• Title/Summary/Keyword: Metal dispersion

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Propagation behaviors of guided waves in graphene platelet reinforced metal foam plates

  • Wubin Shan;Hao Zhong;Nannan Zhang;Guilin She
    • Geomechanics and Engineering
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    • v.35 no.6
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    • pp.637-646
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    • 2023
  • At present, the research on wave propagation in graphene platelet reinforced composite plates focuses on the propagation behavior of bulk waves, in which the effect of boundary condition is ignored, there is no literature report on propagation behaviors of guided waves in graphene platelet reinforced metal foams (GPLRMF) plates. In fact, wave propagation is affected by boundary conditions, so it is necessary to study the propagation characteristics of guided waves. The aim of this paper is to solve this problem. The effective performance of the material was calculated using the mixing law. Equations of motion of GPLRMF plate is derived by using Hamilton's principle. Then, the eigenvalue method is used to obtain the expressions of bending wave, shear wave and longitudinal wave, and the degradation verification is carried out. Finally, the effects of graphene platelets (GPLs) volume fraction, elastic foundation, porosity coefficient, GPLs distribution types and porosity distribution types on the dispersion relations are studied. We find that these factors play an important role in the propagation characteristics and phase velocity of guided waves.

Study on Magnetic Property Enhancement of Metal Powders for Magnetic Tape by Using Ultrasonic Dispersion (자기테이프용 Metal Powder의 초음파 분산에 의한 자기적 특성 향상에 관한 연구)

  • Kim, Chang-Gon;Choe, Hyeon-Seung;Jang, Hak-Jin;Yun, Seok-Yeong;Kim, Tae-Ok
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.972-977
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    • 2001
  • It was investigated the effect of ultrasonic treatment on magnetic property of ultra fine magnetic Fe powders ($\alpha$-Fe) for magnetic tape. The properties were characterized with vibrating sample magnetometer (VSM), particle size analyzer (PSA) and scanning electron microscope (SEM). At 4hours ultrasonic treatment of 70 kHz, magnetic properties such as squareness ratio (S.Q. : 0.8868), orientation ratio (O.R. : 2.45) and switching field distribution (S.F. D. : 0.394) before taping were relatively enhanced. Cumulative particle size distribution of less than 5$\mu\textrm{m}$ fine powder was above 90% below 1 hour leaving time after ultrasonic treatment and it was supposed that ultrasonic treatment prevent aggregation. The magnetic values of S.Q. and S.F.D. of tape manufactured at 70 kHz and 4hour ultrasonic treatment were improved from 0.7747, 0.3818 to 0.8037, 0.3706, respectively. Electro-magnetic property used as in-output signal characteristic was improved, which showed that ultrasonic treatment developed the magnetic properties.

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Propagation of surface polaritons at the interface of metal and left-handed metamaterial (금속과 왼손잡이 메타-물질의 경계면에서 형성되는 표면 폴라리톤의 전파 특성)

  • 윤재웅;송석호;오차환;김필수
    • Korean Journal of Optics and Photonics
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    • v.15 no.2
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    • pp.89-99
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    • 2004
  • At the interface of two materials with frequency-dependent material-parameters of permittivity and permeability, there may exist two kinds of surface polaritons: surface electric-polaritons(SEPs) and surface magnetic-polaritons(SMPs). Possible combinations of the material-parameters to support propagation of the two surface polaritons are suggested at the interface between metals and metamaterials such as a left-handed material. Dispersion relations are also derived in order to characterize frequency dependence of propagation of the SEP and SMP. It is found that only one propagation mode of SEP or SMP is allowed at a given set of four material parameters, and that counter-propagation of the phase and group velocities of the propagation mode can be observed even in the case when there are no double negative(or, negative-index) materials. Physical origin of the counter-propagation of the group velocity is proposed by evaluating the ratio of two electromagnetic-energy densities of a surface polariton propagating along within the two interface media, and it is confirmed by the dispersion relations.

