• Title/Summary/Keyword: Metal Fuel

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ATWS Performance of KALIMER Uranium Metal Core

  • Dohee Hahn;Kim, Young C.
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.592-597
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    • 1996
  • The KALIMER core, of which nuclear design is largely governed by inherent safety and reactivity control issues, is fueled with metallic fuel, and the initial core will be loaded with 20% enriched Uranium metal fuel. KALIMER safety design objectives include the accommodation of unprotected, ATWS events without operator action, and without the support of active shutdown, shutdown heat removal, or any automatic system without damage to the plant and without jeopardizing public safety. The transient analysis of the core designs has been focused on severe events to assess the margins in the design, and ATWS events are the most severe events that must be accommodated by the KALIMER design. The ATWS performance has been evaluated for the preliminary initial core design of KALIMER with a particular emphasis on the inherent negative reactivity feedback effects, including the Doppler, sodium density, fuel axial expansion, core radial expansion, and control rod driveline expansion. Results show that the Uranium metal core design meets the temperature limits with margin.

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A Microbial Fuel Cell Type Lactate Biosensor Using a Metal-Reducing Bacterium, Shewanella putrefaciens

  • KIM, HYUNG JOO;MOON SIK HYUN;IN SEOP CHANG;BYUNG HONG KIM
    • Journal of Microbiology and Biotechnology
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    • v.9 no.3
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    • pp.365-367
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    • 1999
  • A fuel cell type biosensor for lactate was developed using a metal-reducing bacterium, Shewanella putrefaciens IR-1. Under the operational conditions, the bacterial cell suspension generated the current without an electrochemical mediator in the presence of lactate. The current was proportional to the lactate concentration up to 30 mM.

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A Study on the Performance of the Polymer Electrolyte Membrane Fuel Cell Using the Metal Bipolar Plates (금속분리판을 이용한 고분자전해질 연료전지의 성능에 관한 연구)

  • Jeon, U.-S.;Cho, E.A.;Ha, H.-Y.;Hong, S.-A.;Oh, I.-H.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.4
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    • pp.313-320
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    • 2002
  • The characteristics of the AISI bipolar plates have been investigated to replace the expensive graphite bipolar plates. It was found from the contact resistance evaluation of graphites, composites, and AISI that the contact resistance of AISI was the lowest, but it could approach to that of composites at higher compression forces. The single cell operation using the AISI bipolar plates revealed that the lower performance of the AISI single cell compared to the graphite one was due to not only the higher contact resistance but the flooding effect caused by high wettability of AISI. The performance of the AISI single cell could be improved if the channels were modified appropriately. The large size AISI single cell was operated to investigated the size effect on the performance.

AN EXPERIMENTAL STUDY ON AN ELECTROCHEMICAL REDUCTION OF AN OXIDE MIXTURE IN THE ADVANCED SPENT-FUEL CONDITIONING PROCESS

  • Jeong, Sang-Mun;Park, Byung-Heung;Hur, Jin-Mok;Seo, Chung-Seok;Lee, Han-Soo;Song, Kee-Chan
    • Nuclear Engineering and Technology
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    • v.42 no.2
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    • pp.183-192
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    • 2010
  • An electrochemical reduction of a mixture of metal oxides was conducted in a LiCl molten salt containing 3 wt% $Li_2O$ at $650^{\circ}C$. The oxide reduction was carried out by applying a current to an electrolysis cell, and the $Li_2O$ concentration was analyzed during each run. The concentration of $Li_2O$ in the electrolyte bulk phase gradually decreases according to Faraday's law due to a slow diffusion of the $O^{2-}$ ions. A hindrance effect of the unreduced metal oxides was observed for the reduction of the uranium oxide. Cs, Sr, and Ba of high heat-load fission products were diffused into and accumulated in the salt phase as predicted with thermodynamic consideration.

Laser Welding of Seal Tube for Instrumented Irradiation Fuel Test (계장핵연료 조사시험용 실튜브 레이저용접기술)

  • Kim Soo-Sung;Lee Chul-Yong;Kim Woong-Ki;Park Geun-Il;Koh Jinh-Yun;Seo Jun-Seok
    • Journal of Welding and Joining
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    • v.23 no.6
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    • pp.43-48
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    • 2005
  • This work was carried out to obtain sound welds and to select a most suitable binary metal joint among three different dissimilar binary metal combinations such as Zr-4/Ta, Mo/Ta and Ti/Ta(seal tube/sensor sheath) joints fur the instrumented nuclear fuel irradiation test. To do this, Taguchi experimental method was employed to optimize the experimental data. In addition, metallography, micro-focus x-ray radiography and hardness test were conducted to examine the welds. From the weld bead appearance, penetration depth and bead width as well as weld defects standpoint, Zr-4/Ta joint is suggested for the circumferential joining between a seal tube and a sensor sheath. The optimized welding parameters based on Zr-4/Ta joint are suggested as well.

Characteristics of Fuel-rich Solid Propellants with Boron Powder and the Combustion Products (Boron Powder 적용 연료과농 추진제 및 연소 후 생성물의 특성 연구)

  • Kim, Miri;Kim, Jeongeun;Khil, Taeock
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.1
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    • pp.12-19
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    • 2022
  • The propellants used in the gas generator of the ducted rocket are fuel-rich propellants, which contain an excessive amount of metal fuel and a small amount of oxidizing agent compared to general solid rocket propellants. In this paper, boron powder and MgAl(Magnesium-Aluminium alloy) were applied to produce fuel-rich propellants. The optimum formulation was determined by characterizing these metal fuel-rich propellants. Analysis of combustion products in the gas generators confirmed that the fuel-rich propellants containing fine boron powder itself instead of boron-bead could be useful in gas generators.

