• Title/Summary/Keyword: Metal alloy

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Development of Nitric Acid Free Desmut Solution for the Aluminum Alloy in Alkaline Etching and Acid Desmut Processes (Aluminum 합금소재의 알칼리에칭 공정으로 발생한 Smut 제거를 위한 무질산 혼합산용액 개발)

  • Choo, Soo-Tae;Choi, Sang Kyo
    • Clean Technology
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    • v.9 no.2
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    • pp.57-61
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    • 2003
  • A novel nitric acid-free desmut solution has been developed to remove smut, which is produced from a NaOH etching, on the surface of aluminum alloy metal in metal surface treatment processes. Comparing with the performance of 5% $HNO_3$ desmut solution, the mixed acid solution containing 2% $H_2O_2$, 0.5% HF, and 10% $H_2SO_4$ shows the same effect of smut removal for aluminum alloy samples of A16061 and A15052. To examine the surface alterations of the aluminum samples, in addition, the surface analysis is carried out with scanning electron microscopy (SEM) and electron probe microanalysis (EPMA).

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Stabilization of Thermo Electromotive Force of Power Type Shunt Resistor for Mass Storage Secondary Battery Management System (대용량 이차전지 관리 시스템용 전력형 션트저항의 열기전력 안정화)

  • Kim, Eun Min;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.6
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    • pp.376-380
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    • 2017
  • In this paper, we prepared a metal alloy resistor with stable thermal electro motive force (thermal EMF) as well as a low temperature coefficient of resistance (TCR) by adjusting the manganese proportion from 3 to 12 wt% in the Cu-Mn-Ni alloy. Composition of the fabricated metal alloy was investigated using energy dispersive X-ray (EDX) analysis. The TCR of each sample was measured as 44.56, 40.54, 35.60, and 31.56 ppm for Cu-3Mn-2Ni, Cu-5Mn-2Ni, Cu-10Mn-2Ni, and Cu-12Mn-2Ni, respectively. All the resistor samples were available for the F grade (${\pm}1%$ of the allowable error of resistance) high-precision resistor. All the samples satisfied the baseline of high thermal EMF (under 3 mV at $60^{\circ}C$); however, Cu-3Mn-2Ni and Cu-5Mn-2Ni satisfied the baseline of low thermal EMF (under 0.3 mV at $25^{\circ}C$). We were thus able to design and fabricate the metal alloy resistor of Cu-3Mn-2Ni and Cu-5Mn-2Ni to have low TCR and stable thermal EMF at the same time.

A study on the fitness of the margin to recast with a Ni-Cr alloy for full cast crown (전부주조관용 Ni-Cr 합금 재주조에 따른 변연의 적합도에 대한 연구)

  • Moon, Hee-Kyung
    • Journal of Technologic Dentistry
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    • v.31 no.1
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    • pp.17-21
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    • 2009
  • This experimental study was to determine the fitness on each cervical margin of recast using crown base metal alloy. The alloy used in this experimental study was a Ni-Cr alloy(Wirolloy, Bego, Germany) for the fabrication of full cast crown prosthesis. Twenty-five copings were divided into the five groups. And the group A, B, C, D and E were cording successively according to the frequency of recast to five times. Each specimen was recasted without adding new metal. The experimental results were as follows: 1. The group A and B showed good fitness had subtle differences in each cervical margin adaptation, in other words, the mesio and disto cervical margin showed worse adaptation than the bucco and linguo cervical margin. 2. The group C got good fitness in bucco and linguo cervical margins, but the mesio and disto cervical margin showed inaccurate fitness. And I could not get good casting bodies without adding new metal. 3. The group D and E showed bad fitness for each cervical margin. Therefore the group D and E lost its function as a dental restoration.

