• 제목/요약/키워드: Metal contamination

검색결과 692건 처리시간 0.025초

경기북부 산업단지 주변 농지의 토양오염도 조사연구 (A Study on Soil Contamination Investigation of Farmland Around Industrial Areas in Northern Gyeonggi Province)

  • 박진호;권경안;정은희;김재광;김지영;오조교
    • 한국환경보건학회지
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    • 제43권5호
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    • pp.393-400
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    • 2017
  • This study was investigated on pH, heavy metals, oils and solvents in 34 surface soil samples and the samples are collected at two times for 17 farmland sites around 7 industrial areas in Northern Gyeonggi Province. As a result of pH for soil contamination monitoring network, the range of pH showed 4.4~8.4 and average was 6.3. The range of pH for Agricultural land around industrial area was 6.7~7.5 and average indicated 7.1 that mostly showed neutral condition in this area. he average concentrations of Cu, Pb, Ni, As and $Cr^{6+}$ are lower than Korea soil contamination worrisome levels at region 1 and the mean levels of farmland from the soil quality monitoring network. The average concentrations of Zn, Cd and Hg didn't exceed the soil contamination worrisome levels at region 1 but slightly higher than the mean levels of farmland from the soil quality monitoring network. The heavy metal levels of all samples are within Korea soil contamination worrisome levels at region 1. The results showed that the detected heavy metal concentrations ranged from N.D. to ~32.7% of Korea soil contamination worrisome levels at region 1. BTEX, TPH, TCE and PCE were not detected in all samples and thus the farmland around the industrial areas were free from oils and solvents contamination.

추출방법에 따른 금속광산 주변의 토양오염 특성 (Soil Pollution Characteristics of Metallic Mine Area according to Extraction Methods)

  • 양중석;이주영;박영태;백기태;최재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제15권3호
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    • pp.1-6
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    • 2010
  • This study investigated the change of metal contamination levels according to amendment of enforcement regulation of the Soil Environmental Conservation Act in Korea. As an analytical result of 87 samples in abandoned metallic mine area, the extracted amount of As, Pb and Cu with aqua regia was 4.3~29.6 times higher than that with hydrochloric acid extraction and the number of samples, which contamination levels were found to exceed soil contamination standards, was also increased. On the other hand, in case of Cd, Zn, and Ni, the number of samples, which contamination levels were found to exceed soil contamination standards, was decreased or similar. These results can be used as a preliminary material in comparison between the soil pollution data accumulated previously and the data obtained by the revised standard method for the examination of soil pollution.

새만금지역 갯벌 환경(패류, 저질)에서의 중금속 분포특성 (Heavy Metals in Sediments and Burrowing Bivalves (Sinonovacula constricta Lamarck) from Tidal Flats along the Saemankeum Area, Korea)

  • 황갑수;신형선;김강주;여성구;박성민;임규재
    • 한국물환경학회지
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    • 제18권4호
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    • pp.341-354
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    • 2002
  • Heavy metal concentration/distribution in sediments and bivalves from the tidal flats in Saemankeum coastal area, western Korea, were investigated, Among 6 sampling sites, S2, S5 and S6 showed the higher levels of Zn, Cr, Ni, Cu and Cd contamination and S1 did the higher level of Pb contamination than other sites, while S-4 showed the lowest levels of these metal contamination. Overally, the levels of Zn, Cu and Pb concentrations in Sinonovacula constricta were estimated to be relatively high. The shell lengths of the collected mussels were linearly related to their dry weights of the whole soft parts, but the mussels collected from S3 were in a poor nutrition, resulting in the distinctively high levels of metal concentrations in the body. It was shown that in S. constricta, Cr, Ni, Cu and Zn are distributed equally into the whole soft parts or a little more into the flesh, after absorption, while Fe, Cd, Pb and Mn are transferred more into the non-flesh parts than into the flesh parts. In S. constricta, the heavy metal concentrations in the flesh increase with those in the whole soft parts. The bioaccumulation factors(heavy metal concentration in S. constricta/heavy metal concentration in sediment) showed that, of the examined metals, Cd is the most cumulative in the body of S. constricta, followed by Zn and Cu, while Mn, Cr, Ni and Pb are not cumulative.

