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http://dx.doi.org/10.5857/RCP.2014.3.3.42

Molecular Wire World Having Metal Complexes  

Choi, Chang-Shik (Department of Oriental Medicine Fermentation, Far East University)
Publication Information
Rapid Communication in Photoscience / v.3, no.3, 2014 , pp. 42-47 More about this Journal
Abstract
Development of molecular and supramolecular systems showing efficient photoinduced energy or electron transfer are of current research interest due to their applications in various chemical and biological processes. Various polypyridine metal complexes including Ru(II), Ru(III), Os(II), Pt(II), Fe(II), Re(I), Ir(III) and so on as a metal center introduce for expanding some more understanding of molecular-scale photoelectronics. Their complexes are concisely classified by the types of relay ligands as follows; (a) metal-direct ligand-metal system; dinuclear or trinuclear systems, (b) metal-nonconjugated ligand-metal system and metal-nonconjugated ligand system having flexible/rigid ligand, (c) metal-conjugated ligand-metal system, and (d) conjugated ligand-metal-conjugated ligand system and metal-self assembly ligand-metal system. It is pointed out that the role played by the relay ligands is important in constructing the metal complexes.
Keywords
Metal complexes; Bridging ligand; Energy/electron transfer; ${\pi}$-conjugation system; Molecular wire;
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