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Hot Cracking Susceptibility in Welds of High Strength Al Alloys by Using DCSP-GTAW (DCSP-GTAW에 의한 고력 Al합금의 고온균열감수성에 대한 연구)

  • Ha Ryeo-Sun;Jung Byong-Ho;Park Hwa-Soon
    • Journal of Welding and Joining
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    • v.22 no.5
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    • pp.65-72
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    • 2004
  • The tendency and degree of hot cracking of high strength 5083, 6N01 and 7N01 Al alloy welds by using DCSP-GTAW through modified Varestraint test and autogenous butt welding were investigated. In hot cracking test, 6N01 alloy showed the highest susceptibility to hot cracking in the weld metal and HAZ. Cracking susceptibilities generally increased with increase of solidification temperature range of the base metal and bead penetration-to-width ratio of the weld metal. The cracks in welds of the alloys vertically formed to solid-liquid interface and propagated along with columnar grain boundaries. The fracture facets of cracks showed the typical morphology of solidification crack observed as dendritic structures. Especially, in 6N01 alloy, liquation cracks which were due to elements of Si, Fe and Mg also observed in HAZ near fusion boundary. In butt welding of different Al alloys, the bead crack was mainly occurred in the welds of 6N01, 7N01 and other Al alloys together with 6N01 or 7N01. In the butt welds of 7N01, it was found that the component of Cu had an effect on the higher susceptibility to the hot cracking.

The effect of ultrasonic nano crystal surface modification for mitigation of the residual stress after weld inlay on the alloy 82/182 dissimilar metal welds of reactor vessel in/outlet nozzles (원자로 입출구 노즐 Alloy 82/182 이종금속 용접부 Weld Inlay 적용 후 초음파나노표면개질이 잔류응력 완화에 미치는 영향)

  • Cho, Hong Seok;Park, Ik Keun;Jung, Kwang Woon
    • Journal of Welding and Joining
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    • v.33 no.2
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    • pp.40-46
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    • 2015
  • This study was performed to investigate the effect of ultrasonic nano crystal surface modification (UNSM) on residual stress mitigation after Weld Inlay repair for butt dissimilar metal weld with Alloy 82/182 in reactor vessel In/Outlet nozzle. As-welded and Weld Inlay specimens were made in accordance with design standard of ASME Code Case N-766, and two planes of their weld specimens were peened by the optimum UNSM process condition. Peening characteristics for weld specimens after UNSM treatment were evaluated by surface roughness and Vickers hardness test. And, residual stress for weld specimens developed from before and after UNSM treatment was measured and evaluated by instrumented indentation technique. Consequently, it was revealed that the mitigation of residual stress in weld metal after Weld Inlay repair of reactor vessel In/Outlet nozzle could be possible through UNSM treatment.

Mechanical and Electrochemical Characteristics of Welding Parts Surface for Friction Stir Welded 5456-H116 Al Alloy (마찰교반용접한 5456-H116 알루미늄 합금 용접부 표면의 기계적 및 전기화학적 특성)

  • Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.41 no.4
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    • pp.156-162
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    • 2008
  • Small FRP(fiber-reinforced polymer) fishing ships have numerous problems with the point of the environmental and recycling perspectives. In light of these aspects, aluminum can be used as a material for ship building. It is environmental friendly, easy to recycle, and provides a high added value to fishing boats. In this paper, we report on mechanical and electrochemical characteristics of welding parts for friction stir welded 5456-H116 Al alloy. In friction stir welded at various traveling speeds under the rotation speed of 500 RPM, the best characteristics presented in traveling speed of 15mm/min. The anodic polarizations of base metal and welding metal were observed tendency which current density from the open circuit potential suddenly increase. The cathodic polarization presented concentrated polarization caused by the dissolved oxygen reduction reaction and activation polarization caused by hydrogen generation. From result of Tafel analysis, the corrosion potential of 5456 alloy(Base metal) was lower than that of friction stir welded part, as were its corrosion current densities.

The strain measurement on the aluminum alloy welded transition joint (알루미늄 合金 異材熔接部의 變形率測定)

  • 옹장우;전제춘;오상진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.5
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    • pp.625-634
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    • 1986
  • The strain distribution on a welded aluminum alloy transition joint produced by a static tensile load has been measured using a moire method combined with photoelastic coating method. The test specimens were made of aluminum alloy 6061-T6 and 2014-T6 butt welded with ER-4043 filler metal, and were post welded heat treated (solid solution heat treatment 502.deg. C 70min.) and precipitated (artificial aging 171.deg. C 600min.) to cause an abrupt change of mechanical properties between the base metals and weld metal. The photoelastic epoxy rubber was cemented on the specimen grating which had been reproduced on the specimen surface by using an electropolishing. The measurements were compared with strains computed by Finite Element Analysis. The following results were abtained. (1) The maximum strain were distributed along the center line in the transverse directiion of the weld metal. (2) The strain gradient along the fusion line increased approaching the V-groove tip and the maximum value was observed at a quarter of width from the V-groove tip. (3) The moire method combined with photoelastic coating was proved very useful for real time strain measurement in the welded aluminum alloy transition joint.

