• Title/Summary/Keyword: Metal elements

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Effect of Impurities on Stress Induced Void Formation in Al-1% Si Conductors

  • Lee, Seong-Min
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.3
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    • pp.12-17
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    • 2001
  • It is shown in the present study that during the HTS (hot temperature storage) test, the metal contamination by impure elements can be highly susceptible to the void formation, leading to the open failure of the power line in the memory device. Such a functional failure associated with the metal contamination was investigated to be dominant in the early stages of the HTS test while the formation of a stress-driven void is mainly observed in the later stages. In particular, it was found that the void formed in the contaminated metal takes on a slit-like shape which has been known to be characteristic of the stress-related voiding. The impure elements leading to the metal degradation were identified to be carbon and oxygen introduced during the metal sputtering process. The experimental works show that the device reliability was significantly improved by reducing the level of such impure elements within metal. It is shown in the present study that during the HTS (hot temperature storage) test, the metal contamination by impure elements can be highly susceptible to the void formation, leading to the open failure of the power line in the memory device. Such a functional failure associated with the metal contamination was investigated to be dominant in the early stages of the HTS test while the formation of a stress-driven void is mainly observed in the later stages. In particular, it was found that the void formed in the contaminated metal takes on a slit-like shape which has been known to be characteristic of the stress-related voiding. The impure elements leading to the metal degradation were identified to be carbon and oxygen introduced during the metal sputtering process. The experimental works show that the device reliability was significantly improved by reducing the level of such impure elements within metal.

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A Study of Heavy Metals Contents of the Seaweeds at Various Area in Korea (지역별 해조류의 중금속 함량)

  • Choi, Soon-Nam;Lee, Sang-Up;Chung, Keun-Hee;Ko, Weon-Bae
    • Korean journal of food and cookery science
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    • v.14 no.1
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    • pp.25-32
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    • 1998
  • To measure the contents of several heavy metal elements (Cr, Mn, Ni, Cu, Zn, Cd, Hg, Pb) in Korean seaweeds which are closely related to food resources, various seaweed samples were collected from thirteen to seventeen seaweed-producing districts. The results obtained from the experiment are summarized as follows: 1. The content of heavy metal elements in seaweeds of individual sample ranged from 0.0005 to 25.0373 ppm. Their mean levels were as follows: laver, 0.0024∼3.9297 ppm; sea lettuce, 0.0011∼25.0373 ppm; sea mustard, 0.0005∼23.5071 ppm; sea tangle, 0.0006∼4.8550 ppm. The mean levels of Cd and Pb were specially low in the samples collected from the area II in Kangwon and area Ⅸ in Kyungbook. 2. The mean levels of heavy metal elements of collected samples ranged from 0.0117 to 4.4944 ppm. Laver showed the lowest level of Hg and sea lettuce showed the highest level of Mn. Their mean levels of elements were as follows: laver, 0.0117∼2.3339 ppm; sea lettuce,0.0232∼4.4944 ppm; sea mustard, 0.0129∼1.5139 ppm and sea tangle, 0.0182∼1.7410 ppm. 3. The mean levels of heavy metal elements from several locations ranged from 0.0085 ppm to 8.4148 ppm. The mean levels of heavy metal elements in sea mustard from area V of Kyungbook were the lowest, but the mean levels of heavy metal elements in sea lettuce from area Ⅷ of Kyungnam were the highest. The mean level of heavy metal elements were as follows: laver, 0.3613∼1.1124 ppm; sea lettuce, 0.1415∼8.4148 ppm; sea mustard, 0.0729-3.1182 ppm; sea tangle, 0.0085∼0.7587 ppm. 4. Generally the heavy metal elements were detected in the seaweed samples from all locations. The mean levels of heavy metal elements varied with locations and kinds of samples. The levels of heavy metals of the samples taken from all locations from the East Sea, the South Sea, and the West Sea areas showed 99% safety range.

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Study on the Addition and the Transfer of Alloying Elements in FCAW (FCAW에 의한 합금 성분의 첨가와 이행에 관한 연구)

  • 김경중;박관호
    • Journal of Welding and Joining
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    • v.1 no.2
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    • pp.76-82
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    • 1983
  • The chemical composition of deposit metal by flux cored arc welding can be easily regulated though addition of deoxidizers and alloying elements in cored flux and fluxes of flux coored wire arc analogous to those of coated electrode. It is necessary to investigate the transfer and yield efficiency due to addition of necessary alloy elements in deposit metal. This report is made to intorduce an experimental equation from the relation between welding condition and extent of penetration, deposit metal and weld melt slag and to estimate transfer and yield efficiency of alloy components in fluxes through chemical analysis of deposit metal.