용탕청정기능을 부여한 고품질 다이캐스팅 기술의 개발 (Development of High Quality Die Casting Technology with Function to Purify Molten Metal)

  • 파다야지지;고목박기;도원삼차
    • 한국주조공학회지
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    • 제24권1호
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    • pp.3-9
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    • 2004
  • Die casting is "a process in which molten metal is injected at high velocity and pressure into a mold(die) cavity". Casting with smooth surfaces, high dimensional precision, complicated shapes, and reduced weight can be obtained using this process. But this process is susceptible to casting defects such as porosities, scattered chilled layers, hard spots, etc. For preventing casting defects, we developed "low-velocity high pressure die casting technology", "squeeze die casting technology", "heat insulating sleeve lubricant technology", and "direct pouring technology". The "direct pouring technology" is useful for producing molten metal without oxide contamination. It consists of a pumping system which supplies pure molten metal to the die casting machine. By using this technology, we have successfully reduced oxide contamination in castings to 1/20 of that of our previous castings.

하수처리수의 농업용수 재이용이 토양 및 작물의 중금속 함량에 미치는 영향 분석 (Impact of Reclaimed Wastewater Irrigation on Heavy Metal Contamination in Soil and Vegetables)

  • 김학관;장태일;이은정;박승우
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2008년도 학술발표회 논문집
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    • pp.827-831
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    • 2008
  • In this study, the effects of reclaimed wastewater irrigation on the concentration of heavy metals such as lead, zinc, cadmium, and copper in soil and vegetables were investigated by monitoring an experimental area irrigated with reclaimed wastewater. Three treatments and three replications on $10{\times}2$-m plots were installed and heavy metal concentrations in soil and vegetables were monitored from 2005 to 2007. The treatments applied in this study were groundwater irrigation (control treatment), wastewater irrigation, and irrigation with filtered reclaimed wastewater treated with ultraviolet light. The monitored results showed that the concentrations of Cu, Cd, and Pb in soil during the experimental period were lower than initial soil levels before irrigation, whereas Zn increased in all treatment plots. However, the ranges of Zn, Cu, Cd and Pb in soil were below the soil pollution standards in the Republic of Korea. Heavy metal concentrations in vegetables showed insignificant variations for all treatments.

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폐금속 광산의 유형별 오염특성에 관한 연구 (Study on the Contamination Characteristics of Pollutants at Various type of Abandoned Metal Mines)

  • 이종득;김태동;김선구;김휘중
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권3호
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    • pp.93-108
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    • 2013
  • This study is aimed to prepare the effective detail survey methods(Phase II) of abandoned metal mines through the contamination assessment for mine types and facilities in the abandoned metal mine areas. The study sites of 12 abandoned mines are located in Gyeonggi-do and Gangwon-do and those were chosen among 310 sites that the Phase II survey was conducted from 2007 to 2009 after considering the results of Phase I for abandoned mines scattered all over the country. 12 study sites were classified into four types; Type I sites only have pit mouth. Type II sites have pit mouth and mine-waste field. Type III sites have pit mouth and tailing sorting field. Type IV sites have pit mouth, tailing sorting field and concentrator(s). In forest land, paddy soil and farm land of Type I, As and Cd were showed average concentration, and Cu and Pb were high on the pit mouth area in one mines where the pit mouth was developed within 500 m. In the mines of Type II, Cu and Pb were showed average concentration too, but As and Cd were slightly high in pit mouth and mine-waste field. The mines of Type III which had grinding particle process through physical separation milling or hitting showed similar tendency with Type II. However, mines of Type IV pit mouth, mine-waste field and showed various results depending on defining the contamination sources. For example, if contamination source was pit mouth, the mixed results of Type I, II, II were showed. In tailing sorting field which was regarded as the most important source and having high mobility, however, if there were no facilities or it was difficult to access directly, field sampling was missed occasionally during phase I and phase II survey. For that reason, the assessment for tailing sorting field is missed and it leads to completely different results. In the areas of Type I mines, the concentration of heavy metals exceeded precautionary standards of soil contamination or not within 1,000 meters of pit mouth. Nickel(Ni) was the largest factor of the heavy metal contamination in this type. The heavy metals except Arsenic(As) were shown high levels of concentration in Type II areas, where pit mouth and mine-waste field were operated for making powder in upriver region; therefore, to the areas in the vicinity of midstream and downstream, the high content of heavy metals were shown. The tendency of high level of heavy metals and toxic materials contained in flotation agent used during sorting process were found in soil around sorting and tailing field. In the abandoned-pit-mouth area, drygrinding area and tailing sorting field area, the content of Cupper(Cu) and Zinc(Zn) were higher than other areas. Also, the contaminated area were larger than mine reclamation area(2,000 m) and the location of tailing sorting field was one of the important factors to estimate contaminated area.

