• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.456-460
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• 1997

As device sizes are scaled to submicron dimensions, planarization technology becomes increasing1y important, both during device fabrication and during formation of multilevel interconnects and wiring. Chemical Mechanical Polishing (CMP) has emerged recently as a new processing technique for achieving a high degree of planarization for submicron VLSI applications. This paper is presented the results of CMP process window characterization studies for 0.35 micron process with 6 metal layers.

• Biotechnology and Bioprocess Engineering:BBE
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• v.5 no.1
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• pp.40-43
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• 2000

Pyrrolidinedithiocarbamate (PDTC) and N-Acetylcysteine (NAC) are metal and nonmetal-chelating antioxidant which can induce rat and human smooth muscle cell death. When the smooth muscle cells from mouse aorta (MASMC) that we successfully cultured recently was exposed to PDTC and NAC in a normal serum state, the cells were induced to death by these compounds. However, PDTC did not induce the cell death in a serum depleted medium. This data suggests that certain factors in the serum may mediate the cytotoxic effect of PDTC. The metal chelator, Ca-EDTA blocked PDTC-induced cell death, but Cu-, Fe-, and Zn-EDTA did not block the PDTC-induced cell death. This data indicated that copper, iron, and zinc in the serum may lead to the cytotoxic effect of PDTC. Investigation of the intracellular zinc level in PDTC-induced smooth muscle cell death using the zinc probe dye N-(6-methoxy-8-quinolyl)-p-toluenesulfonamide shows that only the muscle-containing layers of the arteries have higher level of zinc. As expected, PDTC increased the intracellular fluorescence level of the zinc. In agreement with these results, the addition of an exogenous metal, zinc, induced the vascular aortic smooth muscle cell death which led to an increased intracellular zinc level. We concluded that PDTC induced mouse aortic smooth muscle cell death required not only zinc level but also intracellular copper and iron level. The mechanism of this antioxidant to induce vascular smooth muscle cell death may provide a new strategy to prevent their proliferation in arteriosclerotic lesions.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.261-264
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• 2005

Since the first discovery of carbon nanotube (CNT) in 1991, a window to new technological areas has been opened. One of the emerging applications of CNTs is the reinforcement of composite materials to overcome the performance limits of conventional materials. However, because of the difficulties in distributing CNTs homogeneously in metal or ceramic matrix by means of traditional composite processes, it has been doubted whether CNTs can really reinforce metals or ceramics. In this study, CNT reinforced Cu matrix nanocomposite is fabricated by a novel fabrication process named molecular level mixing process. This process produces CNT/Cu composite powders whereby the CNTs are homogeneously implanted within Cu powders. The CNT/Cu nanocomposite, consolidated by spark plasma sintering of CNT/Cu composite powders, shows to be 3 times higher strength and 2 times higher Young’s modulus than Cu matrix. This extra-ordinary strengthening effect of carbon nanotubes in metal is higher than that of any other reinforcement ever used for metal matrix composites.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.1
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• pp.68-76
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• 2014

The present study has evaluated the $CO_2$ adsorption amount of activated carbon pellets (AC). Coconut shell based test AC were modified with surface impregnation of glycine, glycine metal salts and monoethanolamine for low level $CO_2$ (3000 ppm) adsorption. Physical and chemical properties of prepared adsorbents were analyzed and the adsorbed amount of $CO_2$ was investigated by using pure and 3,000 ppm $CO_2$ levels. The impregnation of nitrogen functionalities was verified by XPS analysis. The adsorption capacity for pure $CO_2$ gas was found to reach upto 3.08 mmol/g by AC-LiG (Activated carbon-Lithium glycinate), which has the largest specific surface area ($1026.9m^2/g$). As for low level $CO_2$ flow the primary amine impregnated adsorbent showed 0.26 mmol/g of adsorption amount, indicating the highest selectivity. An adsorbent with potassium-glycine salts (AC-KG, Activated carbon-Potassium glycinate) instead of amine presented with 0.12 mmol/g of adsorption capacity, which was higher than that of raw activated carbon granules (0.016 mmol/g).

• Steel and Composite Structures
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• v.17 no.2
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• pp.145-157
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• 2014

This study aimed to investigate the fatigue crack growth behavior of a kind of fiber metal laminates (FML) under four different stress levels. The FML specimen consists of three 2024-T3 aluminum alloy sheets and two layers of glass/epoxy composite lamina. Tensile-tensile cyclic fatigue tests were conducted on centrally notched specimen at four stress levels with various maximum values. A digital camera system was used to take photos of the propagating cracks on both sides of the specimens. Image processing software was adopted to accurately measure the length of the cracks on each photo. The test results show that: (1) a-N and da/dN-a curves of FML specimens can be divided into transient crack growth segment, steady state crack growth segment and accelerated crack growth segment; (2) compared to 2024-T3 aluminum alloy, the fatigue properties of FML are much better; (3) da/dN-${\Delta}K$ curves of FML specimens can be divided into fatigue crack growth rate decrease segment and fatigue crack growth rate increase segment; (3) the maximum stress level has a large influence on a-N, da/dN-a and da/dN-${\Delta}K$ curves of FML specimens; (4) the fatigue crack growth rate da/dN presents a nonlinear accelerated increasing trend to the maximum stress level; (5) the maximum stress level has an almost linear relationship with the stress intensity factor ${\Delta}K$.