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Analysis of Flux′s Conduct by Bead Welding in SAW (SAW 비드 용접을 통한 Flux 거동 해석)

  • 이재윤;이성호;이보영
    • Proceedings of the KWS Conference
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    • 2003.11a
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    • pp.245-247
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    • 2003
  • Elements of Pure Weld Metal(PWM) is important factor that understand to analyze Flux's conduct in SAW welding. For elements of PWM were got, Pile-up welding over 10 floor have used in the past. But, it take a long time to analyze elements of PWM in this method. Elements of Pure Weld Metal is needed to seize more easily. In this research, Bead welding is used to graps an element of Pure Weld Metal using mathematical formula which get to be derivation.

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Effects of Welding Parameters on Weld Metal Strength and Recovery of Alloying Elements in FCAW (FCAW에서 용접변수에 따른 용접금속 강도 및 와이어 합금원소의 회수율 변화)

  • Jung, Dong-Hee;Bang, Kook-Soo;Park, Chan;Chang, Woong-Sung;Park, Chul-Gyu
    • Journal of Welding and Joining
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    • v.26 no.2
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    • pp.69-74
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    • 2008
  • 590MPa grade weldable steels were gas metal arc welded with flux cored wires. Welding parameters such as current, voltage, and speed were varied independently. Effects of each parameter on the strength and chemical composition of weld metal were investigated. Increase of voltage caused decrease of weld metal tensile strength due to the low recovery of alloying elements such as carbon and manganese. On the contrary, increase of current and speed resulted in increase of weld metal strength because of higher recovery of the alloying elements.

Adsorption Behaviors of Metal Elements onto Illite and Halloysite (일라이트, 할로이사이트에 대한 중금속 원소의 흡착특성)

  • 추창오;김수진;정찬호;김천수
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.1
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    • pp.20-31
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    • 1998
  • Adsorption of metal elements onto illite and halloysite was investigated at $25^{\circ}C$ using pollutant water collected from the gold-bearing metal mine. Incipient solution of pH 3.19 was reacted with clay minerals as a function of time: 10 minute, 30 minute, 1 hour, 12 hour, 24 hour, 1 day, 2 day, 1 week, and 2 week. Twenty-seven cations and six anions from solutions were analyzed by AAs (atomic absorption spectrometer), ICP(induced-coupled plasma), and IC (ion chromatography). Speciation and saturation index of solutions were calculated by WATEQ4F and MINTEQA2 codes, indicating that most of metal ions exist as free ions and that there is little difference in chemical species and relative abundances between initial solution and reacted solutions. The adsorption results showed that the adsorption extent of elements varies depending on mineral types and reaction time. As for illite, adsorption after 1 hour-reaction occurs in the order of As>Pb>Ge>Li>Co, Pb, Cr, Ba>Cs for trace elements and Fe>K>Na>Mn>Al>Ca>Si for major elements, respectively. As for halloysite, adsorption after 1 hour-reaction occurs in the order of Cu>Pb>Li>Ge>Cr>Zn>As>Ba>Ti>Cd>Co for trace elements and Fe>K>Mn>Ca>Al>Na>Si for major elements, respectively. After 2 week-reaction, the adsorption occurs in the order of Cu>As>Zn>Li>Ge>Co>Ti>Ba>Ni>Pb>Cr>Cd>Se for trace elements and Fe>K>Mn>Al, Mg>Ca>Na, Si for major elements, respectively. No significant adsorption as well as selectivity was found for anions. Although halloysite has a 1:1 layer structure, its capacity of adsorption is greater than that of illite with 2:1 structure, probably due to its peculiar mineralogical characteristics. According to FTIR (Fourier transform infrared spectroscopy) results, there was no shift in the OH-stretching bond for illite, but the ν1 bond at 3695 cm-1 for halloysite was found to be stronger. In the viewpoint of adsorption, illite is characterized by an inner-sphere complex, whereas halloysite by an outer-sphere complex, respectively. Initial ion activity and dissociation constant of metal elements are regarded as the main factors that control the adsorption behaviors in a natural system containing multicomponents at the acidic condition.

