• Rapid Communication in Photoscience
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• v.3 no.3
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• pp.42-47
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• 2014

Development of molecular and supramolecular systems showing efficient photoinduced energy or electron transfer are of current research interest due to their applications in various chemical and biological processes. Various polypyridine metal complexes including Ru(II), Ru(III), Os(II), Pt(II), Fe(II), Re(I), Ir(III) and so on as a metal center introduce for expanding some more understanding of molecular-scale photoelectronics. Their complexes are concisely classified by the types of relay ligands as follows; (a) metal-direct ligand-metal system; dinuclear or trinuclear systems, (b) metal-nonconjugated ligand-metal system and metal-nonconjugated ligand system having flexible/rigid ligand, (c) metal-conjugated ligand-metal system, and (d) conjugated ligand-metal-conjugated ligand system and metal-self assembly ligand-metal system. It is pointed out that the role played by the relay ligands is important in constructing the metal complexes.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.10 no.1
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• pp.65-70
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• 2001

The hear transfer mechanism initiating the friction welding is examined and a transient three dimensional heat conduc-tion model for the welding of two dissimilar cylindrical metal bars is investigated. The cylindrical metal bars are made of materials made of A2024 and SM 45C. Numerical simulations of heat flow are performed using the finite volume method. Respectively. Commercial FLUENT code is used in the heat flow simulation and maximum temperature and distribution of temperature are calculated. Temperature of friction welded joining face is compared with the temperature distribution measured by experiment and numerical simulation. The maximum temperature of friction welded joining face is lower than melting point of A2024-T6 aluminum alloy using insert metal. The temperature distribution of friction welded join- ing face with insert metal is more uniform than that of without inset metal.

• Journal of Welding and Joining
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• v.15 no.2
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• pp.72-80
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• 1997

The spatter generation rate of GMA welding with $CO_2$ gas shielding was measured with the change of welding conditions such as wire feeding rate and welding voltage and then the results were analized with the accompanying changes in metal transfer mode and in bead geometry. The spatter generation rate (SGR) was relatively low not only wit the short circuit transfer but with the truely globular transfer mode. However, the SGR resulted with the mixed mode were consistantly high. The resultant wave pattern of mixed mode was due to the coexistance of short-circuit and globular transfer and characterized by the frequent appearance of instantaneous short circuit. Considering the result of SGR and that of bead geometry, it could be concluded that when the wire feeding rate (or welding current) was either low or high, the optimum bead shape could be obtained along with the low spatter generation. However, in the middle range of wire feeding rate, the optimum bead shape was only obtained in the mixed mode condition resulting in the high spatter generation.

• Current Photovoltaic Research
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• v.2 no.2
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• pp.73-77
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• 2014

To investigate the effect of metal back-reflective layers (MBLs) on the performance of GaAs solar cells, we fabricated GaAs solar cells on Al and Ag metal layers using the transfer printing technique. We also investigated the effect of MBL texturing on the performance of transfer printed GaAs solar cells. Transfer printed solar cells with MBLs exhibited improved photovoltaic performance compared to solar cells without MBLs due to light trapping. We demonstrated GaAs solar cells with MBLs on a flexible substrate and performed systematic bending tests. All the measured characteristics of solar cells showed little change in performance.

• Journal of Welding and Joining
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• v.15 no.5
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• pp.84-91
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• 1997

The metal transfer phenomenon of the pulsed-GMAW is simulated by formulating the electromagnetic force incorporated with the Volume of Fluid algorithm. The free surface profiles, pressure and velocity distributions within the drop are computed numerically. Axial velocity and acceleration generated during peak current period are found to have a significant effect on drop detachment. Therefore, the accelerated inertia force becomes one of important factors affecting metal transfer in the pulsed-GMAW. When the pulse current parameters are selected properly, the molten drop is detached just after current pulse, and the operating range of the pulsing frequency increases with higher peak current and duty cycle. Calculated operating ranges show reasonably good agreements with the available experimental data.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.1741-1746
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• 2003

Effects of electromagnetic force which is one of the most important factor of metal transfer that affects bead geometry and microstructure of weld metal in GMAW(gas metal arc welding). In this paper, different ways of external electromagnetic forces were applied on GMAW process and their effects on the welding were studied. On certain conditions, better bead geometry, better influence on the arc and metal transfer mode and higher welding efficiency could be obtained. Experimental methods and their results will be presented.

• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.574-582
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• 1991

The CO molecules adsorbed on Ni(111) surface is studied in the cluster approximation employing EH method with self-consistent charge iteration. The effect of CO coverage is simulated by allowing the variation of valence state ionization potentials of each Ni atom in model cluster according to the self-consistent charge iteration method. The CO coverage dependent C-O stretching frequency shift, adsorption site conversion, and metal work function change are attributed to the charge transfer between metal surface and adsorbate. For CO/Ni(111) system, net charge transfer from Ni surface to chemisorbed CO molecules makes surface Ni atoms be more positive with increasing coverage, and lowers Ni surface valence band. This leads to a weaker interaction between metal surface valence band and Co $2{\pi}^{\ast}$ MO, less charge transfer to a single CO molecule, and the bule shift of C-O stretching frequency. Further increase of coverage induces the conversion of 3-fold site CO to lower coordination site CO as well as the blue shift of C-O stretching frequency. This whole process is accompanied by the continuous increase of metal work function.

• Journal of Welding and Joining
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• v.15 no.1
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• pp.109-115
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• 1997

The arc stability and the metal transfer mode of high deposition GMA welding were investigated using various compositions of shielding gas with two types of filler, ie solid wire and metal cored wire. As for a solid wire, the transfer mode changed from axial spray to rotational spray with increasing wire feed rate (welding current) and the transition current was different with the gas composition. The gas composition also affected the apparent stability of rotating arc. As for a metal cored wire, on the other hand, no transition occurred and thus spray transfer mode could be applied with the welding current over 500A (deposition rate over 300g/min). Looking for the development of high deposition GMA welding process, above results were discussed in two different ways, one is to elevate the transition current, the other is to stabilize the rotational transfer mode.

• Laser Solutions
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• v.2 no.1
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• pp.43-50
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• 1999

For the conventional welding method. the high heat transfer makes the crystallized zone of the work material unavoidable. Whereas the laser is able to weld the amorphous metal without a crystallized zone, because heat transfer is limited within a very small restricted volume. In this paper, the possibilities and the limits of the laser welding were studied to utilize the advantageous properties of amorphous metal foils.

• Journal of Photoscience
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• v.12 no.1
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• pp.47-50
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• 2005

Mediumeffects have been explored on the competitive H-atom abstraction and SET-promoted, silyl-transfer reactions of excited states of silylalkyl-substituted phenyl ketones. The chemical selectivities of photochemical reactions of silylalkyl phenyl ketones appear to depend on medium polarity, medium silophilicity, added metal cation and alkyl length. Irradiations of silylalkylketones in aqueous solvent system and in presence of metal cation such as $Li^+$ and $Mg^{+2} $lead to formation of acetophenone predominantly by the sequential SET-silyl transfer route.