and fatigue crack growth rate increase segment; (3) the maximum stress level has a large influence on a-N, da/dN-a and da/dN-${\Delta}K$ curves of FML specimens; (4) the fatigue crack growth rate da/dN presents a nonlinear accelerated increasing trend to the maximum stress level; (5) the maximum stress level has an almost linear relationship with the stress intensity factor ${\Delta}K$.

Cold Cracking Susceptibility in Weld Metal of High Strength-Toughness Steel (고강도 고인성강 용접금속의 저온균열 감수성에 관한 연구)

  • 이종봉;안상곤;안영호;김영우
    • Journal of Welding and Joining
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    • v.13 no.4
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    • pp.46-54
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    • 1995
  • The cold cracking susceptibility of a variety of weld metals deposited by GMAW with several kinds of commercial solid wires for high strength-toughness steel was investigated. G-BOP test and LB-TRC test were carried out to study the effects of preheat, chemical composition and hydrogen level on the weld metal cold cracking. The results obtained are as follows. 1) 10% CPT obtained by G-BOP test was the most valuable criteria for evaluating the cold cracking susceptibility of weld metals compared with percentage of cracking at room temperature and crack free temperature, and it had good correlation with the results of LB-TRC test. 2) Cold cracking susceptibility of weld metals was high in the row of MG100A, MG100C, MG100D and MG100B. Welds deposited with MG130 and MG80 showed similar icidents of cracking with MG100C and MG100B respectively, even though their strength levels were different. 3) Diffusible hydrogen level in weld metals which has good relation with hydrogen content in wire itself was the most critical factor for controlling the cold cracking susceptibility of weld metal.

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A study on the Comparison of the Heavy Metal in Abandoned mine Soil by Sequential Extraction Exthaction Methods (폐광산 주변 토양 내 중금속의 연속추출법과 토양오염공정시험기준에 대한 비교 연구)

  • Lee, Jong-Deuk;Kim, Tae-Dong;Jeon, Gee-Seok;Kim, Hee-Joung
    • Journal of Soil and Groundwater Environment
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    • v.16 no.6
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    • pp.95-105
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    • 2011
  • Total extraction method and environmental standards for heavy metals in soils were revised in regulation recently. In case of Area 3, as the law amended, the soil pollution level has gone up to 4 to 13 times higher depending on the type of heavy metal. In this study, it compares the properties of heavy metals of soil by sequential extraction and total extraction methods depending on the analysis method, using the soil around mine. In case of arsenic, the soil pollution level has gone up to 4 times higher, but 6 to 10 times in the sample soil. Also, according to the results of portability evaluation depending on the type of existence form of heavy metal it exists as residual form in mine waste rock, which is less likely to move, while it exists as migrated form in tailing. Therefore, it should be considered to evaluate the soil pollution and decide the contaminated bounds depending on the existence form of heavy metals on soil to restore the polluted soil.

Wear Characteristics of Metal Ball and Seat for Metal-Seated Ball Valve (금속 볼 밸브의 볼·시트 마멸 특성에 관한 실험적 연구)

  • Bae, Junho;Chung, Koo-Hyun
    • Tribology and Lubricants
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    • v.32 no.1
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    • pp.32-37
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    • 2016
  • The wear characteristics of metal ball and seat in a metal-seated ball valve significantly affect the performances such as leakage and valve torque. In this work, the wear characteristics of metal ball and seat are experimentally investigated. A stainless steel ball and seat with a high corrosion-resistant coating are prepared and a component level test was performed. The hardness and surface roughness of specimens cut from the metal ball and seat are measured before and after the test using a micro-Vickers hardness tester and confocal microscopy, respectively. In order to assess the wear characteristics, the surfaces of the specimens are carefully examined after the test. The confocal microscope data show that the surface roughness values of both the ball and seat increase by a factor of 3-4, which may lead to an increase in valve torque. However, the wear of the seat is found to be more significant than that of the ball. In addition, a comparison of the surfaces of the ball and seat before and after testing revealed that adhesive and abrasive wear are the major wear mechanisms. The results of this study may aid in the design of metal-seated ball valves from the tribological point of view.