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The Correlation of Wavelengths with Heavy Metal Elements on the Circadian Rhythm Conidiation in Neurospora crassa (Neurospora crassa의 포자형성 주기에 미치는 빛파장과 중금속 이온의 영향 관계 조사)

  • 한상진
    • Environmental Analysis Health and Toxicology
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    • v.10 no.3_4
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    • pp.7-13
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    • 1995
  • The most periodlengths($\tau$) of conidiation of Neurospora were shortened in the medium with Li$^+$, Rb$^+$, and Cs$^+$ under the blue or green light. The higher the concentration of the heavy metal elements are, the shorter the circadian lengths are. The largest differences between the maxima- and minima circadian lengths showed in the medium with LiCI, RbCl, and CsCI under the blue lights at 150 Lux, while the little differences of circadian lengths presented in 1 mM heavy metal elements at the 270Lux blue light. Li$^+$ under the blue light effected extremely much and in the order of Rb$^+$ and Cs$^+$ on the conidiation of Neurospora. Under the green lights at 270Lux, the smallest changes of the circadian lengths are resulted in the medium with heavy metal elements. The other way at the green light 150Lux, the conidiation is stimulated by lmM LiCI or RbCl for the average 0.71h and 0.29h longer than the periodlength of control 28.34h. The medium with Li$^+$ under the green light has less effect on the conidiation rhythm of Neurospora than with Rb$^+$ or Cs$^+$.

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Effect of Alloying Elements on the Wear Resistance of Austempered Ductile Iron (오스템퍼링 처리한 구상흑연주철(ADI)의 내마모성에 미치는 합금원소의 영향에 관한 연구)

  • Lee, Sang-Hak;Kim, Hong-Beom;Kim, Jong-Chul;Chun, Byung-Wook;Kim, Chang-Gyu;Choi, Chang-Ock
    • Journal of Korea Foundry Society
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    • v.19 no.1
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    • pp.24-32
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    • 1999
  • A series of investigations for Austempered Ductile Iron (ADI) castings were carried out by using the specimens with various chemical compositions and heat treatment conditions. The rolling wear characteristics of alloyed austempered ductile irons under an unlubricated dry rolling condition was evaluated by the Amsler type test with 9.09% sliding ratio. Generally, the wear amount was increased with the austempering temperature and decreased when the hardness of the matrix was higher. The alloying elements also influenced the austempering reaction, the microstructure and the mechanical properties. In this study, the mechanical properties (i.e.) ultimate tensile strength (UTS), hardness, elongation) and the wear resistance are analysed to show the relationship between the alloying elements and the austempering temperatures. Mo, Cu and Ni are alloyed individually or in combination. It has been found that when Cu and Ni alloyed individually to a casting, the wear amount is increased than others with elements alloyed in combination. The amount of rolling wear loss was decreased when Mo was alloyed in cast iron, individually or in combination.

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A Study on the Variation of Elements Loss of Wires and Oxygen Content of Weld Metal in GMAW (GMA용접에서 와이어 탈산원소 손실 및 용접금속 산소 변화 연구)

  • 방국수;장웅성
    • Journal of Welding and Joining
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    • v.16 no.2
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    • pp.93-99
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    • 1998
  • The effects of welding conditions of gas metal arc welding on the elements loss of solid wire, oxygen content and impact toughness of weld metals were studied. Deoxidizing elements loss was increased with increase of arc voltage in both short-circuit transfer mode and globular transfer mode. It is believed that increase of arc voltage results in increase of reaction time between elements in the droplet and surrounding gas at the end of wire and in the arc column. Based on the thermodynamic equilibrium model, the oxygen content of weld metal can be predicted with the content of silicon and manganese as following : [%O] = $K([%Si][%Mn])^{-0.25}$, K = -15518/T+6.01. The equilibrium temperature was dependent on shielding gas, and it was 187$0^{\circ}C$ for $CO_2$ gas and 180$0^{\circ}C$ for 20%$CO_2$-80%Ar gas. The oxygen content of weld metal which shows maximum impact toughness was varied with deoxidizing alloy system of wires, 0.041 wt% for Si-Mn type wire and 0.026 wt% for Si-Mn-Ti type wire.

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Study on Base metal Alloy (Base metal Alloy에 관한 고찰(考察))

  • Sung, Hwan-Kyung
    • Journal of Technologic Dentistry
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    • v.7 no.1
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    • pp.53-59
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    • 1985
  • This paper aims to examine baes metal alloy in all its aspects - the roles of elements, the content of every element according to uses, characters, laboratory technique methods and the kind of artificial base metal alloy registered in A.D.A. Specification. The results are as follows; 1. Base metal alloy is used widely bacaues it is rather cheap, but it should be handled appropriately in operating because its quality is bad. 2. Classifying base metal alloy, it is classified into Co-Cr alloy, Ni-Cr alloy, and Ni-Cr-Co alloy according to element, it is classified into partial denture alloy, surgical alloy and crown & bridge alloy according to use. 3. Among elements of base metal alloy, Bellium lowers the melting point of the alloy and increases the strength, but the amount should be limited when it is used because it destroys the organization of a living body. 4. The investments for base metal alloy are ethyl silcate bonded investment and phosphate bonded investment which endure well at high burn out temperature. 5. A.D.A specification No.14 in Kore contains Niranium, Nobilium, regalloy, Ticonium and Vitallium.

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