Effect of Pt/Al2O3-based Catalysts on Removal Efficiency of Hydrogen (Pt/Al2O3계 촉매의 특성이 수소제어 활성에 미치는 영향 연구)

  • Won, Jong Min;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.221-229
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    • 2017
  • In this study, a wet impregnation method was applied to catalysts based on the active metal Pt in order to confirm the oxidation characteristics of various commercial alumina supports at room temperature. The catalysts were characterized using XPS, CO-chemisorption, and BET. Various $Pt/Al_2O_3$ catalysts controlled the oxygen species of Pt by the electronegativity of electrons and charges when the catalyst was prepared according to the heat treatment conditions. The reason that the dispersion degree decreases with increasing Pt loading seems to be attributed to HT (Huttig Temperature) of Pt. In addition, the minimum hydrogen concentration that can be controlled at room temperature can control hydrogen from metallic Pt up to 1.0 vol% at over 70.09% in the catalyst.

Dispersion of nanosized noble metals in $TiO_2$ matrix and their photoelectrode properties ($TiO_2$ 매트릭스에 나노사이즈의 귀금속 분산과 광전극 특성)

  • Yoon, Jong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.5
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    • pp.251-255
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    • 2009
  • Nanocomposites based on coupling $TiO_2$ matrix with nanosized noble metals (Pt,Au) particles exhibited promising photoelectrode properties. The $M/TiO_2$ (M=Pt,Au) nanocomposite thin films were deposited on quartz and ITO glass substrates using a co-sputtering method. $TiO_2$ in rutile form is the dominant crystalline phase for as-deposited nanocomposite films. Along with heat treatment up to $600^{\circ}C$, XRD peaks of the rutile phase as well as those of noble metal increased in intensity and decreased in width, indicating the growth of crystallites. The anodic photocurrents of $M/TiO_2$ (M=Au,Pt) thin films were observed not only in the UV range but also in the visible light range. The photocurrent of the nanocomnosite films extended to the visible light region by dispersion of nano-sized noble metal in the $TiO_2$ matrix.

Effect of NBR Component on Adhesion Behaviors between NBR and Metal Joints Using Phenol Adhesive (페놀 수지를 이용한 NBR/냉연강판 접착계에 미치는 NBR 조성의 효과)

  • Lee, Dong-Won;Park, Hae-Youn;Yu, Young-Jae;Kang, Dong-Gug;Seo, Kwan-Ho
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.1-6
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    • 2008
  • The adhesion behaviors and processability of NBR as a sealing material were investigated. In order to find the optimum formulation, the adhesive properties and processability were observed as the change of the contents of acrylonitrile (ACN) in NBR. Effects of Mooney viscosity, filler, plasticizer and crosslinking agent on the adhesion behaviors were also studied. The contents of ACN in NBR have great effects on adhesion behaviors and processability in NBR sealing. To know the optimum condition of roll mixing, degree of dispersion was investigated. It was confirmed that degree of dispersion was influenced by various factors such as mixing order, time, and temperature. The crosslinking system was studied as the observation of sulfur system, peroxide system, crosslinking density, and structure. From the variation of the dry condition and hexamine contents, the relation between adhesive and NBR was studied. These results show the adhesion properties and processability are dependent on the contents of ACN and crosslinking system.

Characteristic Evaluation of the Fe-Al Alloy Preform Fabrication by Reactive Sintering Process for the Al Matrix Composites. (반응소결법으로 제조한 Al기 복합재용 Fe-Al합금 예비성형체의 특성평가)