Modelling of the fire impact on CONSTOR RBMK-1500 cask thermal behavior in the open interim storage site

  • Robertas Poskas;Kestutis Rackaitis;Povilas Poskas;Hussam Jouhara
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2604-2612
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    • 2023
  • Spent nuclear fuel and long-lived radioactive waste must be carefully handled before disposing them off to a geological repository. After the pre-storage period in water pools, spent nuclear fuel is stored in casks, which are widely used for interim storage. Interim storage in casks is very important part in the whole cycle of nuclear energy generation. This paper presents the results of the numerical study that was performed to evaluate the thermal behavior of a metal-concrete CONSTOR RBMK-1500 cask loaded with spent nuclear fuel and placed in an open type interim storage facility which is under fire conditions (steady-state, fire, post-fire). The modelling was performed using the ANSYS Fluent code. Also, a local sensitivity analysis of thermal parameters on temperature variation was performed. The analysis demonstrated that the maximum increase in the fuel load temperatures is about 10 ℃ and 8 ℃ for 30 min 800 ℃ and 60 min 600 ℃ fires respectively. Therefore, during the fire and the post-fire periods, the fuel load temperatures did not exceed the 300 ℃ limiting temperature set for an RBMK SNF cladding for long-term storage. This ensures that fire accident does not cause overheating of fuel rods in a cask.

Preparation of Pt/C catalyst for PEM fuel cells using polyol process (Polyol Process를 통한 PEM Fuel Cell용 Pt/C촉매 제조)

  • Oh, Hyoung-Seok;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.443-446
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    • 2006
  • Carbon-supported Platinum (Pt) is the potential electro-catalyst material for anodic and cathodic reactions in fuel cell. Catalytic activity of the metal strongly depends on the particle shape, size and distribution of the metal in the porous supportive network. Conventional preparation techniques based on wet impregnation and chemical reduction of the metal precursors often do not provide adequate control of particle size and shape. We have proposed a novel route for preparing nano sized Pt colloidal particles in solution by oxidation of ethylene glycol. These Pt nano particles were deposited on large surface area carbon support. The process of nano Pt colloid formation involves the oxidation of solvent ethylene glycol to mainly glycolic acid and the presence of its anion glycolate depends on the solution pH. In the process of colloidal Pt formation glycolate actsas stabilizer for the Pt colloidal particle and prevents the agglomeration of colloidal Pt particles. These mono disperse Pt particles in carbon support are found uniformly distributed in nearly spherical shape and the size distribution was narrow for both supported and unsupported metals. The average diameter of the Pt nano particle was controlled in the range off to 3 nm by optimizing reaction parameters. Transmission electron microscopy, CV and RRDE experiments were used to compliment the results.

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Status Analysis for the Confinement Monitoring Technology of PWR Spent Nuclear Fuel Dry Storage System (경수로 사용후핵연료 건식저장시스템의 격납감시 기술현황 분석)

  • Baeg, Chang-Yeal;Cho, Chun-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.1
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    • pp.35-44
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    • 2016
  • Leading national R&D project to design a PWR spent nuclear fuel interim dry storage system that has been under development since mid-2009, which consists of a dual purpose metal cask and concrete storage cask. To ensure the safe operation of dry storage systems in foreign countries, major confinement monitoring techniques currently consist of pressure and temperature measurement. In the case of a dual purpose metal cask, a pressure sensor is installed in the interspace of bolted double lid(primary and secondary lid) in order to measure pressure. A concrete storage cask is a canister based system made of double/redundant welded lid to ensure confinement integrity. For this reason, confinement monitoring method is real time temperature measurement by thermocouple placed in the air flow(air intake and exit) of the concrete structure(over pack and module). The use of various monitoring technologies and operating experiences for the interim dry storage system over the last decades in foreign countries were analyzed. On the basis of the analysis above, development of the confinement monitoring technology that can be used optimally in our system will be available in the near future.

Application of Atomic Layer Deposition to Electrodes in Solid Oxide Fuel Cells

  • Kim, Eui-Hyeon;Hwang, Heui-Soo;Ko, Myeong-Hee;Bae, Seung-Muk;Hwang, Jin-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.319.1-319.1
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    • 2013
  • Solid oxide fuel cells (SOFCs) have been recognized as one of emerging renewable energy sources, due to minimized pollutant production and high efficiency in operation. The performance of SOFCs is largely dependent on the electrode polarization which involves the oxidation/reduction in cathodes and anodes along with the charge transport of ions and electronic carriers. Atomic layer deposition is based on the alternate chemical surface reaction occurring at low temperatures with high uniformity and superior step coverage. Such features can be extended into the coating of metal oxide and/or metal layer onto the porous materials. In particular, the atomic layer deposition is can manipulated in controlling the charge transport in terms of triple phase boundaries, in order to control artificially the electrochemical polarization in electrodes of SOFC. The current work applied atomic layer deposition of metal oxides intro the electrodes of SOFCs. The corresponding effect was monitored in terms of the electrochemical characterization. The roles of atomic layer deposition in solid oxide fuel cells are discussed towards optimized towards long-term durability at intermediate temperature.

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