• Journal of Welding and Joining
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• v.13 no.4
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• pp.46-54
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• 1995

The cold cracking susceptibility of a variety of weld metals deposited by GMAW with several kinds of commercial solid wires for high strength-toughness steel was investigated. G-BOP test and LB-TRC test were carried out to study the effects of preheat, chemical composition and hydrogen level on the weld metal cold cracking. The results obtained are as follows. 1) 10% CPT obtained by G-BOP test was the most valuable criteria for evaluating the cold cracking susceptibility of weld metals compared with percentage of cracking at room temperature and crack free temperature, and it had good correlation with the results of LB-TRC test. 2) Cold cracking susceptibility of weld metals was high in the row of MG100A, MG100C, MG100D and MG100B. Welds deposited with MG130 and MG80 showed similar icidents of cracking with MG100C and MG100B respectively, even though their strength levels were different. 3) Diffusible hydrogen level in weld metals which has good relation with hydrogen content in wire itself was the most critical factor for controlling the cold cracking susceptibility of weld metal.

• Journal of Soil and Groundwater Environment
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• v.16 no.6
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• pp.95-105
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• 2011

Total extraction method and environmental standards for heavy metals in soils were revised in regulation recently. In case of Area 3, as the law amended, the soil pollution level has gone up to 4 to 13 times higher depending on the type of heavy metal. In this study, it compares the properties of heavy metals of soil by sequential extraction and total extraction methods depending on the analysis method, using the soil around mine. In case of arsenic, the soil pollution level has gone up to 4 times higher, but 6 to 10 times in the sample soil. Also, according to the results of portability evaluation depending on the type of existence form of heavy metal it exists as residual form in mine waste rock, which is less likely to move, while it exists as migrated form in tailing. Therefore, it should be considered to evaluate the soil pollution and decide the contaminated bounds depending on the existence form of heavy metals on soil to restore the polluted soil.

• Tribology and Lubricants
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• v.32 no.1
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• pp.32-37
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• 2016

The wear characteristics of metal ball and seat in a metal-seated ball valve significantly affect the performances such as leakage and valve torque. In this work, the wear characteristics of metal ball and seat are experimentally investigated. A stainless steel ball and seat with a high corrosion-resistant coating are prepared and a component level test was performed. The hardness and surface roughness of specimens cut from the metal ball and seat are measured before and after the test using a micro-Vickers hardness tester and confocal microscopy, respectively. In order to assess the wear characteristics, the surfaces of the specimens are carefully examined after the test. The confocal microscope data show that the surface roughness values of both the ball and seat increase by a factor of 3-4, which may lead to an increase in valve torque. However, the wear of the seat is found to be more significant than that of the ball. In addition, a comparison of the surfaces of the ball and seat before and after testing revealed that adhesive and abrasive wear are the major wear mechanisms. The results of this study may aid in the design of metal-seated ball valves from the tribological point of view.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.4
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• pp.51-58
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• 2008

This paper presents the effect of acid treatment on the removal of metals and the brightness of pulp. The bleached kraft pulps, metal-absorbed pulps and recycled pulps((ONP, OCC, MOW, and SC) were treated with the acidic solutions. Among metals in the bleached kraft pulps, Cu, Ca and Mg were removed easily by the acid washing, whereas Fe, Al and Si were not removed. The acid washing also removed distinctly metals from the metal-absorbed pulps. The metals absorbed in pulps reduced the brightness (%, ISO). Especially, Fe was the most detrimental metal. However, the brightness which was decreased by metals was restored to the status quo by the acid washing. The level of metals in recycled pulps was gradually reduced after the first flotation and acid treatment. Hence, the degree of metal removal by the acid washing was mainly dependent upon the kinds of waste pulps and metal ions.

• Journal of Preventive Medicine and Public Health
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• v.37 no.4
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• pp.329-336
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• 2004

Objectives : Iron (Fe) is an essential element in biological processes; however excessive Fe is harmful to human health. Some air pollutants contain a high level of Fe, and the human lung could therefore be over-exposed to Fe through inhaled air pollutants. This study was performed to investigate the role of metal transporters (divalent metal transporter 1, DMT1, and metal transporter protein 1, MTP1) in the lung under the environments of Fe deficiency in the body and Fe over-exposure in the lung. Methods : Rats were fed Fe deficient (FeD, 2-6 mg Fe/kg) or Fe supplemented (FeS, 120 mg Fe/kg) diet for 4 weeks, followed by a single intratracheal instillation of ferrous sulfate at low (10 mg/kg) or high (20 mg/kg) dose. Fe concentration was analyzed in the serum, lung and liver, and histopathological findings were observed in the lung at 24 hours after Fe administration. The level of DMT1 and MTP1 expression in the lung was analyzed by RT-PCR. Also, the effect of Fe deficiency in the body was evaluated on the level of Fe concentration and metal transporters compared to FeS-diet fed rats at the end of 4-week FeD or FeS diet. Results : The 4-week FeD diet in rats induced an Fe deficiency anemia with decreased serum total Fe, increased unsaturated Fe binding capacity and hypochromic microcytic red blood cells. The concentration of Fe in the lung and liver was lower in the FeD-diet fed rats than in the FeS-diet fed rats. The level of metal transporters mRNA expression was higher in the FeD-diet fed rats than in the FeS-diet. The concentration of Fe in the lung was increased in a dose-dependent pattern after intratracheal instillation of Fe into the rats, while the level of Fe in the serum and liver was not increased in the low-dose Fe administered rats. Therefore, DMT1 and MTP1 mRNA was highly expressed in both FeD-diet and FeS-diet fed rats, after intratracheal instillation of Fe. Conclusions : DMT1 and MTP1 mRNA were more highly expressed in FeD-diet fed rats than in FeS-diet fed rats. The over-exposure of Fe intratracheally induced high expression of metal transporters and increased Fe deposition in the lung in both FeD-diet and FeS-diet fed rats, but did not increase the Fe level of the serum and liver in low-dose Fe administered rats. These results suggest that the role of metal transporters in the lung might be different in a part from the duodenum under the environment of over-exposure to Fe.