• Journal of the Korean Society for Precision Engineering
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• v.23 no.10
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• pp.60-67
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• 2006

This paper presents the temperature control in aluminum plate with Peltier module. From the experimental work, Peltier module is used to control the temperature of small aluminum plate for both heating and cooling with the control of current and fan ON/OFF. And current control of Peltier module was accomplished by PWM method. As a result of experiments, it is proper that operate cooling fan only while cooling duration and there exist a proper cooling current to drop temperature rapidly. It takes about 125sec to control temperature of aluminium plate between $30^{\circ}C$ and $70^{\circ}C$ and about 70sec between $40^{\circ}C$ and $60^{\circ}C$, in ambient temperature $28^{\circ}C{\sim}29^{\circ}C$ while cooling fan is operated only cooling duration. With the cooling current, temperature control of aluminum plate was accomplished more rapidly in comparison without cooling current. Future aim is to realize more rapid temperature control and develop SMHA(special metal hydride actuator) by using Peltier module as a heating and cooling source.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.199-204
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• 2006

We manufactured the metal hydrides of $(Ti_{0.88}Mg_{0.12})H_2$ using a very easy and cheap way that Ti-12%Mg blending powder was mechanically milled with liquid milling media such as isopropyl alcohol ($C_3H_8O$, containing oxygen) and hexane ($C_6H_{14}$, no oxygen) as hydrogen source. The $(Ti_{0.88}Mg_{0.12})H_2$ synthesized in isopropyl alcohol contained the high oxygen of 11.2%, while one in hexane had the low oxygen content of 0.7%. Such a difference of oxygen content affected the dehydriding behavior, phase transformation, and microstructural evolution at high temperature, which was investigated through X-ray diffraction and DSC measurements, and electron microscope observations.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.7 no.4
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• pp.715-720
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• 2006

Metalhydrides such as $Cp(CO)_{2}(L)MH$ (L = t-butylisocyanide and 2,6-dimethylphenylisocyanide M = Mo and W) have been synthesized and used for ionic hydrogenation of the carbonyl groups in the presence of triflic acid. When these complexes have also used as catalyst precursors for hydrogenation of 3-pentanone under mild conditions ($23^{\circ}C,\;<4.1\;atm H_{2}$). The turnover rates were very slow, with the fastest initial rate of about 2 turnovers per 1 day for the [$Cp(CO)_{2}(ArNC)Mo][BA_{r}^{F}_{4}$] system.

• Transactions of the Korean hydrogen and new energy society
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• v.10 no.3
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• pp.151-157
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• 1999

The development of hydrogen vehicles has been actively progressed in the developed countries such as U. S., Japan and Germany. The most important technology of using hydrogen fuel is to develope a compatible storage tank with respect to the fossil fuel tank. Among many storage methods, the liquid hydrogen is the most desirable state because of the lowest volume and weight. The metal hydride tank is too heavy and the compressed hydrogen tank is too bulky. Because of these reasons, it is the principal purpose to analyze the theoretical heat transfer for designing and manufacturing an actual $LH_2$ tank. The insulation methods of the room between inner and outer vessel are non-vacuum, vacuum, vacuum with MLI(Multi-Layer Insulation). According to the results of the numerically calculated heat leak through the walls of the $LH_2$ tank, the vacuum insulated tank has 20 times and the MLI tank has 5616 times less heat leak than the non-vacuum tank.

• Transactions of the Korean hydrogen and new energy society
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• v.7 no.2
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• pp.137-145
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• 1996

The Zr-based $AB_2$ type Laves phase hydrogen storage alloys have some promising properties, long cycle life, high discharge capacity, as electrode materials in reversible metal hydride batteries. However, when these alloys are used as negative electrode for battery, there is a problem that their rate capabilities are worse than those of commercialized $AB_5$ type hydrogen storage alloys. In this work, we tried to develop the Zr-based $AB_2$ type Laves phase hydrogen storage alloys which have high capacity and, especially, high rate capability.