Formation of Thicker Hard Alloy Layer on Surface of Aluminum Alloy by PTA Overlaying with Metal Powder (알루미늄 합금의 표면경화)

  • Lee, Young-Ho
    • Proceedings of the KWS Conference
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    • 1996.10a
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    • pp.3-15
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    • 1996
  • The formation of a thicker hard alloyed layer have been investigated on the surface of aluminum cast alloy (AC2B) by PTA overlaying process with Cr, Cu and Ni motel powders under the condition of overlaying current 125-200A. overlaying speed 150 mm/min and different powder feeding rate 5-20 g/min. In addition the characteristics of hardening and wear resistance of alloyed layer here been examined in relation to the microstructure of alloyed layer. Main results obtained were summarized as follows: 1) There was an optimum overlaying condition to get a good alloyed layer with smooth surface. This good layer became easy to be formed as increasing overlaying current and decreasing powder feeding rate under a constant overlaying speed. 2) Cu powder was the most superior one in metal powders used due to a wide optimum overlaying condition range, uniform hardness distribution of Hv250-350, good oar resistance and freedom from cracking in alloyed layer with fine hyper-eutectic structure. 3) On the contrary, irregular hardness distribution was usually obtained in Cr ar Ni alloyed layers of which hardness was increased as Cr or Ni contents and reached to maximum hardness of about Hv400-850 at about 60wt%cr or 40wt%Ni in alloyed layer. 4) Cracking occurred in Cr or Ni alloyed layers with higher hardness than Hv250-300 at mere than 20-25wt% of Cr or Ni contents in alloyed layer. Porosity was observed in all alloyed layers but decreased by usage of spherical powder with smooth surface.

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Effect of In on Surface Behaviors of Porcelain-Metal Boundary in Low Gold Porcelain Alloys (도재소부용 저금함유금합금에서 도재계면의 표면거동에 미치는 미량원소 In의 영향)

  • Nam, S.Y.;Lee, K.D.
    • Journal of Technologic Dentistry
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    • v.21 no.1
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    • pp.15-26
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    • 1999
  • This study was carried out by observing to composition of oxide on the surface of dental porcelain low gold alloy with various Indium additions according to the degassing and analysing the change composition of additional elements In on diffusion behaviors of Porcelain-matal surface. The specimens used were Au-Pd-Ag alloys by small indium addition. These specimens were treated for 10min at $1000^{\circ}C$ in vacuum condition. To investigate the microsturcture of oxidized alloy surface, SEM and EDAX were used, and EPMA were used to investigate the diffusion behaviors of porcelain-metal surface. X-ray diffraction were used to observe the morphological changes in the oxidation zone. The results of this study were obtained as follows ; 1) The hardness of alloy increased with increasing amount of In addition. 2) The formation of oxidation increased with increasing In content after heat treatment. 3) Diffusion of indium elements increased with increasing In content in metal-porcelain surface after firing. 4) The oxidations of alloy surface were mainly $In_2O_3$.

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Modification Behavior of Eutectic Si with Varying Heat Treatment Conditions in A356 Alloy with Al2Ca (Al2Ca를 함유한 A356 합금에서의 다양한 열처리 조건에 따른 공정 Si 개량화 거동)

  • Kim, Se-Jun;Hyun, Soong-Keun;Kim, Shae K.;Yoon, Young-Ok
    • Journal of Korea Foundry Society
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    • v.34 no.5
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    • pp.156-161
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    • 2014
  • This study is focused on the effect of $Al_2Ca$ as a modifier on eutectic Si modification of A356 alloy. Microstructural observation was carried out for as-cast, as-solution treated and as-aged samples. Solution treatment and aging were performed for 2, 4, 6 and 10 hrs at $540^{\circ}C$ and $170^{\circ}C$, respectively. Although A356 alloy, which $Al_2Ca$ was added, has no significant difference in as-cast phases with normal A356 alloys, it shows much more modified eutectic Si, grain refinement and improved tensile property both in as-cast and as-heat treated conditions. TGA result shows that $Al_2Ca$ added A356 alloy has a certain improvement in oxidation resistance.