토양특성별 중금속 유효도와 토양오염 평가방법의 개선점 (Availability of Heavy Metals in Soils with Different Characteristics and Controversial Points for Analytical Methods of Soil Contamination in Korea)

  • 정구복;김원일;이종식;신중두;김진호;윤순강
    • 한국환경농학회지
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    • 제24권2호
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    • pp.106-116
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    • 2005
  • This experiment was conducted to investigate available extraction capacity and potential mobility of heavy metal according to the distribution property and contamination level of heavy metals in soils and to suggest a reform measure of soil environment assessment methodology applied with soil quality and the official soil heavy metal test methods in domestic and foreign countries. The soils were collected from the natural forest paddy with long-term application of same type fertilizer, and paddies near metal mine and industrial complex. The post-treatment methods of soil were partial extraction, acid digestion and sequential extraction methods. For the heavy metal contents with different soil properties, it was shown that their natural forest and paddy soil were slightly low and similar to the general paddy soil, while their paddies near metal mine and industrial complex were higher than the standard level of Soil Environment Protection Act. Heavy metal concentrations in the soils with different soil properties had difference between $HNO_3\;and\;HNO_3+HCl$ extractant by US-EPA 3051a method. There were highly significant positive relationships in both two methods. It was appeared that the higher extractable concentration ratio with 0.1N-HCl to total heavy metal content with $HNO_3+HCl$ extractant the greater total heavy metal content. There were highly significant positive correlationship between total heavy metal content and extractable content with 0.1N-HCl. For extractable capacity of soil extractable solution compared to the total heavy metal content it was appeared that it extractable method with 0.1N-HCl was higher than those with EDTA and DTPA. In extractable ratio with 0.1N-HCl in the contaminated paddy soils near mine and industrial complex, it was shown that the lower soil pH, the higher total heavy metal content. The order of a potential mobility coefficient by distribution of heavy metal content with ie different typies in the soil was Cd>Ni>Zn>Cu>Pb. It could be known that contamination characteristics of heavy metals with different types of soils were affected by different heavy metal components, contamination degree and soil chemical properties, and heavy metal concentration with different extractable methods had great variations with adjacent environment. To be compared with assessment methodology of soil environment impact at domestic and foreign countries with our results, it might be considered that there was necessary to make a single analysis method based on total heavy metal content with environmental overloading concept because of various analysis methods for total heavy metal content and present analysis method with great variation according to soil environment. In spite of showing higher concentration of heavy metal with acidic digestion than the extractable method, it might be considered that there is need to be adjusted the national standard of soil heavy metal contamination.

수도권 매립지 주변 하천의 독성물질 오염실태 조사 (The Survey about Toxic Material Contamination at the Streamwater around the Sudokwon Kandfill Area)

  • 강창민;이인현;장원
    • 한국환경과학회지
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    • 제7권4호
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    • pp.565-572
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    • 1998
  • This study estimate the degree of contamination in the streamwater around the Sudokwon landfill site. It was sampled at 10 sites in Jan., Apr., Jul. and Oct., 1996. There were analyzed five kinds of toxic chemical material-CN, AES, PCB, As, Org-p, and four kinds of heavy metal-Pb, Hg, Cd, $C^{+6}$ The result are 1)The COD was generally increased to compare before landfall, 2) The Org-P and PCB were not detected at all points, 3) The concentrations of Pb, $C^{+6}$ and As were lower than the environmental criteria values, 4) The CN, Hg and Cd were over envirommental criteria values. and so emergent regulation is needed, 5) The effects of the streamwater contamination were not only the leachate of the landfall, but also the small factories and agricultural land around the landfill.

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폐광산지역의 오염특성 조사와 평가를 위한 지구화학적 접근방법 (Geochemical Approaches for Investigation and Assessment of Heavy Metal Contamination in Abandoned Mine Sites)

  • 이평구;조호영;염승준
    • 자원환경지질
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    • 제37권1호
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    • pp.35-48
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    • 2004
  • 본 논문에서는 폐광산지역의 오염특성 조사와 평가를 위한 지구화학적 접근방법에 대하여 정리ㆍ기술하였다. 폐광산지역의 주요 오염원은 갱내수, 광석, 광미 및 선광을 위해 사용한 화학약품 등이고 산성광산배수의 배출, 광산폐기물의 유실, 유해성 침출수의 배출, 광미와 분진의 분산 등에 의해 중금속이 이동/확산되어 주변토양, 퇴적물, 지표수, 지하수, 생태계에 광역적/지속적으로 심각한 영향을 미친다. 따라서 오염원, 주변 토양, 지표수, 지하수 등에 대한 화학분석, 광물학적분석, 광산산성배수 예측실험, 물리/지화학탐사와 같은 현장실험 등의 방법을 이용한 조사를 통해 폐광산이 주변 환경에 미치는 잠재적이고 실제적인 영향이 조사$.$평가 되어야한다.