• Transactions of the Korean hydrogen and new energy society
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• v.5 no.1
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• pp.1-8
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• 1994

Lattice structure, hydrogen absorption characteristics, discharge capacity and cycle life of $V_{22}Ti_{16}Zr_{16}Ni_{39}X_7$(X= Cr, Co, Fe, Mn, Al) alloys were investigated. The matrix phases of these alloys were the C14 Laves phase. Chromium-containing alloy had a vanadium-rich phase in addition to the Laves phase. The chromium, maganese, or aluminum-containing alloys had lower hydrogen equilibrium pressure and larger hydrogen absorption content than the cobalt or iron-containing alloys. The discharge capacities of these alloys were 270~330mAh/g. The discharge capacity according to the alloying element X decreased in the order of Mn>Cr>Co, Al)Fe. The charge/discharge cycle lives of the chromium, cobalt or iron-containing alloys were longer than those of maganese or aluminum-containing alloys due to the lower vanadium dissolution rate.

• Transactions of the Korean hydrogen and new energy society
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• v.1 no.1
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• pp.1-8
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• 1989

The hydriding kinetic mechanism and the change of the hydriding reaction rate of $MmNi_{4.5}Al_{0.5}$ during the thermally induced hydrogen absorption-desorption cycling are investigated. Comparison of the reaction rate data which are obtained by the pressure sweep method with the theoretical rate equations suggests that the hydriding rate controlling step has changed from the dissociative chemisorption of hydrogen molecules at the surface to the hydrogen diffusion through the hydride phase with the increase of the hydriding fraction. These hydriding kinetic mechanism is not changed during the cycling. However, the intrinsic hydriding reaction rate of $MmNi_{4.5}Al_{0.5}$ after 5500 cycles increases significantly comparing with the activated one. It is suggested that the change of the hydriding kinetic behavior due to intrinsic degradation of $MmNi_{4.5}Al_{0.5}$ can be interpreted as follows ; the formation of nickel cluster at the surface of the sample and the host metal atom exchange in bulk by thermal cycling.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.4
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• pp.458-464
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• 2011

Recently, one of the hydrogen production methods has attracted using dense metallic membrane. It has high hydrogen permeation and selectivity which hardly could adopt industrial product because of high cost, hydrogen embrittlment and thermal stability. Meanwhile, vanadium has high hydrogen solubility and it use to instead of Pd-Ag amorphous membrane. Aluminum carried out blocking hydrogen diffusion on grain boundary therefore protecting hydrogen embrittlement. Most of dense metallic membrane is solution diffusion mechanism. The solution diffusion mechanism was very similar hydrogen storing steps such as steps of metal hydride. Thus, V-Al composites were fabricated to use hydrogen induced mechanical alloying. The fabricated V-Al composites were characterized by XRD, SEM, EDS and simultaneous TG/DSC analyses. The hydrogenation behaviors were evaluated using a Sievert's type automatic PCT apparatus. The hydrogenation behaviors of V-Al composites was evaluated too low hydrogen stored capacity and fast hydrogenation kinetics. In PCI results, V-Al composites had low hydrogen solubility, in spite of that, hydrogen kinetics was calculated very fast and hydrogen absorption/desorption contents were same capacity.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.4
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• pp.495-503
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• 2011

The sealed nickel-metal hydride (Ni-MH) secondary battery are primarily used as energy storage for the HEV. But, the research on Ni-MH battery has focused on anode materials. In the present study, we investigate to improve the electrochemical characteristics of Ni-MH batteries using the surface treatment of $Ni(OH)_2$ cathode by CoOOH. Surface treated $Ni(OH)_2$ cathode showed significant improvement in the activation behavior, rate capability, charge retention, and cycle life of the batteries were significantly improved. In addition, the surface treated electrode exhibited the higher overvoltage for oxygen evolution than the untreated electrode. This phenomenon indicates that the charge efficiency can be improved by suppressing the oxygen evolution on cathode.

• Journal of Korea Foundry Society
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• v.31 no.3
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• pp.145-151
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• 2011

Metallic foam has been known as a functional material which can be used for absorption properties of energy and sound. The unique characteristics of Al foam of mechanical, acoustic, thermal properties depend on density, cell size distribution and cell size, and these characteristics expected to apply industry field. Al-Zn-Mg-Cu alloy foams was fabricated by following process; firstly melting the Al alloy, thickening process of addition of Ca granule to increased of viscosity, foaming process of addition of titanium hydride powder to make the pores, holding in the furnace to form of cooling down to the room temperature. Metal foams with various porosity level were manufactured by change the foaming temperature. Compressive strength of the Al alloy foams was 2 times higher at 88% porosity and 1.2 times higher at 92% porosity than pure Al foams. It's sound and vibration absorption coefficient were higher than pure Al foams and with increasing porosity.