  • Choi, Dap-Chon;Park, Sung-Hyuk;Joo, Hyung-Gon
    • Journal of Korea Foundry Society
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    • v.19 no.6
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    • pp.493-500
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    • 1999
  • Squeeze casting was used for fabricating a light metal base composite having high strength and wearresistance. Reactive sintering was used to prepare the preform of Squeeze casting. To utilize Fe-Al intermetallic compounds and SiC particle as a reinforcement, there needs to prepare Fe-Al mixed powder at 50, 60, 70at.%Al, and add SiC powder to the above mixture at 4, 7, 16, 24wt.%. The prepared mixture with SiC was reactive sintered in a tube furnace at $660^{\circ}C$ to get a porous hybrid preform of intermetallic compound and SiC. The preform prepared above was placed in a metal mold, preheated at $660^{\circ}C$ AC4C matrix was injected into the mold with the temperature of the melt at $610^{\circ}C$ After these processes, 66MPa was applied to the mold for 5 minute to finish the whole procedure. The maximum reaction temperature was increased with the increased Al amount, but decreased with the increased SiC amount. The density of the preform was decreased with SiC amount increase in the compacts due to swelling of the preform. An optical microscope was applied to observe the micro structure and the dispersion of the reinforcements. To analyze phases, We utilized XRD, EDS. Hardness test were chosen to get the information of mechanical properties. There were no significant changes in micro structure between the composite and preform. However, it was shown that uniform dispersion of the reinforcers and complete infiltration of the melt into the preform were achieved through the procedure of the squeeze casting. It was observed that the hardness of the composite is decreased with increased SiC amount, resulting from the volumetric expansion of the preform.

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The Effect of Calcination Temperature of RuTi Catalysts on the Reaction Activity of NH3-SCO (RuTi 촉매의 소성온도가 NH3-SCO 반응활성에 미치는 영향)

  • Shin, Jung Hun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.200-207
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    • 2020
  • In this study, the effect of calcination temperature on the production of RuTi catalyst in NH3-SCO (selective catalytic oxidation) was investigated. The RuTi catalyst was prepared using the wet impregnation method, and calcined at 400~600 ℃ for 4 h in air condition. The catalysts were named RuTi x00 where x00 means the calcination temperature. According to XRD (X-Ray diffraction), TEM (transmission electron microscope), H2-TPR (H2-temperature programmed reduction) analyses, RuTi x00 catalysts displayed that the dispersion of active metal decreased via increasing the calcination temperature. The catalysts with low dispersion showed a decrease in the surface adsorption oxygen species (Oβ) and NH3 adsorption amount via XPS, and NH3-TPD analyses. Therefore, the RuTi 400 catalyst was well dispersed in the active metal on TiO2 surface, and also, the NH3 removal efficiency was excellent.

Effect of Physico-chemical Properties of Pt/TiO2 Catalyst on CO Oxidation at Room Temperature (Pt/TiO2 촉매의 물리화학적 특성이 CO 상온산화 반응에 미치는 영향 연구)

  • Kim, Sung Chul;Kim, Geo Jong;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.657-662
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    • 2018
  • In this study, the effect of $Pt/TiO_2$ catalysts on the CO oxidation reaction at room temperature was investigated using various $TiO_2$ supports with different physical properties to compare and evaluate $Pt/TiO_2$ catalysts. Physicochemical properties of the catalyst were alanyzed using XPS, CO-chemisorption, BET, and CO-TPD. As a result, when the active particle diameter was smaller, while the metal dispersion and surface area were larger, the CO room temperature oxidation reaction was better. These physical properties increased the number of active sites, causing the target material to increase the adsorption amount of CO. In addition, when the $O_2$-consumption increased, the CO-room temperature oxidation reaction activity increased due to the excellent oxygen-transferring ability.

High-Performance Plasmon Bio-Sensor with Grating Profile based on Metallic Layer (금속층에 기반한 격자구조형 고성능 플라즈마 바이오센서)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.22 no.3
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    • pp.145-150
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    • 2022
  • An analytical model based on a modal transmission-line theory (MTLT) is developed to investigate the optical transmission through metal gratings. This model gives well physical meanings for the transmission as well as for the dispersion relations of the modes responsible for high transmission. These concepts provide accurate information even for real metals used in the visible~near-infrared wavelength range, where surface plasmon polaritons (SPP's) are excited. Furthermore, the dispersion relations allow the nature of the propagation modes to be assessed. The propagation modes are hybrid between Fabry-Pérot like modes and SPP's. It is important to consider different period and aspect ratio of metal gratings in order to determine the nature of the hybrid modes. In this paper, the sensing characteristics and mode propagation phenomena of high-performance plasma bio-sensors that depend on these variables were clearly analyzed.